Multihierarchical electrodes based on titanate nanotubes and zinc oxide nanorods for photoelectrochemical water splitting

Studies involving water splitting to form hydrogen and oxygen have attracted attention because H2 is considered the fuel of the future. Photoelectrocatalysts have been widely used for this application, and several metal oxides can be applied as catalysts. Among them, we highlight zinc oxide nanorods (ZnONRs) and titanate nanotubes (TiNTs); however, their individual nanostructures exhibit disadvantages. For example, ZnONR shows rapid recombination of the photogenerated charges, and TiNT gives rise to randomly orientated films; these disadvantages limit their application as photoanodes. In this study, for the first time, we present a new class of multihierarchical electrodes based on TiNT-decorated ZnONR films that exhibited superior results to the individual species. The TiNTs are homogenously dispersed over the surface of the rods without forming agglomerates, giving rise to a heterojunction that exhibits lower recombination rates. It was found that the results are better when the contents of TiNT in the electrode are higher; thus, glycine was successfully used as a bridge to link both of the structures, increasing the amount of TiNT decorating the rods. As a result, the photocurrent generated with these multihierarchical electrodes is higher than that obtained for pure ZnONR electrodes (0.9 mA and 0.45 mA, respectively), and the electrode potentials for O2 evolution is lower than that observed for pure TiNT electrodes (0 V and 0.8 V vs. ERHE, respectively). The IPCE values are also higher for the multihierarchical electrodes

Arabidopsis in the wild—the effect of seasons on seed performance

Climate changes play a central role in the adaptive life histories of organisms all over the world. In higher plants, these changes may impact seed performance, both during seed development and after dispersal. To examine the plasticity of seed performance as a response to environmental fluctuations, eight genotypes known to be affected in seed dormancy and longevity were grown in the field in all seasons of two years. Soil and air temperature, day length, precipitation, and sun hours per day were monitored. We show that seed performance depends on the season. Seeds produced by plants grown in the summer, when the days began to shorten and the temperature started to decrease, were smaller with deeper dormancy and lower seed longevity compared to the other seasons when seeds were matured at higher temperature over longer days. The performance of seeds developed in the different seasons was compared to seeds produced in controlled conditions. This revealed that plants grown in a controlled environment produced larger seeds with lower dormancy than those grown in the field. All together the results show that the effect of the environment largely overrules the genetic effects, and especially, differences in seed dormancy caused by the different seasons were larger than the differences between the genotypes.</p

Airway wall extracellular matrix changes induced by bronchial thermoplasty in severe asthma

Background: Airway remodeling is a prominent feature of asthma, which involves increased airway smooth muscle mass and altered extracellular matrix composition. Bronchial thermoplasty (BT), a bronchoscopic treatment for severe asthma, targets airway remodeling.Objective: We sought to investigate the effect of BT on extracellular matrix composition and its association with clinical outcomes.Methods: This is a substudy of the TASMA trial. Thirty patients with severe asthma were BT-treated, of whom 13 patients were treated for 6 months with standard therapy (control group) before BT. Demographic data, clinical data including pulmonary function, and bronchial biopsies were collected. Biopsies at BT-treated and nontreated locations were analyzed by histological and immunohistochemical staining. Associations between histology and clinical outcomes were explored.Results: Six months after treatment, it was found that the reticular basement membrane thickness was reduced from 7.28 μm to 5.74 μm (21% relative reduction) and the percentage area of tissue positive for collagen increased from 26.3% to 29.8% (13% relative increase). Collagen structure analysis revealed a reduction in the curvature frequency of fibers. The percentage area positive for fibulin-1 and fibronectin increased by 2.5% and 5.9%, respectively (relative increase of 124% and 15%). No changes were found for elastin. The changes in collagen and fibulin-1 negatively associated with changes in FEV1 reversibility.Conclusions: Besides reduction of airway smooth muscle mass, BT has an impact on reticular basement membrane thickness and the extracellular matrix arrangement characterized by an increase in tissue area occupied by collagen with a less dense fiber organization. Both collagen and fibulin-1 are negatively associated with the change in FEV1 reversibility.</p

Physiological responses and production of 'Syrah' vines as a function of training systems

Plant architecture and its interaction with agricultural practices and environmental constraints is determinant for grapevine canopy structure, which is related to carbon assimilation, bud fertility and fruit quality. In this context, this study evaluated the performance of field-grown 'Syrah' grapevines conducted by two management systems: Vertical Shoot Position (VSP) or a modified Geneva Double Curtain (GDC), in Pirapora, state of Minas Gerais, Brazil, during the winters of 2007 and 2008. The evaluations of leaf area, water relations and net CO2 assimilation were made at the end of the ripening period. Yield per vine and per hectare were estimated and mean berry weight and diameter, total soluble solids, pH and titratable acidity were evaluated during berry ripening. The grapevines trained in VSP had higher water status as compared to GDC, shown by differences in pre-dawn leaf water potential (&#968;pd) and stem water potential (&#968;stem). However, the CO2 assimilation was similar in both training systems. Fruit exposure was higher in VSP than in GDC, which contributed to increasing berry temperature. At harvest, the berries in GDC reached values near to 23 ºBrix whereas berries in VSP showed values near 21 ºBrix

Evolution of the differential transverse momentum correlation function with centrality in Au+Au collisions at sNN=200\sqrt{s_{NN}} = 200 GeV

We present first measurements of the evolution of the differential transverse momentum correlation function, {\it C}, with collision centrality in Au+Au interactions at $\sqrt{s_{NN}} = 200$ GeV. {\it C} exhibits a strong dependence on collision centrality that is qualitatively similar to that of number correlations previously reported. We use the observed longitudinal broadening of the near-side peak of {\it C} with increasing centrality to estimate the ratio of the shear viscosity to entropy density, $\eta/s$, of the matter formed in central Au+Au interactions. We obtain an upper limit estimate of $\eta/s$ that suggests that the produced medium has a small viscosity per unit entropy.Comment: 7 pages, 4 figures, STAR paper published in Phys. Lett.

Longitudinal double-spin asymmetry and cross section for inclusive neutral pion production at midrapidity in polarized proton collisions at sqrt(s) = 200 GeV

We report a measurement of the longitudinal double-spin asymmetry A_LL and the differential cross section for inclusive Pi0 production at midrapidity in polarized proton collisions at sqrt(s) = 200 GeV. The cross section was measured over a transverse momentum range of 1 < p_T < 17 GeV/c and found to be in good agreement with a next-to-leading order perturbative QCD calculation. The longitudinal double-spin asymmetry was measured in the range of 3.7 < p_T < 11 GeV/c and excludes a maximal positive gluon polarization in the proton. The mean transverse momentum fraction of Pi0's in their parent jets was found to be around 0.7 for electromagnetically triggered events.Comment: 6 pages, 3 figures, submitted to Phys. Rev. D (RC

Measurement of the p-pbar -> Wgamma + X cross section at sqrt(s) = 1.96 TeV and WWgamma anomalous coupling limits

The WWgamma triple gauge boson coupling parameters are studied using p-pbar -> l nu gamma + X (l = e,mu) events at sqrt(s) = 1.96 TeV. The data were collected with the DO detector from an integrated luminosity of 162 pb^{-1} delivered by the Fermilab Tevatron Collider. The cross section times branching fraction for p-pbar -> W(gamma) + X -> l nu gamma + X with E_T^{gamma} > 8 GeV and Delta R_{l gamma} > 0.7 is 14.8 +/- 1.6 (stat) +/- 1.0 (syst) +/- 1.0 (lum) pb. The one-dimensional 95% confidence level limits on anomalous couplings are -0.88 < Delta kappa_{gamma} < 0.96 and -0.20 < lambda_{gamma} < 0.20.Comment: Submitted to Phys. Rev. D Rapid Communication