Midwest Consumers’ Beliefs and Attitudes Regarding Agricultural Biotechnology: An Executive Summary

As part of a project investigating the social, economic, and ethical issues related to the application of biotechnology to food production and to the adoption or rejection of genetically modified organisms (GMOs), we conducted a survey using a questionnaire mailed to a randomly selected sample of consumers in five Midwestern states—Iowa, Minnesota, North Dakota, South Dakota, and Wisconsin. This report highlights the responses of the 458 respondents to that completed and returned questionnaire

Catalysts for long-life closed-cycle CO2 lasers

Long-life, closed-cycle operation of pulsed CO2 lasers requires catalytic CO-O2 recombination both to remove O2, which is formed by discharge-induced CO2 decomposition, and to regenerate CO2. Platinum metal on a tin (IV) oxide substrate (Pt/SnO2) has been found to be an effective catalyst for such recombination in the desired temperature range of 25 to 100 C. This paper presents a description of ongoing research at NASA-LaRC on Pt/SnO2 catalyzed CO-O2 recombination. Included are studies with rare-isotope gases since rare-isotope CO2 is desirable as a laser gas for enhanced atmospheric transmission. Results presented include: (1) achievement of 98% to 100% conversion of a stoichiometric mixture of CO and O2 to CO2 for 318 hours (greater than 1 x 10 to the 6th power seconds), continuous, at a catalyst temperature of 60 C, and (2) development of a technique verified in a 30-hour test, to prevent isotopic scrambling when CO-18 and O-18(2) are reacted in the presence of a common-isotope Pt/Sn O-16(2) catalyst

Pt/SnO2-based CO-oxidation catalysts for long-life closed-cycle CO2 lasers

Noble-metal/tin-oxide based catalysts such as Pt/SnO2 have been shown to be good catalysts for the efficient oxidation of CO at or near room temperature. These catalysts require a reductive pretreatment and traces of hydrogen or water to exhibit their full activity. Addition of Palladium enhances the activity of these catalysts with about 15 to 20 percent Pt, 4 percent Pd, and the balance SnO2 being an optimum composition. Unfortunately, these catalysts presently exhibit significant decay due in part to CO2 retention, probably as a bicarbonate. Research on minimizing the decay in activity of these catalysts is currently in progress. A proposed mechanism of CO oxidation on Pt/SnO2-based catalysts has been developed and is discussed

Chemical Study of the Interstitial Water Dissolved Organic Matter and Gases in Lake Erie, Cleveland Harbor, and Hamilton Harbour Bottom Sediments - Composition and Fluxes to Overlying Waters

The research on which this report is based was financed in part by the U.S. Department of the Interior, as authorized by the Water Research and Development Act of 1978 (P.L. 95-467).(print) iv, 167, [45] p. : ill., maps ; 29 cm.FINAL REPORT FOR OWRT GRANT A-O59-OHIOItem lacks publication date. Issue date supplied from hand-written year on coverIntroduction -- The Study Area -- Methods and Materials -- Results -- Discussion -- Conclusions -- Selected Bibliographic References -- Tables 1-32 -- Figures 1-36 -- Appendi

How does conformational flexibility influence key structural features involved in activation of anaplastic lymphoma kinase?

Anaplastic Lymphoma Kinase (ALK) plays a major role in developing tumor processes and therefore has emerged as a validated therapeutic target. Applying atomistic molecular dynamics simulations on the wild type enzyme and the nine most frequently occurring and clinically important activation mutants we revealed important conformational effects on key interactions responsible for the activation of the enzyme

Reactivation of a tin oxide-containing catalyst

A method for the reactivation of a tin oxide-containing catalyst of a CO.sub.2 laser is provided. First, the catalyst is pretreated by a standard procedure. When the catalyst experiences diminished activity during usage, the heated zone surrounding the catalyst is raised to a temperature which is the operating temperature of the laser and 400.degree. C. for approximately one hour. The catalyst is exposed to the same laser gas mixture during this period. The temperature of the heated zone is then lowered to the operating temperature of the CO.sub.2 laser

Measurements of the Complex Conductivity of NbxSi1-x Alloys on the Insulating Side of the Metal-Insulator Transition

We have conducted temperature and frequency dependent transport measurements in amorphous Nb_x Si_{1-x} samples in the insulating regime. We find a temperature dependent dc conductivity consistent with variable range hopping in a Coulomb glass. The frequency dependent response in the millimeter-wave frequency range can be described by the expression $sigma(omega) \propto (-\imath omega)^alpha$ with the exponent somewhat smaller than one. Our ac results are not consistent with extant theories for the hopping transport.Comment: 4 pages with 3 figures; published version has a different title from original (was: "Electrodynamics in a Coulomb glass"

Observational constraints on the chemistry of isoprene nitrates over the eastern United States

The formation of organic nitrates during the oxidation of the biogenic hydrocarbon isoprene can strongly affect boundary layer concentrations of ozone and nitrogen oxides (NOx = NO + NO2). We constrain uncertainties in the chemistry of these isoprene nitrates using chemical transport model simulations in conjunction with observations over the eastern United States from the International Consortium for Atmospheric Research on Transport and Transformation (ICARTT) field campaign during summer 2004. The model best captures the observed boundary layer concentrations of organic nitrates and their correlation with ozone using a 4% yield of isoprene nitrate production from the reaction of isoprene hydroxyperoxy radicals with NO, a recycling of 40% NOx when isoprene nitrates react with OH and ozone, and a fast dry deposition rate of isoprene nitrates. Simulated boundary layer concentrations are only weakly sensitive to the rate of photochemical loss of the isoprene nitrates. An 8% yield of isoprene nitrates degrades agreement with the observations somewhat, but concentrations are still within 50% of observations and thus cannot be ruled out by this study. Our results indicate that complete recycling of NOx from the reactions of isoprene nitrates and slow rates of isoprene nitrate deposition are incompatible with the observations. We find that ∼50% of the isoprene nitrate production in the model occurs via reactions of isoprene (or its oxidation products) with the NO3 radical, but note that the isoprene nitrate yield from this pathway is highly uncertain. Using recent estimates of rapid reaction rates with ozone, 20–24% of isoprene nitrates are lost via this pathway, implying that ozonolysis is an important loss process for isoprene nitrates. Isoprene nitrates are shown to have a major impact on the nitrogen oxide (NOx = NO + NO2) budget in the summertime U.S. continental boundary layer, consuming 15–19% of the emitted NOx, of which 4–6% is recycled back to NOx and the remainder is exported as isoprene nitrates (2–3%) or deposited (8–10%). Our constraints on reaction rates, branching ratios, and deposition rates need to be confirmed through further laboratory and field measurements. The model systematically underestimates free tropospheric concentrations of organic nitrates, indicating a need for future investigation of the processes controlling the observed distribution

The XMM-SSC survey of hard-spectrum XMM-Newton sources 1: optically bright sources

We present optical and X-ray data for a sample of serendipitous XMM-Newton sources that are selected to have 0.5-2 keV vs 2-4.5 keV X-ray hardness ratios which are harder than the X-ray background. The sources have 2-4.5 keV X-ray flux >= 10^-14 cgs, and in this paper we examine a subsample of 42 optically bright (r < 21) sources; this subsample is 100 per cent spectroscopically identified. All but one of the optical counterparts are extragalactic, and we argue that the single exception, a Galactic M star, is probably a coincidental association. The X-ray spectra are consistent with heavily absorbed power laws (21.8 < log NH < 23.4), and all of them appear to be absorbed AGN. The majority of the sources show only narrow emission lines in their optical spectra, implying that they are type-2 AGN. Only a small fraction of the sources (7/42) show broad optical emission lines, and all of these have NH < 10^23 cm^-2. This implies that ratios of X-ray absorption to optical/UV extinction equivalent to > 100 times the Galactic gas-to-dust ratio are rare in AGN absorbers (at most a few percent of the population), and may be restricted to broad absorption-line QSOs. Seven objects appear to have an additional soft X-ray component in addition to the heavily absorbed power law. We consider the implications of our results in the light of the AGN unified scheme. We find that the soft components in narrow-line objects are consistent with the unified scheme provided that > 4 per cent of broad-line AGN have ionised absorbers that attenuate their soft X-ray flux by >50 per cent. In at least one of the X-ray absorbed, broad-line AGN in our sample the X-ray spectrum requires an ionised absorber, consistent with this picture.Comment: accepted for publication in MNRA