Electrochemical and structural studies of nickel (II) Schiff base complexes derived from salicylaldehyde. Structural effects of bridge substituents on the stabilisation of the +3 oxidation state

The oxidative chemistry of three Ni(II) complexes with Schiff base ligands derived from salicylaldehyde and diamines with different steric demands, N,N9-2-methylpropane-2,3-diyl-bis(salicylideneiminate)nickel(II) (1), N,N9-1,2-cyclohexyl-1,2-dyil-bis(salicylideneiminate)- nickel(II) (2) and N,N9-2,3-dimethylbutane-2,3-diyl-bis(salicylideneiminate)nickel(II) (3), was studied by cyclic voltammetry and chronoamperometry in N,N9-dimethylformamide and (CH3)2SO

Análise da problemática dos Bruquideos (Coleoptera) em ervilha armazenada numa perspectiva de protecção integrada

Bruchids (Coleoptera: Bruchidae) are considered the main enemies of stored pulses. In the 32 samples of stored peas (Pisum sativum L.) collected in different areas of Portugal, 96% of the insects found were Bruchidae. Of these, 93% were Bruchus pisorum (L.), which was detected in all samples. The other bruchids found were: Bruchus rufimanus Boh., Bruchus tristiculus Fahr., Acanthoscelides obtectus (Say), Spermophagus sericeus (Geoffr.) e Zabrotes subfasciatus (Boh.). For the evaluation of pea varieties resistance to bruchids attack, the mean number of attacked seeds was used as the evaluation parameter. The varieties Ucero, Solara and Talanda were the most promising ones in order to be used as an alternative or complement of pesticides. Other control methods, which still need to be developed for an efficient control of bruchids in stored peas, are also discussed

III Ciclo de Conferências do Conselho Técnico-Científico : temas atuais em investigação

A obra é constituída pelos resumos das comunicações apresentadas pelos docentes da Escola Superior Agrária do Instituto Politécnico de Castelo Branco e são referentes aos projetos de investigação nos quais estão envolvidos.O Conselho Técnico-Científico da Escola Superior Agrária (ESA), eleito para o biénio 2014-2016, tomou posse no dia 27 de março de 2014. Uma das iniciativas previstas no seu Plano de Atividades consistia no desenvolvimento de ações de divulgação de atividades técnico-científicas, com intervenção da ESA. Neste âmbito promoveu-se o III Ciclo de Conferências do Conselho Técnico-Científico, através do qual se procurou fomentar a difusão do conhecimento e valorizar os resultados de trabalhos de investigação e de experimentação, através da divulgação do seu contributo para o desenvolvimento tecnológico e da inovação de empresas e produtos. Com a presente publicação pretende dar-se a conhecer a um auditório mais vasto a informação apresentada e debatida publicamente, assim como promover uma maior colaboração entre entidades e instituições em ações suscetíveis de contribuir para o aumento da competitividade e do espírito empreendedor de empresas associadas ao setor agrícola e agroindustrial

Biodiversity Assessment and Geographical Affinities of Discards in Clam Fisheries in the Atlantic–Mediterranean Transition (Northern Alboran Sea)

This study focused on the assessment and quantification of discards generated by clam fisheries along the northern Alboran Sea (western Mediterranean). Discard samples (n = 278) were collected throughout one year on board nine commercial vessels. A total of 129 species were identified, mostly represented by molluscs (72 spp.), arthropods (20 spp.) and echinoderms (12 spp.). Molluscs dominated in terms of abundance (67.5%) and biomass (94.2%). The superfamily Paguroidea (i.e. hermit crabs), together with undersized target individuals, were the most abundant taxa. The abundance and biomass of discards displayed significant maximum values in winter, which could be partly related to biotic factors including population dynamics of some dominant species. Multivariate analyses indicated the presence of different assemblages related to the targeted bivalve species, reflecting the transition between a fine surface-sands biocoenosis exposed to wave action and a well-sorted fine sands biocoenosis below 5 m depth. Analysis of biogeographical affinities showed that most discarded species (73.2%) have an extensive Atlantic range, whereas 7.1% have a restricted distribution within the Mediterranean. The presence of subtropical species highlights the uniqueness of this area (the Atlantic–Mediterranean transition) in European seas. The usefulness of discard analysis for biodiversity assessment is discussed.Postprin

SEDIGISM-ATLASGAL: Dense Gas Fraction and Star Formation Efficiency Across the Galactic Disk

By combining two surveys covering a large fraction of the molecular material in the Galactic disk we investigate the role the spiral arms play in the star formation process. We have matched clumps identified by ATLASGAL with their parental GMCs as identified by SEDIGISM, and use these giant molecular cloud (GMC) masses, the bolometric luminosities, and integrated clump masses obtained in a concurrent paper to estimate the dense gas fractions ($DGF_{gmc} = ∑M_{clump}/M_{gmc}$) and the instantaneous star forming efficiencies (i.e., $SFE_{gmc} = ∑L_{clump}/M_{gmc}$). We find that the molecular material associated with ATLASGAL clumps is concentrated in the spiral arms (∼60 per cent found within ±10 km s$^{−1}$ of an arm). We have searched for variations in the values of these physical parameters with respect to their proximity to the spiral arms, but find no evidence for any enhancement that might be attributable to the spiral arms. The combined results from a number of similar studies based on different surveys indicate that, while spiral-arm location plays a role in cloud formation and HI to H$_2$ conversion, the subsequent star formation processes appear to depend more on local environment effects. This leads us to conclude that the enhanced star formation activity seen towards the spiral arms is the result of source crowding rather than the consequence of a any physical process

Spatial rigid-multi-body systems with lubricated spherical clearance joints : modeling and simulation

The dynamic modeling and simulation of spatial rigid-multi-body systems with lubricated spherical joints is the main purpose of the present work. This issue is of paramount importance in the analysis and design of realistic multibody mechanical systems undergoing spatial motion. When the spherical clearance joint is modeled as dry contact; i.e., when there is no lubricant between the mechanical elements which constitute the joint, a body-to-body (typically metal-to-metal) contact takes place. The joint reaction forces in this case are evaluated through a Hertzian-based contact law. A hysteretic damping factor is included in the dry contact force model to account for the energy dissipation during the contact process. The presence of a fluid lubricant avoids the direct metal-to-metal contact. In this situation, the squeeze film action, due to the relative approaching motion between the mechanical joint elements, is considered utilizing the lubrication theory associated with the spherical bearings. In both cases, the intra-joint reaction forces are evaluated as functions of the geometrical, kinematical and physical characteristics of the spherical joint. These forces are then incorporated into a standard formulation of the system’s governing equations of motion as generalized external forces. A spatial four bar mechanism that includes a spherical clearance joint is considered here as example. The computational simulations are carried out with and without the fluid lubricant, and the results are compared with those obtained when the system is modeled with perfect joints only. From the general results it is observed that the system’s performance with lubricant effect presents fewer peaks in the kinematic and dynamic outputs, when compared with those from the dry contact joint model.Fundação para a Ciência e a Tecnologia (FCT