Experimental analysis of enhanced cement-sand-based geothermal grouting materials

Nowadays, Ground Source Heat Pumps (GSHP) are achieving significant efficiencies, mostly because of the development of their electromechanical components. However, concepts such as the technical performance of the grouting materials deserve more profound analysis, as becoming essential in areas where good potential thermal performance of the GSHP and serious risks of groundwater contamination exist. In this paper, several fluid mortars with enhanced characteristics have been evaluated. Results show improved mechanical and thermal properties compared to conventional grouting materials. Likewise, mortars exhibited good performance after being subjected to durability treatment. For now, the cost of some mortars may constitute a barrier.This work is based on the project with reference BIA2013-40917-R. This project was financed by the Ministry of Economy and Competitiveness through the State General Budget and the European Regional Development Fund (FEDER)

Nanostructures in hydrogen peroxide sensing

In recent years, several devices have been developed for the direct measurement of hydrogen peroxide (H2O2 ), a key compound in biological processes and an important chemical reagent in industrial applications. Classical enzymatic biosensors for H2O2 have been recently outclassed by electrochemical sensors that take advantage of material properties in the nano range. Electrodes with metal nanoparticles (NPs) such as Pt, Au, Pd and Ag have been widely used, often in combination with organic and inorganic molecules to improve the sensing capabilities. In this review, we present an overview of nanomaterials, molecules, polymers, and transduction methods used in the optimization of electrochemical sensors for H2O2 sensing. The different devices are compared on the basis of the sensitivity values, the limit of detection (LOD) and the linear range of application reported in the literature. The review aims to provide an overview of the advantages associated with different nanostructures to assess which one best suits a target application.Fil: Trujillo, Ricardo Matias. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto Superior de Investigaciones Biológicas. Universidad Nacional de Tucumán. Instituto Superior de Investigaciones Biológicas; Argentina. Universidad Nacional de Tucumán. Facultad de Ciencias Exactas y Tecnología. Departamento de Bioingeniería. Laboratorio de Medios e Interfases; ArgentinaFil: Barraza, Daniela Estefanía. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto Superior de Investigaciones Biológicas. Universidad Nacional de Tucumán. Instituto Superior de Investigaciones Biológicas; Argentina. Universidad Nacional de Tucumán. Facultad de Ciencias Exactas y Tecnología. Departamento de Bioingeniería. Laboratorio de Medios e Interfases; ArgentinaFil: Zamora, Martín Lucas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto Superior de Investigaciones Biológicas. Universidad Nacional de Tucumán. Instituto Superior de Investigaciones Biológicas; Argentina. Universidad Nacional de Tucumán. Facultad de Ciencias Exactas y Tecnología. Departamento de Bioingeniería. Laboratorio de Medios e Interfases; ArgentinaFil: Cattani Scholz, Anna. Universitat Technical Zu Munich; AlemaniaFil: Madrid, Rossana Elena. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto Superior de Investigaciones Biológicas. Universidad Nacional de Tucumán. Instituto Superior de Investigaciones Biológicas; Argentina. Universidad Nacional de Tucumán. Facultad de Ciencias Exactas y Tecnología. Departamento de Bioingeniería. Laboratorio de Medios e Interfases; Argentin

Durability of geothermal grouting materials considering extreme loads

The concern about the massive use of the non-renewable and very limited fossil fuels together with the well-known effects of the global warming makes it more necessary the efficient use of the current forms of renewable energy generation. Because of the crucial role played by the grouting materials in the Ground Source Heat Pumps (GSHP), a proper selection of these elements should be made based on a deep knowledge of their performance. In this paper, thermal conductivity, mechanical strength and grout-pipe permeability of four different highly workable grouts have been tested before and after they were subjected to wet-dry and freeze-thaw durability treatments. Results obtained demonstrated the harmful effects of using a large amount of mixing water in grouts subjected to those extreme loads. However, the use of these type of grouts with very good workability is still possible in GSHP installations with balanced thermal designs provided that regular operational and environment conditions are considered.The authors wish to express their gratitude to the Ministry of Economy and Competitiveness which funded this study within the Spanish National Plan for Scientific and Technical Research and Innovation (INNPACTO program) through the research project IPT-2011-0877-920000. The authors are also grateful to all the organizations and companies participating in this project: Sacyr Industrial, Universidad Politécnica de Madrid and Cype

Influence of early colour degradation of asphalt pavements on their thermal behaviour

Environmental goals such as the reduction of fossil fuel consumption or greenhouse gas (GHG) emissions through the development of new renewable energy sources have led to the emergence of the so called asphalt solar collectors. Moreover, in recent years, engineers are devoting increased interest to the effect of the thermal loads on the mechanical behaviour of pavements. Several approaches to these topics can be found in the literature. However, a study of the influence of the colour degradation suffered by pavements on their thermal behaviour is still necessary since both the efficient application of the asphalt collectors and the proper study of the effect of the solar radiation on the asphalt pavement behaviour are directly affected by the loss of colour occurring as time goes by. Therefore, the thermal behaviour of two different asphalt mixes was studied before and after being subjected to a colour degradation process. The degradation of five different asphalt mixes was studied and the results were compared to those obtained in the access roads to seven low volume car parks. The final results show that there are large differences between the two asphalt mixes with different gradations and densities. The importance attributed by other authors to conductivity was also confirmed. Furthermore, the results showed that it was possible to simulate the early colour degradation suffered by a low volume road. Finally, a slight reduction in temperature and energy collection capacity was measured after the colour degradation process

Test methods and influential factors for analysis of bonding between bituminous pavement layers

The durability and maintenance of pavements depend on several factors. One of the most influential is the bond between layers. This bond is responsible for ensuring all layers behave as a single entity, reducing cracks and deformation of the pavement. Several methods, developed by different authors over the past 30 years, to measure bonding between layers are analyzed in this paper. Different research lines are discussed, concluding that the most influential variables are: tack coat type, dosage, mixture type, surface characteristics, temperature, and emulsion breaking time. In order to reach the highest bond strength values, the following factors should be considered: high values of surface macro-texture, low temperatures, the use of heat-adhesive emulsion, a dosage from 300 to 450 g/m2 of residual bitumen and the compaction after emulsion break. Moreover, a non-destructive test method to assess tack coat dosage on site is proposed

Development of an estimative model for the optimal tack coat dosage based on aggregate gradation of hot mix asphalt pavements

In this work the performance of tack coats on asphalt pavement layers is analysed. Adjustment models based on experimental measurements were implemented, relating surface layer macro-texture and aggregate content larger than 8 mm. The best fits were obtained with a Gompertz model, which follows the expected physical macro-texture changes outside the test range. Shear strength was analysed, through prediction curves of each evaluated tack coat dosage, with an optimum tack coat performance for aggregate contents larger than 8 mm between 45% and 50%, and no relevant influence of the tack coat dosage used.The authors would like to acknowledge the support provided by the Technologic Research Construction Group (GITECO) and the Group of Roads of Santander at Cantabria University for the development of tests and samples. We would also like to thank the company Emilio Bolado S.L. and the Society for the Development of Cantabria Region (SODERCAN) for the material provided, and the DID Research Department from the Austral University of Chile for the support

Marine biodiversity baseline for Área de Conservación Guanacaste, Costa Rica: published records

The diversity of tropical marine organisms has not been studied as intensively as the terrestrial biota worldwide. Additionally, marine biodiversity research in the tropics lags behind other regions. The 43,000 ha Sector Marino of Área de Conservación Guanacaste (ACG, Marine Sector of Guanacaste Conservation Area), on the North Pacific coast of Costa Rica is no exception. For more than four decades, the terrestrial flora and fauna has been studied continuously. The ACG marine biodiversity was studied in the 1930’s by expeditions that passed through the area, but not much until the 1990’s, except for the marine turtles. In the mid 1990’s the Center for Research in Marine Science and Limnology (CIMAR) of the Universidad de Costa Rica (UCR) initiated the exploration of the marine environments and organisms of ACG. In 2015, ACG, in collaboration with CIMAR, started the BioMar project whose goal is to inventory the species of the marine sector of ACG (BioMar ACG project). As a baseline, here I have compiled the published records of marine ACG species, and found that 594 marine species have been reported, representing 15.5% of the known species of the Pacific coast of Costa Rica. The most diverse groups were the crustaceans, mollusks and cnidarians comprising 71.7% of the ACG species. Some taxa, such as mangroves and fish parasites are well represented in ACG when compared to the rest of the Costa Rican coast but others appear to be greatly underrepresented, for example, red algae, polychaetes, copepods, equinoderms, and marine fishes and birds, which could be due to sampling bias. Thirty species have been originally described with specimens from ACG, and 89 species are not known from other localities on the Pacific coast of Costa Rica except ACG. Most of the sampling has been concentrated in a few localities in Sector Marino, Playa Blanca and Islas Murciélago, and in the nearby waters of Bahía Santa Elena. In an effort to fill this gap, CIMAR is collaborating with ACG and a private foundation to start an inventory of the marine organisms of the conservation area. The project will be assisted by two marine parataxonomists, and all samples will be catalogued, photographed, bar coded and voucher specimens deposited at the Museo de Zoología, UCR. All the information will be available through Internet. It is anticipated that the BioMar project will fill many of the knowledge gaps and significantly more marine species will be encountered. This project could become a viable model for marine biodiversity inventories in other Costa Rican Conservation Areas (Áreas de Conservación) and in other countries.UCR::Vicerrectoría de Investigación::Unidades de Investigación::Ciencias Básicas::Centro de Investigación en Ciencias del Mar y Limnología (CIMAR

Memoria del II Coloquio Internacional sobre Diversidad Cultural y Estudios Regionales

Desde la Sede de Occidente y, específicamente, en el seno de la Coordinación de Investigación y con el apoyo de la Dirección de la Sede y las Coordinaciones de Docencia, Administración y Acción Social, así como de la Vicerrectoría de Investigación, se han celebrado en el 2011 y en el 2012 dos coloquios internacionales sobre diversidad cultural y estudios regionales. El propósito de ambos consistió principalmente en motivar a investigadores e investigadoras de las distintas unidades académicas de la Universidad de Costa Rica y de otras instituciones de Educación Superior, así como a representantes de Centros e Institutos de Investigación nacionales e internacionales, a presentar resultados de investigaciones que contribuyeran a un mayor conocimiento de los procesos culturales y que dieran a conocer resultados que permitieran la comprensión de las realidades de distintos sectores y regiones. En el 2011 se presentaron cuarenta y seis ponencias y se dictaron tres conferencias magistrales, y en el 2012 se expusieron cincuenta ponencias y se impartieron tres conferencias magistrales.UCR::Sedes Regionales::Sede de Occidente::Recinto San Ramón::Centro de Investigaciones sobre Diversidad Cultural y Estudios Regionales (CIDICER

Development of a procedure for the optimisation of a flexible pavement behaviour by means of a geosynthetics as anti-reflective cracking element

RESUMEN: En el presente trabajo se ha desarrollado un procedimiento, basado en dos ensayos de laboratorio, que facilita la selección del geosintético y la dotación de ligante más adecuada para optimizar la adherencia y durabilidad frente al avance de una grieta refleja. Además, se ha investigado el deterioro que pueden sufrir estos materiales por efecto de la temperatura al estar en contacto con una mezcla bituminosa. El ensayo de adherencia es de tipo estático y determina la tensión cortante necesaria para desplazar, en un sistema tricapa, la probeta central con respecto a las exteriores. Este ensayo es sensible al tipo de geosintético utilizado, a la variación del contenido de ligante aplicado a cada geosintético, al tipo de betún residual utilizado y al procedimiento de fabricación de las probetas. El ensayo antirremonte de fisuras es de tipo dinámico, se aplica a una probeta bicapa en la que se ha inducido una prefisura en la cara inferior. Este ensayo ha permitido evaluar la incidencia en la durabilidad de diferentes tipos de geosintético; además, permite establecer los contenidos óptimos de ligante para obtener una mayor durabilidad del sistema.ABSTRACT: This thesis has developed a procedure, based on two lab tests, that helps to select the geosynthetics and the optimal binder percentage more suitable to optimize adherence and durability in front of a reflect crack. Besides, the failure is studied that these materials may suffer as a consequence of temperature when in contact with a hot-mix asphalt. The Bond-test is static and determines the shear stress necessary to move, in a three-layer system, the central specimen in relation to the exterior ones. This test has demonstrated through statistical analysis that is sensitive to the geosynthetic employed, to the variation of binder content applied to each geosynthetic, the kind of asphalt residue used and the procedure to manufacture specimens. The anti-reflective cracking test is dynamic, applied on a two-layer specimen, where a crack has been induced in the lower side. This test has helped to assess the influence on durability on different kinds of geosynthetics; moreover, helps to establish the optimum binder contents to obtain the system highest durability

ANÁLISIS TÉRMICO DE GEOSINTÉTICOS UTILIZADOS EN LA REHABILITACIÓN DE PAVIMENTOS THERMAL ANALYSIS OF GEOSYNTHETICS USED IN THE REHABILITATION OF PAVEMENTS

El crecimiento de la utilización de los geosintéticos en la rehabilitación de pavimentos flexibles se ha visto incrementado de forma considerable desde la década de los años setenta. Estos materiales presentan una serie de ventajas que motivan su gran demanda en la actualidad. La utilización de geosintéticos en la rehabilitación se basa en su capacidad de resistir deformaciones, atenuando las fisuras y grietas que pudiesen presentar los pavimentos flexibles. Se han realizado dos experiencias en laboratorio para simular el proceso de puesta en obra de los geosintéticos en la zona de intercapa. El procedimiento consiste en verter sobre el geosintético extendido, una capa de mezcla bituminosa en caliente comprendida entre 135 - 165 ºC. El análisis térmico de los resultados obtenidos avala significativamente al material poliéster (PS), con respecto al polipropileno (PP), en futuras aplicaciones de rehabilitación de pavimentos flexibles.<br>The use of geosynthetics in rehabilitating flexible pavements has substantially expanded since the mid-seventies. These materials have a number of advantages that motivate their demand at present. The use of geosynthetics in rehabilitation is based on its ability to resist deformation, attenuating fissures and cracks that flexible pavements could present. Two experiments have been done to simulate the process of placing the geosynthetics in the interlayer area. The process consists of pouring on the spread geosynthetics a layer of hot bituminous mix between 135-165 °C. The thermal analysis of the results shows a significant performance of polyester (PS), compared to polypropylene (PP), in future applications for the rehabilitation of flexible pavements