The evolution of the specific star formation rate of massive galaxies to z ~ 1.8 in the E-CDFS

We study the evolution of the star formation rate (SFR) of mid-infrared (IR) selected galaxies in the extended Chandra Deep Field South (E-CDFS). We use a combination of U-K GaBoDS and MUSYC data, deep IRAC observations from SIMPLE, and deep MIPS data from FIDEL. This unique multi-wavelength data set allows us to investigate the SFR history of massive galaxies out to redshift z ~ 1.8. We determine star formation rates using both the rest-frame ultraviolet luminosity from young, hot stars and the total IR luminosity of obscured star formation obtained from the MIPS 24 um flux. We find that at all redshifts the galaxies with higher masses have substantially lower specific star formation rates than lower mass galaxies. The average specific star formation rates increase with redshift, and the rate of incline is similar for all galaxies (roughly (1+z)^{n}, n = 5.0 +/- 0.4). It does not seem to be a strong function of galaxy mass. Using a subsample of galaxies with masses M_*> 10^11 M_sun, we measured the fraction of galaxies whose star formation is quenched. We consider a galaxy to be in quiescent mode when its specific star formation rate does not exceed 1/(3 x t_H), where t_H is the Hubble time. The fraction of quiescent galaxies defined as such decreases with redshift out to z ~ 1.8. We find that, at that redshift, 19 +/-9 % of the M_* > 10^11 M_sun sources would be considered quiescent according to our criterion.Comment: 7 pages, 6 figures, accepted for publication in Ap

Constraints on the Assembly and Dynamics of Galaxies: I. Detailed Rest-frame Optical Morphologies on Kiloparsec-scale of z ~ 2 Star-forming Galaxies

We present deep and high-resolution HST/NIC2 F160W imaging at 1.6micron of six z~2 star-forming galaxies with existing near-IR integral field spectroscopy from SINFONI at the VLT. The unique combination of rest-frame optical imaging and nebular emission-line maps provides simultaneous insight into morphologies and dynamical properties. The overall rest-frame optical emission of the galaxies is characterized by shallow profiles in general (Sersic index n<1), with median effective radii of ~5kpc. The morphologies are significantly clumpy and irregular, which we quantify through a non-parametric morphological approach, estimating the Gini (G), Multiplicity (Psi), and M_20 coefficients. The strength of the rest-frame optical emission lines in the F160W bandpass indicates that the observed structure is not dominated by the morphology of line-emitting gas, and must reflect the underlying stellar mass distribution of the galaxies. The sizes and structural parameters in the rest-frame optical continuum and Halpha emission reveal no significant differences, suggesting similar global distributions of the on-going star formation and more evolved stellar population. While no strong correlations are observed between stellar population parameters and morphology within the NIC2/SINFONI sample itself, a consideration of the sample in the context of a broader range of z~2 galaxy types indicates that these galaxies probe the high specific star formation rate and low stellar mass surface density part of the massive z~2 galaxy population, with correspondingly large effective radii, low Sersic indices, low G, and high Psi and M_20. The combined NIC2 and SINFONI dataset yields insights of unprecedented detail into the nature of mass accretion at high redshift. [Abridged]Comment: 44 pages, 19 figures. Revised version accepted for publication in the Astrophysical Journa

PPARγ agonists negatively regulate αIIbβ3 integrin outside-in signalling and platelet function through upregulation of protein kinase A activity

BACKGROUND: Agonists for the peroxisome proliferator activated receptor PPARγ, have been shown to have inhibitory effects on platelet activity following stimulation by GPVI and GPCR agonists. OBJECTIVES: Profound effects on thrombus formation led us to suspect a role for PPARγ agonists in the regulation of integrin αIIbβ3 mediated signalling. Both GPVI and GPCR signalling pathways lead to αIIbβ3 activation, and signalling through αIIbβ3 plays a critical role in platelet function and normal haemostasis. METHODS: The effects of PPARγ agonists on the regulation of αIIbβ3 outside-in signalling was determined by monitoring the ability of platelets to adhere and spread on fibrinogen and undergo clot retraction. Effects on signalling components downstream of αIIbβ3 activation were also determined following adhesion to fibrinogen by western blotting. RESULTS: Treatment of platelets with PPARγ agonists inhibited platelet adhesion and spreading on fibrinogen and diminished clot retraction. A reduction in phosphorylation of several components of αIIbβ3 signalling, including the integrin β3 subunit, Syk, PLCγ2, FAK and Akt was also observed as a result of reduced interaction of the integrin β3 subunit with Gα13. Studies of VASP phosphorylation revealed that this was a due to an increase in PKA activity following treatment with PPARγ receptor agonists. CONCLUSIONS: This study provides further evidence for anti-platelet actions of PPARγ agonists, identifies a negative regulatory role for PPARγ agonists in the control of integrin αIIbβ3 outside-in signalling, and provides a molecular basis by which the PPARγ agonists negatively regulate platelet activation and thrombus formation

Spectroscopic Identification of Massive Galaxies at z~2.3 with Strongly Suppressed Star Formation

We present first results of a spectroscopic survey targeting K-selected galaxies at z=2.0-2.7 using the GNIRS instrument on Gemini-South. We obtained near-infrared spectra with a wavelength coverage of 1.0-2.5 micron for 26 K-bright galaxies (K<19.7) selected from the MUSYC survey using photometric redshifts. We successfully derived spectroscopic redshifts for all 26 galaxies using rest-frame optical emission lines or the redshifted Balmer/4000 Angstrom break. Twenty galaxies have spectroscopic redshifts in the range 2.0<z<2.7, for which bright emission lines like Halpha and [OIII] fall in atmospheric windows. Surprisingly, we detected no emission lines for nine of these 20 galaxies. The median 2 sigma upper limit on the rest-frame equivalent width of Halpha for these nine galaxies is ~10 Angstrom. The stellar continuum emission of these same nine galaxies is best fitted by evolved stellar population models. The best-fit star formation rate (SFR) is zero for five out of nine galaxies, and consistent with zero within 1 sigma for the remaining four. Thus, both the Halpha measurements and the independent stellar continuum modeling imply that 45% of our K-selected galaxies are not forming stars intensely. This high fraction of galaxies without detected line emission and low SFRs may imply that the suppression of star formation in massive galaxies occurs at higher redshift than is predicted by current CDM galaxy formation models. However, obscured star formation may have been missed, and deep mid-infrared imaging is needed to clarify this situation.Comment: Accepted for publication in ApJ Letter

The Space Density and Colors of Massive Galaxies at 2<z<3: the Predominance of Distant Red Galaxies

Using the deep multi-wavelength MUSYC, GOODS, and FIRES surveys we construct a stellar mass-limited sample of galaxies at 2<z<3. The sample comprises 294 galaxies with M>10^11 Solar masses distributed over four independent fields with a total area of almost 400 sq arcmin. The mean number density of massive galaxies in this redshift range is (2.2+-0.6) x 10^-4 Mpc^-3. We present median values and 25th and 75th percentiles for the distributions of observed R mags, observed J-K colors, and rest-frame UV continuum slopes, M/L(V) ratios, and U-V colors. The galaxies show a large range in all these properties. The ``median galaxy'' is faint in the observer's optical (R=25.9), red in the observed near-IR (J-K=2.48), has a rest-frame UV spectrum which is relatively flat (beta=-0.4), and rest-frame optical colors resembling those of nearby spiral galaxies (U-V=0.62). We determine which galaxies would be selected as Lyman break galaxies (LBGs) or Distant Red Galaxies (DRGs, having J-K>2.3) in this mass-limited sample. By number DRGs make up 69% of the sample and LBGs 20%, with a small amount of overlap. By mass DRGs make up 77% and LBGs 17%. Neither technique provides a representative sample of massive galaxies at 2<z<3 as they only sample the extremes of the population. As we show here, multi-wavelength surveys with high quality photometry are essential for an unbiased census of massive galaxies in the early Universe. The main uncertainty in this analysis is our reliance on photometric redshifts; confirmation of the results presented here requires extensive near-infrared spectroscopy of optically-faint samples.Comment: Accepted for publication in ApJ Letter

The effect of crystalline phase (anatase, brookite and rutile) and size on the photocatalytic activity of calcined polymorphic titanium dioxide (TiO2)

© 2018 Elsevier Ltd. The effect of thermal treatment on the morphology (crystalline phase and size) and photocatalytic activity of freshly prepared TiO 2 nano-powder is communicated. TiO 2 nano-powders, prepared by hydrolyzing titanium tetraisopropoxide at room temperature, were all dried at 382 K and subsequently calcined at different temperatures, for 1 h, up to 1172 K. Raman analysis of each thermally treated sample exhibited different titania phase structures. Up to 772 K a mixture of brookite and anatase phases was observed, while a mixture of all three phases, i.e. anatase, brookite and rutile, was observed at 872 K, with a rutile only phase at 1097 K and above. The photocatalytic activity of all samples was assessed by means of the photocatalytic degradation of methyl orange dye (MeO). All anatase-brookite compositions exhibited high photocatalytic activity with the rate of degradation decreasing with increasing calcination temperature, which coincides with (i) a slight increase of the anatase phase, (ii) a slight decrease of the brookite phase, and (iii) a gradual increase of the crystallite size of all phases. The greatest photocatalytic activity was observed for the sample calcined at 382 K, which contained the highest amount of brookite (in the presence of anatase as the dominant phase), while the lowest rate was observed for the pure rutile sample

Constraints on the assembly and dynamics of galaxies. II. Properties of kiloparsec-scale clumps in rest-frame optical emission of z ~ 2 star-forming galaxies

We study the properties of luminous stellar clumps identified in deep, high resolution HST/NIC2 F160W imaging at 1.6um of six z~2 star-forming galaxies with existing near-IR integral field spectroscopy from SINFONI at the VLT. Individual clumps contribute ~0.5%-15% of the galaxy-integrated rest-frame ~5000A emission, with median of about 2%; the total contribution of clump light ranges from 10%-25%. The median intrinsic clump size and stellar mass are ~1kpc and log(Mstar[Msun])~9, in the ranges for clumps identified in rest-UV or line emission in other studies. The clump sizes and masses in the subset of disks are broadly consistent with expectations for clump formation via gravitational instabilities in gas-rich, turbulent disks given the host galaxies' global properties. By combining the NIC2 data with ACS/F814W imaging available for one source, and AO-assisted SINFONI Halpha data for another, we infer modest color, M/L, and stellar age variations within each galaxy. In these two objects, sets of clumps identified at different wavelengths do not fully overlap; NIC2-identified clumps tend to be redder/older than ACS- or Halpha-identified clumps without rest-frame optical counterparts. There is evidence for a systematic trend of older ages at smaller galactocentric radii among the clumps, consistent with scenarios where inward migration of clumps transports material towards the central regions. From constraints on a bulge-like component at radii <1-3kpc, none of the five disks in our sample appears to contain a compact massive stellar core, and we do not discern a trend of bulge stellar mass fraction with stellar age of the galaxy. Further observations are necessary to probe the build-up of stellar bulges and the role of clumps in this process.Comment: 29 pages, 11 figures. Revised version accepted for publication in the Astrophysical Journa

HST and Spitzer imaging of red and blue galaxies at z~2.5: A correlation between size and star formation activity from compact quiescent galaxies to extended star forming galaxies

We present HST NICMOS+ACS and Spitzer IRAC+MIPS observations of 41 galaxies at 2<z<3.5 in the FIRES MS1054 field with red and blue rest-frame optical colors. About half of the galaxies are very compact (effective radii r_e < 1 kpc) at rest-frame optical wavelengths, the others are extended (1< r_e < 10 kpc). For reference, 1 kpc corresponds to 0.12 arcsec at z=2.5 in the adopted cosmology. We separate actively star forming galaxies from quiescent galaxies by modeling their rest-frame UV-NIR SEDs. The star forming galaxies span the full range of sizes, while the quiescent galaxies all have r_e<2kpc. In the redshift range where MIPS 24 micron imaging is a sensitive probe of re-radiated dust emission (z<2.5), the 24 micron fluxes confirm that the light of the small quiescent galaxies is dominated by old stars, rather than dust-enshrouded star formation or AGN activity. The inferred surface mass densities and velocity dispersions for the quiescent galaxies are very high compared to those in local galaxies. The galaxies follow a Kormendy relation (between surface brightness and size) with approximately the same slope as locally, but shifted to brighter surface brightnesses, consistent with a mean stellar formation redshift of z_f~5. This paper demonstrates a direct relation between star formation activity and size at z~2.5, and the existence of a significant population of massive, extremely dense, old stellar systems without readily identifiable counterparts in the local universe.Comment: Accepted for publication in Ap

The Origin of Line Emission in Massive z~2.3 Galaxies: Evidence for Cosmic Downsizing of AGN Host Galaxies

Using the Gemini Near-InfraRed Spectrograph (GNIRS), we have assembled a complete sample of 20 K-selected galaxies at 2.0<z<2.7 with high quality near-infrared spectra. As described in a previous paper, 9 of these 20 galaxies have strongly suppressed star formation and no detected emission lines. The present paper concerns the 11 galaxies with detected Halpha emission, and studies the origin of the line emission using the GNIRS spectra and follow-up observations with SINFONI on the VLT. Based on their [NII]/Halpha ratios, the spatial extent of the line emission and several other diagnostics, we infer that four of the eleven emission-line galaxies host narrow line active galactic nuclei (AGNs). The AGN host galaxies have stellar populations ranging from evolved to star-forming. Combining our sample with a UV-selected galaxy sample at the same redshift that spans a broader range in stellar mass, we find that black-hole accretion is more effective at the high-mass end of the galaxy distribution (~2.9x10^11 Msun) at z~2.3. Furthermore, by comparing our results with SDSS data, we show that the AGN activity in massive galaxies has decreased significantly between z~2.3 and z~0. AGNs with similar normalized accretion rates as those detected in our K-selected galaxies reside in less massive galaxies (~4.0x10^10 Msun) at low redshift. This is direct evidence for downsizing of AGN host galaxies. Finally, we speculate that the typical stellar mass-scale of the actively accreting AGN host galaxies, both at low and at high redshift, might be similar to the mass-scale at which star-forming galaxies seem to transform into red, passive systems.Comment: Accepted for publication in the Astrophysical Journa

Use of ion-assisted sputtering technique for producing photocatalytic titanium dioxide thin films: Influence of thermal treatments on structural and activity properties based on the decomposition of stearic acid

Titanium dioxide thin films were deposited by the reactive ion-assisted sputtering method from titanium targets at various partial pressures and deposition parameters. The films were deposited onto substrates at temperatures ranging from room-temperature conditions to 722 K. A selection of thin films was post-deposited annealed at temperatures up to 972 K for 10 min and characterized by micro-Raman spectroscopy and scanning electron microscopy (SEM) and subsequently analysed to assess their photocatalytic activity. Micro-Raman characterization revealed that the as-deposited films had either predominant amorphous, rutile-like structures, anatase-like structures or anatase-rutile mixed structures. The thin films deposited with a high substrate temperature and with energy assistance from the ion source tended to be amorphous, while films deposited on a hot substrate without ion energy assistance tended to have a mixed crystalline phase. On subsequent annealing the amorphous films changed to a rutile structure at temperatures above 672 K, while mixed anatase-rutile films changed to predominant rutile structures only after thermal treatments above 872 K. Thus, this study has revealed an astonishing persistence of the anatase-rutile mixed phase at very high temperatures and showed the possible existence of a key transition temperature at 672 K, where it was possible to see a transformation from amorphous or mixed phase to a rutile or dominant rutile mixed phase. Photocatalytic tests were undertaken by using a novel method consisting of observing the degradation of a film of stearic acid by the thin films under artificial UV radiation. Of the films investigated those with anatase-rutile mixed phases showed the greatest photoactivity. This work was essential in the understanding of the correlation between growth deposition conditions, phase transitions and photocatalytic activity. This set of experiments demonstrated that titania made under a highly oxidizing atmosphere, with no temperature applied on the substrate during fabrication and using an ion sputtering method, is a useful and valuable novel method for creating active TiO2thin films