1,587 research outputs found
A transient network of telechelic polymers and microspheres : structure and rheology
We study the structure and dynamics of a transient network composed of
droplets of microemulsion connected by telechelic polymers. The polymer induces
a bridging attraction between droplets without changing their shape. A
viscoelastic behaviour is induced in the initially liquid solution,
characterised in the linear regime by a stretched exponential stress
relaxation. We analyse this relaxation in the light of classical theories of
transient networks. The role of the elastic reorganisations in the deformed
network is emphasized. In the non linear regime, a fast relaxation dynamics is
followed by a second one having the same rate as in the linear regime. This
behaviour, under step strain experiments, should induce a non monotonic
behaviour in the elastic component of the stress under constant shear rate.
However, we obtain in this case a singularity in the flow curve very different
from the one observed in other systems, that we interpret in terms of fracture
behaviour.Comment: 9 pages, 4 figure
Time scales in shear banding of wormlike micelles
Transient stress and birefringence measurements are performed on wormlike micellar solutions that "shear band", i.e. undergo flow-induced coexistence of states of different viscosities along a constant stress "plateau". Three well-defined relaxation times are found after a strain rate step between two banded flow states on the stress plateau. Using the Johnson-Segalman model, we relate these time scales to three qualitatively different stages in the evolution of the bands and the interface between them: band destabilization, reconstruction of the interface, and travel of the fully formed interface. The longest timescale is then used to estimate the magnitude of the (unknown) "gradient" terms that must be added to constitutive relations to explain the history independence of the steady flow and the plateau stress selection
Determinação de ácido ascórbico em bebidas de abacaxi (Ananas comosus) e beterraba (Beta vulgaris) por titrimetria e cromatografia líquida.
Procoagulant changes in fibrin clot structure in patients with cirrhosis are associated with oxidative modifications of fibrinogen
Patients with cirrhosis have hemostatic changes, which may contribute to a risk of thrombosis. This in vitro study compares clot formation and structure between patients and healthy subjects. Clot formation is delayed in patients; ultimately, however, clot permeability is decreased. The thrombogenic structure of fibrin clots may contribute to the thrombotic risk in cirrhosis. Background and Objectives: Patients with cirrhosis can be at risk of thrombotic complications due to an imbalance between hemostatic components. However, little is known on how the disease affects clot generation or how alterations in the structure of fibrin clots may affect the hemostatic function of these patients. Methods: We investigated the formation and structure of clots generated with plasma and purified fibrinogen of 42 patients with cirrhosis. Clots generated with plasma and fibrinogen of 29 healthy volunteers were studied for comparison. Clot formation and structure were assessed by turbidity, permeation studies, confocal laser and scanning electron microscopy (SEM). The extent of fibrinogen oxidation was assessed by measuring the carbonyl content of purified fibrinogen samples. Results: Tissue factor and thrombin-induced clotting of plasma was delayed in patients. The clotting rate was also decreased, but change in turbidity, fibrin density and fiber thickness were largely comparable to healthy volunteers. Conversely, clot permeability was significantly decreased in patients. When clots were generated with purified fibrinogen, differences in clot formation and structure similar to those in plasma were found. The carbonyl content was increased in patient fibrinogen and correlated with disease severity and clot permeability. Conclusions: Delayed clot formation in cirrhosis ultimately results in decreased clot permeability. Similar alterations in clots generated with purified fibrinogen suggest that modifications of the molecule are (partly) responsible. Taken together, these findings are indicative of hypercoagulable features of clots of patients with cirrhosis, which may explain the increased risk of thrombosis associated with this condition
Bebida contendo abacaxi (Ananas comosus) e beterraba (Beta vulgaris) para crianças: tratar termicamente ou não?
Edição dos Resumos do VI Congresso Latinoamericano e XII Congresso Brasileiro de Higienistas de Alimentos, II Encontro Nacional de Vigilância das Zoonoses, IV Encontro do Sistema Brasileiro de Inspeção de Produtos de Origem Animal, Gramado, abr. 2013
Entropic phase separation of linked beads
We study theoretically a model system of a transient network of microemulsion
droplets connected by telechelic polymers and explain recent experimental
findings. Despite the absence of any specific interactions between either the
droplets or polymer chains, we predict that as the number of polymers per drop
is increased, the system undergoes a first order phase separation into a dense,
highly connected phase, in equilibrium with dilute droplets, decorated by
polymer loops. The phase transition is purely entropic and is driven by the
interplay between the translational entropy of the drops and the
configurational entropy of the polymer connections between them. Because it is
dominated by entropic effects, the phase separation mechanism of the system is
extremely robust and does not depend on the particlular physical realization of
the network. The discussed model applies as well to other polymer linked
particle aggregates, such as nano-particles connected with short DNA linkers
Understanding the core density profile in TCV H-mode plasmas
Results from a database analysis of H-mode electron density profiles on the
Tokamak \`a Configuration Variable (TCV) in stationary conditions show that the
logarithmic electron density gradient increases with collisionality. By
contrast, usual observations of H-modes showed that the electron density
profiles tend to flatten with increasing collisionality. In this work it is
reinforced that the role of collisionality alone, depending on the parameter
regime, can be rather weak and in these, dominantly electron heated TCV cases,
the electron density gradient is tailored by the underlying turbulence regime,
which is mostly determined by the ratio of the electron to ion temperature and
that of their gradients. Additionally, mostly in ohmic plasmas, the Ware-pinch
can significantly contribute to the density peaking. Qualitative agreement
between the predicted density peaking by quasi-linear gyrokinetic simulations
and the experimental results is found. Quantitative comparison would
necessitate ion temperature measurements, which are lacking in the considered
experimental dataset. However, the simulation results show that it is the
combination of several effects that influences the density peaking in TCV
H-mode plasmas.Comment: 23 pages, 12 figure
Characterization of intermediate depth reservoirs in complex coastal areas with CSEM method
International audienc
An elastic, plastic, viscous model for slow shear of a liquid foam
We suggest a scalar model for deformation and flow of an amorphous material
such as a foam or an emulsion. To describe elastic, plastic and viscous
behaviours, we use three scalar variables: elastic deformation, plastic
deformation rate and total deformation rate; and three material specific
parameters: shear modulus, yield deformation and viscosity. We obtain equations
valid for different types of deformations and flows slower than the relaxation
rate towards mechanical equilibrium. In particular, they are valid both in
transient or steady flow regimes, even at large elastic deformation. We discuss
why viscosity can be relevant even in this slow shear (often called
"quasi-static") limit. Predictions of the storage and loss moduli agree with
the experimental literature, and explain with simple arguments the non-linear
large amplitude trends
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