Electrochemical Impedance Spectroscopic Studies of the First Lithiation of Si/C Composite Electrode

The Si/C composite materials were prepared by ball milling method, and characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The result displayed that Si in the Si/C composite materials still maintained a good crystal structure and uniformly dispersed in carbon black matrix. The first discharge capacity was 3393 mAh/g, and 4 cycles later still retained 1000 mAh/g, showing better charge-discharge cycle performance. Electrochemical impedance spectroscopy test indicated that there appeare three semicircles respectively representing the impedance of contact problems, solid electrolyte interface film (SEI film), charge transfer and phase transformation in the first lithiation, and their evolutive principles were also investigated

A comparative photocatalytic study of TiO2 loaded on three natural clays with different morphologies

[EN] In this work, a sol-gel method was used to load TiO2 nanoparticles on three clays (kaolinite, halloysite and palygorskite) with different morphologies (plates, tubes, and rods with micro tunnels), and then the photocatalytic performance of obtained clay-TiO2 composites for degradation of methyl orange was comparatively investigated. The results surprisingly show that the trend of photocatalytic performance of composites is opposite to that of special surface area of corresponding clays. By concentrated analysis of the loading status of TiO2, the lowest photocatalytic efficiency of palygorskite-TiO2 composite is mainly ascribed to (1) the aggregation of TiO2 nanoparticles on Pal surface, not the amount of TiO2 and (2) the relatively weak adsorption of Pal to methyl orange. The additional adsorption of hydroxyl surface of Kaol to methyl orange and little TiO2 in the lumen of Hal tube leads to the better photocatalytic performance of kaolinite-TiO2 composite than halloysite-TiO2 composite. Finally, kaolinite is proved to be an excellent carrier to support nano TiO2 resulting in a good photocatalytic performance and cycle stability, and the study can provide a direct guidance to select appropriate clay-photocatalyst composites for different practical applications.This work is supported by the National Natural Science Foundation of China (41502032) and the Fundamental Research Funds for the Central Universities (2019XKQYMS76).Wu, A.; Wang, D.; Wei, C.; Zhang, X.; Liu, Z.; Feng, P.; Ou, X.... (2019). A comparative photocatalytic study of TiO2 loaded on three natural clays with different morphologies. Applied Clay Science. 183:1-12. https://doi.org/10.1016/j.clay.2019.105352S11218

Sol–gel synthesis of TiO2-modified nanocomposite coatings on titanium

Titanium dioxide nanoparticles-modified nanocomposite coatings were synthesized on titanium by sol–gel process. The specimens were studied by differential scanning calorimetry, transmission electron microscopy, field-emission scanning electron microscopy and bonding tests. TEM results showed that TiO2 nanoparticles were adhered and enwrapped in the hybrid sol matrixes to form aggregates of TiO2 nanoparticles. The size of the particle aggregates increased from about 160\ua0nm to above 500\ua0nm with the content of the TiO2 particles increasing from 45 to 60\ua0ma%. At the same time, the quantities of the microcracks on the coating surface gradually decreased. The solid phase content of the sols was increased by the addition of TiO2 nanoparticles, which avoided the formation of microcracks on the coatings surface. Compared to the uncoated group, the highest bonding strength improvement of about 24\ua0% was obtained at the TiO2 content of 60 ma%. Graphical Abstract: [Figure not available: see fulltext.

Optimal Inflow Performance Relationship Equation for Horizontal and Deviated Wells in Low-Permeability Reservoirs

After Vogel proposed a dimensionless inflow performance equation, with the rise of the horizontal well production mode, a large number of inflow performance relationship (IPR) equations have emerged. In the productivity analysis of deviated and horizontal wells, the IPR equation proposed by Cheng is mainly used. However, it is still unclear whether these inflow performance models (such as the Cheng, Klins-Majcher, Bendakhlia-Aziz, and Wiggins-Russell-Jennings types) are suitable for productivity evaluations of horizontal and deviated wells in low-permeability reservoirs. In-depth comparisons and analyses have not been carried out, which hinders improvements in the accuracy of the productivity evaluations of horizontal wells in low-permeability reservoirs. In this study, exploratory work was conducted in two areas. First, the linear flow function relationship used in previous studies was improved. Based on the experimental pressure-volume-temperature results, a power exponential flow function model was established according to different intervals greater or less than the bubble point pressure, which was introduced into the subsequent derivation of the inflow performance equation. Second, given the particularity of low-permeability reservoir percolation, considering that the reservoir is a deformation medium, and because of the existence of a threshold pressure gradient in fluid flow, the relationship between permeability and pressure was changed. The starting pressure gradient was introduced into the subsequent establishment of the inflow performance equation. Based on the above two aspects of this work, the dimensionless IPR of single-phase and oil-gas two-phase horizontal wells in a deformed medium reservoir was established by using the equivalent seepage resistance method and complex potential superposition principle. Furthermore, through regression and error analyses of the standard inflow performance data, the correlation coefficients and error distributions of six types of IPR equations applicable to deviated and horizontal wells at different inclination angles were compared. The results show that the IPR equation established in this study features good stability and accuracy and that it can fully reflect the particularity of low-permeability reservoir seepage. It provides the best choice of the IPR between inclined wells and horizontal wells in low-permeability reservoirs. The other types of IPR equations are the Wiggins-Russell-Jennings, Klins-Majcher, Vogel, Fetkovich, Bendakhlia-Aziz, and Harrison equations, listed here in order from good to poor in accuracy

Effect of laser parameters on the microstructure of bonding porcelain layer fused on titanium

Bonding porcelain layer was fused on Ti surface by laser cladding process using a 400 W pulse CO laser. The specimens were studied by field-emission scanning electron microscopy, X-ray diffraction and bonding tests. During the laser fusion process, the porcelain powders were heated by laser energy and melted on Ti to form a chemical bond with the substrate. When the laser scanning speed decreased, the sintering temperature and the extent of the oxidation of Ti surface increased accordingly. When the laser scanning speed is 12.5 mm/s, the bonding porcelain layers were still incomplete sintered and there were some micro-cracks in the porcelain. When the laser scanning speed decreased to 7.5 mm/s, vitrified bonding porcelain layers with few pores were synthesized on Ti

Modification of exploration of long‐term nutrient trajectories for nitrogen (ELEMeNT-N) model to quantify legacy nitrogen dynamics in a typical watershed of eastern China

Legacy nitrogen (N) is recognized as a primary cause for the apparent failure of watershed N management strategies to achieve desired water quality goals. The ELEMeNT-N (exploration of long‐term nutrient trajectories for nitrogen) model, a parsimonious and process-based model, has the potential to effectively distinguish biogeochemical and hydrological legacy effects. However, ELEMeNT-N is limited in its ability to address long-term legacy N dynamics as it ignores temporal changes in soil organic N (SON) mineralization rates. This work represents the first use and modification of ELEMeNT-N to quantify legacy effects and capture spatial heterogeneity of legacy N accumulation in China. An exponential function based on mean annual temperature was employed to estimate yearly changes in SON mineralization rate. Based on a 31 year water quality record (1980–2010), the modified model achieved higher efficiency metrics for riverine N flux in the Yongan watershed in eastern China than the original model (Nash–Sutcliff coefficient: 0.87 vs. 0.72 and R ^2 : 0.80 vs. 0.71). The modified ELEMeNT-N results suggested that the riverine N flux mainly originated from the legacy N pool (88.2%). The mean overall N lag time was 11.9 years (95% confidence intervals (CIs): 8.3–21.3), of which biogeochemical lag time was 9.7 years (6.3–18.4) and hydrological lag time was 2.2 years (2.0–3.0). Legacy N accumulation showed considerable spatial heterogeneity, with 219–239 kg N ha ^−1 accumulated in soil and 143–188 kg N ha ^−1 accumulated in groundwater. The ELEMeNT-N model was an effective tool for addressing legacy N dynamics, and the modified form proposed here enhanced its ability to capture SON mineralization dynamics, thereby providing managers with critical information to optimize watershed N pollution control strategies

Surface modifications and Nano-composite coatings to improve the bonding strength of titanium-porcelain

Surface modifications of Ti and nano-composite coatings were employed to simultaneously improve the surface roughness, corrosion resistance and chemical bonding between porclain-Ti. The specimens were studied by field-emission scanning electron microscopy, surface roughness, differential scanning calorimetry, Fourier transform infrared spectroscopy, corrosion resistance and bonding strength tests. The SEM results showed that hybrid structures with micro-stripes, nano-pores and nano-protuberances were prepared by surface modification of Ti, which significantly enhanced the surface roughness and corrosion resistance of Ti. Porous nano-composite coatings were synthesized on Ti anodized with pre-treatment in 40% HF acid. TiO nanoparticles were added into the hybrid coating to increase the solid phase content of the sols and avoid the formation of microcracks. With the TiO content increasing from 45 wt% to 60 wt%, the quantities of the microcracks on the coating surface gradually decreased. The optimal TiO content for the nanocomposite coatings is 60 wt% in this research. Compared to the uncoated group, the bonding strength of the coated groups showed a bonding strength improvement of 23.96%. The cytotoxicity of the 4# coating group was ranked as zero, which corresponds to non-cytotoxicity

Long-Term (1990–2013) Changes and Spatial Variations of Cropland Runoff across China

Quantitative information on regional cropland runoff is important for sustainable agricultural water quantity and quality management. This study combined the Soil Conservation Service Curve Number (SCS-CN) method and geostatistical approaches to quantify long-term (1990–2013) changes and regional spatial variations of cropland runoff in China. Estimated CN values from 17 cropland study sites across China showed reasonable agreement with default values from the National Engineering Handbook (R2 = 0.76, n = 17). Among four commonly used geostatistical interpolation methods, the inverse distance weighting (IDW) method achieved the highest accuracy (R2 = 0.67, n = 209) for prediction of cropland runoff. Using default CN values and the IDW method, estimated national annual cropland runoff volume and runoff depth in 1990–2013 were 253 ± 25 km3 yr−1 and 182 ± 15 mm yr−1, respectively. Estimated cropland runoff depth gradually increased from the drier northwest inland region to the wetter southeast coastal region (range: 2–1375 mm yr−1). Regionally, eastern, central and southern China accounted for 39% of the cultivated area and 53% of the irrigated land area and contributed to 68% of the national cropland runoff volume. In contrast, northwestern, northern, southwestern and northeastern China accounted for 61% of the cultivated area and 47% of the irrigated land area and contributed to 32% of the runoff volume. Rainfall was the main source (72%) of cropland runoff for the entire nation, while irrigation became the main source of cropland runoff in drier regions (northwestern and southwestern China). Over the 24-year study period, estimated cropland runoff depth showed no significant trends, whereas cropland runoff volume and irrigation-contributed percentages decreased by 7% and 35%, respectively, owing to implementation of water-saving irrigation technologies. To reduce excessive runoff and increase water utilization efficiencies, regionally specific water management strategies should be further promoted. As the first long-term national estimate of cropland runoff in China, this study provides a simple framework for estimating regional cropland runoff depth and volume, providing critical information for guiding developments of management practices to mitigate agricultural nonpoint source pollution, soil erosion and water scarcity