66 research outputs found
Streaming potential measurements 1. Properties of the electrical double layer from crushed rock samples
The ξ potential has been inferred from streaming potential measurements with crushed rock samples as a function of pH and electrolyte concentration for various salts. The value obtained for crushed Fontainebleau sandstone at pH = 5.7 and a KCl solution with a resistivity of 400 Ω m is −40 ± 5 mV, where the error is dominated by sample to sample variations. The sensitivity of the ξ potential to the electrolyte resistivity for KCl is given experimentally by ρ_f^(0.23±0.014) where ρ_f is the electrolyte resistivity. The point of zero charge (pzc) is observed for pH = 2.5 ± 0.1, and the ξ potential is positive for pH pzc. For pH > 5 the variations of the ξ potential with pH can be approximated by ξ(pH)/ξ(5.7) = 1 + (0.068 ± 0.004)(pH - 5.7) for ρ_f = 100 Ω m. The ξ potential has been observed to be sensitive to the valence of the ions and is approximately reduced by the charge of the cation, unless specific adsorption takes place like in the case of Al^3+. The experimental results are well accounted for by a three-layer numerical model of the electrical double layer, and the parameters of this model can be evaluated from the experimental data. The sensitivity of the ξ potential to the rock minerals has also been studied. The ξ potential obtained for granitic rocks is comparable to that obtained for Fontainebleau sandstone but can be reduced by a factor of 2–4 for sandstones containing significant fractions of carbonates or clay. To take into account the effect of the chemical composition of the electrolyte, a chemical efficiency is defined as the ratio of the ξ potential to the ξ potential measured for KCl. This chemical efficiency is measured to be ∼80% for typical groundwater but can be as low as 40% for a water with a high dissolved carbonate content. The set of empirical laws derived from our measurements can be used to assess the magnitude of the streaming potentials expected in natural geophysical systems
A multi-site campaign to measure solar-like oscillations in Procyon. II. Mode frequencies
We have analyzed data from a multi-site campaign to observe oscillations in
the F5 star Procyon. The data consist of high-precision velocities that we
obtained over more than three weeks with eleven telescopes. A new method for
adjusting the data weights allows us to suppress the sidelobes in the power
spectrum. Stacking the power spectrum in a so-called echelle diagram reveals
two clear ridges that we identify with even and odd values of the angular
degree (l=0 and 2, and l=1 and 3, respectively). We interpret a strong, narrow
peak at 446 muHz that lies close to the l=1 ridge as a mode with mixed
character. We show that the frequencies of the ridge centroids and their
separations are useful diagnostics for asteroseismology. In particular,
variations in the large separation appear to indicate a glitch in the
sound-speed profile at an acoustic depth of about 1000 s. We list frequencies
for 55 modes extracted from the data spanning 20 radial orders, a range
comparable to the best solar data, which will provide valuable constraints for
theoretical models. A preliminary comparison with published models shows that
the offset between observed and calculated frequencies for the radial modes is
very different for Procyon than for the Sun and other cool stars. We find the
mean lifetime of the modes in Procyon to be 1.29 +0.55/-0.49 days, which is
significantly shorter than the 2-4 days seen in the Sun.Comment: accepted for publication in Ap
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