Revealing the Role of d Orbitals of Transition-Metal-Doped Titanium Oxide on High-Efficient Oxygen Reduction

Precise catalysis is critical for the high-quality catalysis industry. However, it remains challenging to fundamentally understand precise catalysis at the atomic orbital level. Herein, we propose a new strategy to unravel the role of specific d orbitals in catalysis. The oxygen reduction reaction (ORR) catalyzed by atomically dispersed Pt/Co-doped Ti$_{1−x}$O$_{2}$ nanosheets (Pt$_{1}$/Co$_{1}$–Ti$_{1−x}$O$_{2}$) is used as a model catalysis. The z-axis d orbitals of Pt/Co–Ti realms dominate the O$_{2}$ adsorption, thus triggering ORR. In light of orbital-resolved analysis, Pt$_{1}$/Co$_{1}$–Ti$_{1−x}$O$_{2}$ is experimentally fabricated, and the excellent ORR catalytic performance is further demonstrated. Further analysis reveals that the superior ORR performance of Pt$_{1}$–Ti$_{1−x}$O2 to Co$_{1}$–Ti$_{1−x}$O$_{2}$ is ascribed to stronger activation of Ti by Pt than Co via the d–d hybridization. Overall, this work provides a useful tool to understand the underlying catalytic mechanisms at the atomic orbital level and opens new opportunities for precise catalyst design

Where Brain, Body and World Collide

The production cross section of electrons from semileptonic decays of beauty hadrons was measured at mid-rapidity (|y| < 0.8) in the transverse momentum range 1 < pt < 8 Gev/c with the ALICE experiment at the CERN LHC in pp collisions at a center of mass energy sqrt{s} = 7 TeV using an integrated luminosity of 2.2 nb^{-1}. Electrons from beauty hadron decays were selected based on the displacement of the decay vertex from the collision vertex. A perturbative QCD calculation agrees with the measurement within uncertainties. The data were extrapolated to the full phase space to determine the total cross section for the production of beauty quark-antiquark pairs

Exclusive J/ψ\mathrm{J/}\psi photoproduction off protons in ultra-peripheral p-Pb collisions at sNN=5.02\sqrt{s_{\rm NN}}=5.02 TeV

We present the first measurement at the LHC of exclusive J/$\psi$ photoproduction off protons, in ultra-peripheral proton-lead collisions at $\sqrt{s_{\rm NN}}=5.02$ TeV. Events are selected with a dimuon pair produced either in the rapidity interval, in the laboratory frame, 2.5We present the first measurement at the LHC of exclusive J/ψ photoproduction off protons, in ultraperipheral proton-lead collisions at sNN=5.02  TeV. Events are selected with a dimuon pair produced either in the rapidity interval, in the laboratory frame, 2.5<y<4 (p-Pb) or -3.6<y<-2.6 (Pb-p), and no other particles observed in the ALICE acceptance. The measured cross sections σ(γ+p→J/ψ+p) are 33.2±2.2(stat)±3.2(syst)±0.7(theor)  nb in p-Pb and 284±36(stat)-32+27(syst)±26(theor)  nb in Pb-p collisions. We measure this process up to about 700 GeV in the γp center of mass, which is a factor of two larger than the highest energy studied at HERA. The data are consistent with a power law dependence of the J/ψ photoproduction cross section in γp energies from about 20 to 700 GeV, or equivalently, from Bjorken x scaling variable between ∼2×10-2 and ∼2×10-5, thus indicating no significant change in the gluon density behavior of the proton between HERA and LHC energies.We present the first measurement at the LHC of exclusive J/\psi$photoproduction off protons, in ultra-peripheral proton-lead collisions at$\sqrt{s_{\rm NN}}=5.02$TeV. Events are selected with a dimuon pair produced either in the rapidity interval, in the laboratory frame,$2.5<y<4$(p-Pb) or$-3.6<y<-2.6$(Pb--p), and no other particles observed in the ALICE acceptance. The measured cross sections$\sigma (\gamma + {\rm p} \rightarrow J/\psi + {\rm p})$are 33.2$\pm$2.2 (stat)$\pm$3.1 (syst)$\pm$0.7 (theo) nb in p-Pb and 284$\pm$36 (stat)$^{+27}_{-32}$(syst)$\pm$26 (theo) nb in Pb-p collisions. We measure this process up to about 700 GeV in the$\gamma {\rm p}$centre-of-mass, which is a factor of two larger than the highest energy studied at HERA. The data are consistent with a power law dependence of the$J/\psi$photoproduction cross section in$\gamma {\rm p}$energies from about 20 to 700 GeV, or equivalently, from Bjorken-$x$between$\sim 2\times 10^{-2}$to$\sim 2\times 10^{-5}$, thus indicating no significant change in the gluon density behaviour of the proton between HERA and LHC energies

Production of inclusive ϒ(1S) and ϒ(2S) in p–Pb collisions at sNN=5.02\sqrt{s_{\rm NN}} = 5.02 TeV

We report on the production of inclusive ϒ (1S) and ϒ (2S) in p–Pb collisions at sNN=5.02 TeV at the LHC. The measurement is performed with the ALICE detector at backward ( −4.46<ycms<−2.96 ) and forward ( 2.03<ycms<3.53 ) rapidity down to zero transverse momentum. The production cross sections of the ϒ (1S) and ϒ (2S) are presented, as well as the nuclear modification factor and the ratio of the forward to backward yields of ϒ (1S). A suppression of the inclusive ϒ (1S) yield in p–Pb collisions with respect to the yield from pp collisions scaled by the number of binary nucleon–nucleon collisions is observed at forward rapidity but not at backward rapidity. The results are compared to theoretical model calculations including nuclear shadowing or partonic energy loss effects

Multiplicity dependence of jet-like two-particle correlations in p-Pb collisions at sNN\sqrt{s_NN} = 5.02 TeV with ALICE at LHC

Two-particle angular correlations between unidentified charged trigger and associated particles are measured by the ALICE detector in p–Pb collisions at a nucleon–nucleon centre-of-mass energy of 5.02 TeV. The transverse-momentum range 0.7 < $p_{T,assoc} < p_{T,trig}$ < 5.0 GeV/c is examined, to include correlations induced by jets originating from low momentum-transfer scatterings (minijets). The correlations expressed as associated yield per trigger particle are obtained in the pseudorapidity range |η| < 0.9. The near-side long-range pseudorapidity correlations observed in high-multiplicity p–Pb collisions are subtracted from both near-side short-range and away-side correlations in order to remove the non- jet-like components. The yields in the jet-like peaks are found to be invariant with event multiplicity with the exception of events with low multiplicity. This invariance is consistent with the particles being produced via the incoherent fragmentation of multiple parton–parton scatterings, while the yield related to the previously observed ridge structures is not jet-related. The number of uncorrelated sources of particle production is found to increase linearly with multiplicity, suggesting no saturation of the number of multi-parton interactions even in the highest multiplicity p–Pb collisions. Further, the number scales in the intermediate multiplicity region with the number of binary nucleon–nucleon collisions estimated with a Glauber Monte-Carlo simulation.Two-particle angular correlations between unidentified charged trigger and associated particles are measured by the ALICE detector in p–Pb collisions at a nucleon–nucleon centre-of-mass energy of 5.02 TeV. The transverse-momentum range 0.7<pT,assoc<pT,trig<5.0 GeV/c is examined, to include correlations induced by jets originating from low momentum-transfer scatterings (minijets). The correlations expressed as associated yield per trigger particle are obtained in the pseudorapidity range |η|<0.9 . The near-side long-range pseudorapidity correlations observed in high-multiplicity p–Pb collisions are subtracted from both near-side short-range and away-side correlations in order to remove the non-jet-like components. The yields in the jet-like peaks are found to be invariant with event multiplicity with the exception of events with low multiplicity. This invariance is consistent with the particles being produced via the incoherent fragmentation of multiple parton–parton scatterings, while the yield related to the previously observed ridge structures is not jet-related. The number of uncorrelated sources of particle production is found to increase linearly with multiplicity, suggesting no saturation of the number of multi-parton interactions even in the highest multiplicity p–Pb collisions. Further, the number scales only in the intermediate multiplicity region with the number of binary nucleon–nucleon collisions estimated with a Glauber Monte-Carlo simulation.Two-particle angular correlations between unidentified charged trigger and associated particles are measured by the ALICE detector in p-Pb collisions at a nucleon-nucleon centre-of-mass energy of 5.02 TeV. The transverse-momentum range 0.7 $< p_{\rm{T}, assoc} < p_{\rm{T}, trig} <$ 5.0 GeV/$c$ is examined, to include correlations induced by jets originating from low momen\-tum-transfer scatterings (minijets). The correlations expressed as associated yield per trigger particle are obtained in the pseudorapidity range $|\eta|<0.9$. The near-side long-range pseudorapidity correlations observed in high-multiplicity p-Pb collisions are subtracted from both near-side short-range and away-side correlations in order to remove the non-jet-like components. The yields in the jet-like peaks are found to be invariant with event multiplicity with the exception of events with low multiplicity. This invariance is consistent with the particles being produced via the incoherent fragmentation of multiple parton--parton scatterings, while the yield related to the previously observed ridge structures is not jet-related. The number of uncorrelated sources of particle production is found to increase linearly with multiplicity, suggesting no saturation of the number of multi-parton interactions even in the highest multiplicity p-Pb collisions. Further, the number scales in the intermediate multiplicity region with the number of binary nucleon-nucleon collisions estimated with a Glauber Monte-Carlo simulation

Elliptic flow of identified hadrons in Pb-Pb collisions at sNN\sqrt{s_{\rm{NN}}} = 2.76 TeV

The elliptic flow coefficient ($v_{2}$) of identified particles in Pb--Pb collisions at $\sqrt{s_\mathrm{{NN}}} = 2.76$ TeV was measured with the ALICE detector at the LHC. The results were obtained with the Scalar Product method, a two-particle correlation technique, using a pseudo-rapidity gap of $|\Delta\eta| > 0.9$ between the identified hadron under study and the reference particles. The $v_2$ is reported for $\pi^{\pm}$, $\mathrm{K}^{\pm}$, $\mathrm{K}^0_\mathrm{S}$, p+$\overline{\mathrm{p}}$, $\mathrm{\phi}$, $\Lambda$+$\overline{\mathrm{\Lambda}}$, $\Xi^-$+$\overline{\Xi}^+$ and $\Omega^-$+$\overline{\Omega}^+$ in several collision centralities. In the low transverse momentum ($p_{\mathrm{T}}$) region, $p_{\mathrm{T}} 3$GeV/$c$.The elliptic flow coefficient (v$_{2}$) of identified particles in Pb-Pb collisions at $\sqrt{s_{\mathrm{NN}}}=2.76$ TeV was measured with the ALICE detector at the Large Hadron Collider (LHC). The results were obtained with the Scalar Product method, a two-particle correlation technique, using a pseudo-rapidity gap of |Δη| > 0.9 between the identified hadron under study and the reference particles. The v$_{2}$ is reported for π$^{±}$, K$^{±}$, K$_{S}^{0}$ , $\mathrm{p}+\overline{\mathrm{p}}$ , ϕ, $\Lambda +\overline{\Lambda}$ , ${\Xi}^{-}+{\overline{\Xi}}^{+}$ and ${\Omega}^{-}+{\overline{\Omega}}^{+}$ in several collision centralities. In the low transverse momentum (p$_{T}$) region, p$_{T}$ 3 GeV/c.The elliptic flow coefficient ($v_{2}$) of identified particles in Pb-Pb collisions at $\sqrt{s_\mathrm{{NN}}} = 2.76$ TeV was measured with the ALICE detector at the LHC. The results were obtained with the Scalar Product method, a two-particle correlation technique, using a pseudo-rapidity gap of $|\Delta\eta| > 0.9$ between the identified hadron under study and the reference particles. The $v_2$ is reported for $\pi^{\pm}$, $\mathrm{K}^{\pm}$, $\mathrm{K}^0_\mathrm{S}$, p+$\overline{\mathrm{p}}$, $\mathrm{\phi}$, $\Lambda$+$\overline{\mathrm{\Lambda}}$, $\Xi^-$+$\overline{\Xi}^+$ and $\Omega^-$+$\overline{\Omega}^+$ in several collision centralities. In the low transverse momentum ($p_{\mathrm{T}}$) region, $p_{\mathrm{T}} 3$GeV/$c$

Event-by-event mean pT{p}_{\mathbf {T}} fluctuations in pp and Pb-Pb collisions at the LHC

Event-by-event fluctuations of the mean transverse momentum of charged particles produced in pp collisions at √s = 0.9, 2.76 and 7 TeV, and Pb–Pb collisions at √sNN = 2.76 TeV are studied as a function of the charged-particle multiplicity using the ALICE detector at the LHC. Non-statistical fluctuations are observed in all systems. The results in pp collisions show little dependence on collision energy. The Monte Carlo event generators PYTHIA and PHOJET are in qualitative agreement with the data. Peripheral Pb–Pb data exhibit a similar multiplicity dependence as that observed in pp. In central Pb–Pb, the results deviate from this trend, featuring a significant reduction of the fluctuation strength. The results in Pb–Pb are in qualitative agreement with previous measurements in Au–Au at lower collision energies and with expectations from models that incorporate collective phenomena.Event-by-event fluctuations of the mean transverse momentum of charged particles produced in pp collisions at $\sqrt{s}$ = 0.9, 2.76 and 7 TeV, and Pb–Pb collisions at $\sqrt{s_\mathrm{NN}}$   = 2.76 TeV are studied as a function of the charged-particle multiplicity using the ALICE detector at the LHC. Dynamical fluctuations indicative of correlated particle emission are observed in all systems. The results in pp collisions show little dependence on collision energy. The Monte Carlo event generators PYTHIA and PHOJET are in qualitative agreement with the data. Peripheral Pb–Pb data exhibit a similar multiplicity dependence as that observed in pp. In central Pb–Pb, the results deviate from this trend, featuring a significant reduction of the fluctuation strength. The results in Pb–Pb are in qualitative agreement with previous measurements in Au–Au at lower collision energies and with expectations from models that incorporate collective phenomena.Event-by-event fluctuations of the mean transverse momentum of charged particles produced in pp collisions at $\sqrt{s}$ = 0.9, 2.76 and 7 TeV, and Pb-Pb collisions at $\sqrt{s_{NN}}$ = 2.76 TeV are studied as a function of the charged-particle multiplicity using the ALICE detector at the LHC. Dynamical fluctuations indicative of correlated particle emission are observed in all systems. The results in pp collisions show little dependence on collision energy. The Monte Carlo event generators PYTHIA and PHOJET are in qualitative agreement with the data. Peripheral Pb-Pb data exhibit a similar multiplicity dependence as that observed in pp. In central Pb-Pb, the results deviate from this trend, featuring a significant reduction of the fluctuation strength. The results in Pb--Pb are in qualitative agreement with previous measurements in Au-Au at lower collision energies and with expectations from models that incorporate collective phenomena