Why don't zombies like hibiscus tea? A multi-subject approach to photosynthesis through the use of Grätzel cells

Traditionally, photosynthesis has been seen as the domain of biology, with some input from chemistry when dealing with chromatography, while, apart from a passing reference to the colour of leaves, physics has tended to steer clear of the process that provides the lifeblood of human existence. This article outlines how a recent technological advance can be used as a teaching resource in all three branches of science

Buoyancy-driven inflow to a relic cold core: the gas belt in radio galaxy 3C 386

We report measurements from an XMM-Newton observation of the low-excitation radio galaxy 3C 386. The study focusses on an X-ray-emitting gas belt, which lies between and orthogonal to the radio lobes of 3C 386 and has a mean temperature of $0.94\pm0.05$ keV, cooler than the extended group atmosphere. The gas in the belt shows temperature structure with material closer to the surrounding medium being hotter than gas closer to the host galaxy. We suggest that this gas belt involves a `buoyancy-driven inflow' of part of the group-gas atmosphere where the buoyant rise of the radio lobes through the ambient medium has directed an inflow towards the relic cold core of the group. Inverse-Compton emission from the radio lobes is detected at a level consistent with a slight suppression of the magnetic field below the equipartition value.Comment: 11 pages, 10 figures, accepted for publication in MNRA

Barriers to women in the UK construction industry

Purpose – This paper aims to identify the main barriers that lead to the under-representation of women in the UK construction industry. The study, funded by ConstructionSkills, seeks to explore the issues that women face and investigate the potential positive impact that continuous professional development (CPD) may have upon improving the retention and career progression of women. Design/methodology/approach – The study uses an open-ended grounded theory (GT) approach, including 231 semi-structured questionnaires and nine focus groups with women from a range of professional occupations. All the findings were analysed using keyword analysis to identify the top two barriers that women face, alongside a series of cross-cutting key themes and issues. Findings – The findings reveal that male-dominated organisational cultures and inflexible working practices are the main barriers to women in the UK construction industry, irrespective of job role or profession. This paper concludes by arguing for a sea-change in the expansion of CPD opportunities for women in managerial, confidence and communication based skills, with accompanying networking and support systems to facilitate the retention and advancement of women in the industry sector. Research limitations/implications – Due to the research approach, the data are not generalisable. Therefore, researchers are advised to research and test the findings with a larger group. Researchers are also recommended to investigate the impact of expanded CPD opportunities for both men and women. Originality/value – The paper puts forward a business case for the advancement of specific CPD training for women, to facilitate the expansion of equality and diversity in the workforce in the UK construction industry

Laser photolysis of photographic image dyes

Studies have been carried out investigating the photochemical and photophysical properties of pyrazolotriazole azomethine dyes. Such compounds can be used as magenta images in the subtractive colour photographic process. This work has been carried out both in dilute fluid solution and in high concentration, high viscosity systems designed to mimic the photographic product. Picosecond pump-probe laser flash photolysis studies have provided the first observation of photoinduced transient absorption changes attributable to the excited states of this class of dyes, and have allowed assignment of the excited singlet state lifetime as being in the range 1 to 3ps at room temperature, with little dependence upon solvent properties or the pattern of substituents on the dye skeleton. Using picosecond laser flash photolysis it has also been possible to observe evolution of the population along the ground state potential surface to the two isomeric forms, the rate of this process showing some solvent dependence. Nanosecond and picosecond laser flash photolysis studies have been used to investigate the process of syn-anti and anti-syn isomerisation about the azomethine linkage. The syn-anti photoisomerisation occurs on picosecond timescales, the anti isomer so produced relaxing thermally back to the syn form on timescales ranging from microseconds to milliseconds. The rate constant for this process is a complex function of solvent properties as well as being dependent upon steric factors within the molecule, and the reasons for this are discussed. Triplet energy sensitisation studies have demonstrated that a pathway exists for this isomerisation process via the triplet manifold, and has allowed determination of minimum isomerisation quantum yields from the triplet state. Such studies have also allowed estimation of limits for the molar decadic absorption coefficients of the anti isomer. The photographic product dyes have been demonstrated to be efficient quenchers of singlet molecular oxygen, the quenching mechanism being predominantly physical in nature. The quantum yields of singlet oxygen production are too small to be measured using time resolved techniques. These factors are used to explain in part the resistance of such compounds to oxidative photodegradation. Steady state irradiation of azomethine dyes in systems designed to simulate the photographic product by a high intensity source of known spectral profile has allowed determination of the quantum yields of photodegradation, which in combination with the results obtained in fluid solution provide a basis for explaining the behaviour of image dyes in the photographic product environment

Multifrequency Study of The Radio Galaxy NGC326

We present the results of a multi-frequency study of the inversion symmetric radio galaxy NGC326 based on Very Large Array observations at 1.4, 1.6, 4.8, 8.5 and 14.9 GHz. The morphological, spectral and polarization properties of this peculiar object are studied at different levels of spatial resolutions. The interpretation of the data will be discussed in forthcoming papers.Comment: 15 pages, 15 ps figures, accepted by A&

The inner jet of radio galaxy NGC 315 as observed with Chandra and the VLA

We present Chandra X-ray results for the jet, nucleus, and gaseous atmosphere of NGC 315, a nearby radio galaxy whose jet kinematics are known through deep radio mapping. Diffuse X-ray synchrotron emission is detected from the jet out to 30 arcsec from the nucleus, through regions both of fast bulk flow and deceleration. The X-ray to radio flux ratio drops considerably where the flow decelerates, but the X-ray and radio emissions show similar transverse extents throughout, requiring distributed particle acceleration to maintain the supply of X-ray-emitting electrons. A remarkable knotty filament within the jet is seen in both the radio and X-ray, contributing roughly 10 per cent of the diffuse emission along its extent at both wavelengths. No completely satisfactory explanation for the filament is found, though its oscillatory appearance, roughly aligned magnetic field, and requirements for particle acceleration, suggest that it is a magnetic strand within a shear layer between fast inner and slower outer flow.Comment: Accepted for publication in the MNRAS. 13 pages,14 figures (some in colour

The magnetized medium around the radio galaxy B2 0755+37: an interaction with the intra-group gas

We explore the magneto-ionic environment of the isolated radio galaxy B2 0755+37 using detailed imaging of the distributions of Faraday rotation and depolarization over the radio source from Very Large Array observations at 1385,1465 and 4860 MHz and new X-ray data from XMM-Newton. The Rotation Measure (RM) distribution is complex, with evidence for anisotropic fluctuations in two regions. The approaching lobe shows low and uniform RM in an unusual `stripe' along an extension of the jet axis and a linear gradient transverse to this axis over its Northern half. The leading edge of the receding lobe shows arc-like RM structures with sign reversals. Elsewhere, the RM structures are reasonably isotropic. The RM power spectra are well described by cut-off power laws with slopes ranging from 2.1 to 3.2 in different sub-regions. The corresponding magnetic-field autocorrelation lengths, where well-determined, range from 0.25 to 1.4 kpc. It is likely that the fluctuations are mostly produced by compressed gas and field around the leading edges of the lobes. We identify areas of high depolarization around the jets and inner lobes. These could be produced by dense gas immediately surrounding the radio emission containing a magnetic field which is tangled on small scales. We also identify four ways in which the well known depolarization (Faraday depth) asymmetry between jetted and counter-jetted lobes of extended radio sources can be modified by interactions with the surrounding medium.Comment: 16 pages, 13 figures, accepted for publication in MNRAS. Full resolution paper available at: ftp://ftp.ira.inaf.it/pub/outgoing/guidetti/ Subjects: Cosmology and Extragalactic Astrophysics (astro-ph.CO

The X-ray spectrum of 3C 273

An X-ray spectral measurement of the quasar 3C 273 with the HEAO-A2 experiment in June/July 1978 is reported. The best power law fit to the photon flux over the range 2-60 keV gives a slope of 1.41 + or - 0.02. However, structure is observed, indicating a slope of 1.52 between 2 keV and 9 keV and a slight flattening between 9 keV and 30 keV. Observations with the same experiment in December 1977 and OSO-8 in June 1976 allows confirmation of 40% intensity variability on the time scale of months, although within limits provided by the poorer statistical quality of the additional data no spectral change is discerned. Absorption from the source is found to be low, with the 1978 data yielding a 90% confidence upper limit to the hydrogen column density of 4.5 x 10 to the 21st power atoms/sq cm