Understanding the Reactivity of a Thin Li1.5Al0.5Ge1.5(PO4)3 Solid-State Electrolyte toward Metallic Lithium Anode

The thickness of solid-state electrolytes (SSEs) significantly affects the energy density and safety performance of all-solid-state lithium batteries. However, a sufficient understanding of the reactivity toward lithium metal of ultrathin SSEs (<100 µm) based on NASICON remains lacking. Herein, for the first time, a self-standing and ultrathin (70 µm) NASICON-type Li1.5Al0.5Ge1.5(PO4)3 (LAGP) electrolyte via a scalable solution process is developed, and X-ray photoelectron spectroscopy reveals that changes in LAGP at the metastable Li–LAGP interface during battery operation is temperature dependent. Severe germanium reduction and decrease in LAGP particle size are detected at the Li–LAGP interface at elevated temperature. Oriented plating of lithium metal on its preferred (110) face occurs during in situ X-ray diffraction cycling

Herschel Observations of a Newly Discovered UX Ori Star in the Large Magellanic Cloud

The LMC star, SSTISAGE1C J050756.44-703453.9, was first noticed during a survey of EROS-2 lightcurves for stars with large irregular brightness variations typical of the R Coronae Borealis (RCB) class. However, the visible spectrum showing emission lines including the Balmer and Paschen series as well as many Fe II lines is emphatically not that of an RCB star. This star has all of the characteristics of a typical UX Ori star. It has a spectral type of approximately A2 and has excited an H II region in its vicinity. However, if it is an LMC member, then it is very luminous for a Herbig Ae/Be star. It shows irregular drops in brightness of up to 2 mag, and displays the reddening and "blueing" typical of this class of stars. Its spectrum, showing a combination of emission and absorption lines, is typical of a UX Ori star that is in a decline caused by obscuration from the circumstellar dust. SSTISAGE1C J050756.44-703453.9 has a strong IR excess and significant emission is present out to 500 micron. Monte Carlo radiative transfer modeling of the SED requires that SSTISAGE1C J050756.44-703453.9 has both a dusty disk as well as a large extended diffuse envelope to fit both the mid- and far-IR dust emission. This star is a new member of the UX Ori subclass of the Herbig Ae/Be stars and only the second such star to be discovered in the LMC.Comment: ApJ, in press. 9 pages, 5 figure

The Dust-to-Gas Ratio in the Small Magellanic Cloud Tail

The Tail region of the Small Magellanic Cloud (SMC) was imaged using the MIPS instrument on the Spitzer Space Telescope as part of the SAGE-SMC Spitzer Legacy. Diffuse infrared emission from dust was detected in all the MIPS bands. The Tail gas-to-dust ratio was measured to be 1200 +/- 350 using the MIPS observations combined with existing IRAS and HI observations. This gas-to-dust ratio is higher than the expected 500-800 from the known Tail metallicity indicating possible destruction of dust grains. Two cluster regions in the Tail were resolved into multiple sources in the MIPS observations and local gas-to-dust ratios were measured to be ~440 and ~250 suggests dust formation and/or significant amounts of ionized gas in these regions. These results support the interpretation that the SMC Tail is a tidal tail recently stripped from the SMC that includes gas, dust, and young stars.Comment: 6 pages, 3 figures, ApJ Letters, in press, (version with full resolution figures at http://www.stsci.edu/~kgordon/papers/PS_files/sage-smc_taildust_v1.62.pdf

Spitzer Sage Survey of the Large Magellanic Cloud. III. Star Formation and ~1000 New Candidate Young Stellar Objects

We present ~1000 new candidate Young Stellar Objects (YSOs) in the Large Magellanic Cloud selected from Spitzer Space Telescope data, as part of the Surveying the Agents of a Galaxy's Evolution (SAGE) Legacy program. The YSOs, detected by their excess infrared (IR) emission, represent early stages of evolution, still surrounded by disks and/or infalling envelopes. Previously, fewer than 20 such YSOs were known. The candidate YSOs were selected from the SAGE Point Source Catalog from regions of color-magnitude space least confused with other IR-bright populations. The YSOs are biased toward intermediate- to high-mass and young evolutionary stages, because these overlap less with galaxies and evolved stars in color-magnitude space. The YSOs are highly correlated spatially with atomic and molecular gas, and are preferentially located in the shells and bubbles created by massive stars inside. They are more clustered than generic point sources, as expected if star formation occurs in filamentary clouds or shells. We applied a more stringent color-magnitude selection to produce a subset of "high-probability" YSO candidates. We fitted the spectral-energy distributions (SEDs) of this subset and derived physical properties for those that were well fitted. The total mass of these well-fitted YSOs is ~2900 M_☉ and the total luminosity is ~2.1 × 10^6 L_☉ . By extrapolating the mass function with a standard initial mass function and integrating, we calculate a current star-formation rate of ~0.06 M_☉ yr^(–1), which is at the low end of estimates based on total ultraviolet and IR flux from the galaxy (~0.05 – 0.25 M_☉ yr^(–1)), consistent with the expectation that our current YSO list is incomplete. Follow-up spectroscopy and further data mining will better separate the different IR-bright populations and likely increase the estimated number of YSOs. The full YSO list is available as electronic tables, and the SEDs are available as an electronic figure for further use by the scientific community

Spitzer SAGE survey of the Large Magellanic Cloud II: Evolved Stars and Infrared Color Magnitude Diagrams

Color-magnitude diagrams (CMDs) are presented for the Spitzer SAGE (Surveying the Agents of a Galaxy's Evolution) survey of the Large Magellanic Cloud (LMC). IRAC and MIPS 24 um epoch one data are presented. These data represent the deepest, widest mid-infrared CMDs of their kind ever produced in the LMC. Combined with the 2MASS survey, the diagrams are used to delineate the evolved stellar populations in the Large Magellanic Cloud as well as Galactic foreground and extragalactic background populations. Some 32000 evolved stars brighter than the tip of the red giant branch are identified. Of these, approximately 17500 are classified as oxygen-rich, 7000 carbon-rich, and another 1200 as ``extreme'' asymptotic giant branch (AGB) stars. Brighter members of the latter group have been called ``obscured'' AGB stars in the literature owing to their dusty circumstellar envelopes. A large number (1200) of luminous oxygen--rich AGB stars/M supergiants are also identified. Finally, there is strong evidence from the 24 um MIPS channel that previously unexplored, lower luminosity oxygen-rich AGB stars contribute significantly to the mass loss budget of the LMC (1200 such sources are identified).Comment: LaTex, 31 pages, 10 figures. Accepted for publication in the Astronomical Journa

SPITZER SAGE Observations of Large Magellanic Cloud Planetary Nebulae

We present IRAC and MIPS images and photometry of a sample of previously known planetary nebulae (PNe) from the SAGE survey of the Large Magellanic Cloud (LMC) performed with the Spitzer Space Telescope. Of the 233 known PNe in the survey field, 185 objects were detected in at least two of the IRAC bands, and 161 detected in the MIPS 24 micron images. Color-color and color-magnitude diagrams are presented using several combinations of IRAC, MIPS, and 2MASS magnitudes. The location of an individual PN in the color-color diagrams is seen to depend on the relative contributions of the spectral components which include molecular hydrogen, polycyclic aromatic hydrocarbons (PAHs), infrared forbidden line emission from the ionized gas, warm dust continuum, and emission directly from the central star. The sample of LMC PNe is compared to a number of Galactic PNe and found to not significantly differ in their position in color-color space. We also explore the potential value of IR PNe luminosity functions (LFs) in the LMC. IRAC LFs appear to follow the same functional form as the well-established [O III] LFs although there are several PNe with observed IR magnitudes brighter than the cut-offs in these LFs.Comment: 18 pages, 10 figures, 3 tables, to be published in the Astronomical Journal. Additional online data available at http://www.cfa.harvard.edu/irac/publications

Thirty Years After Michael E. Porter: What Do We Know About Business Exit?

Although a business exit is an important corporate change initiative, the buyer’s side seems to be more appealing to management researchers than the seller’s because acquisitions imply growth, i.e., success. Yet from an optimistic viewpoint, business exit can effectively create value for the selling company. In this paper we attempt to bring the relevance of the seller’s side back into our consciousness by asking: What do we know about business exit? We start our exploration with Porter (1976), focusing on literature that investigates the antecedents of, barriers to, and outcomes of business exit. We also include studies from related fields such as finance and economics.1 Through this research we determine three clusters of findings: factors promoting business exit, exit barriers, and exit outcomes. Overall, it is the intention of this paper to highlight the importance of business exit for research and practice. Knowing what we know about business exits and their high financial value we should bear in mind that exit need not mean failure but a new beginning for a corporation

The mass-loss return from evolved stars to the Large Magellanic Cloud III. Dust properties for carbon-rich asymptotic giant branch stars

We present a 2Dust model for the dust shell around a LMC long-period variable (LPV) previously studied as part of the OGLE survey. OGLE LMC LPV 28579 (SAGE J051306.40-690946.3) is a carbon-rich asymptotic giant branch (AGB) star for which we have photometry and spectra from the Spitzer SAGE and SAGE-Spec programs along with UBVIJHK_s photometry. By modeling this source, we obtain a baseline set of dust properties to be used in the construction of a grid of models for carbon stars. We reproduce its spectral energy distribution using a mixture of AmC and SiC (15% by mass). The grain sizes are distributed according to the KMH model. The best-fit model has an optical depth of 0.28 for the shell at the peak of the SiC feature, with R_in~1430 R_sun or 4.4 R_star. The temperature at this inner radius is 1310 K. Assuming an expansion velocity of 10 km s^-1, we obtain a dust mass-loss rate of 2.5x10^-9 M_sun yr-1. We calculate a 15% variation in this rate by testing the fit sensitivity against variation in input parameters. We also present a simple model for the molecular gas in the extended atmosphere that could give rise to the 13.7 \mu m feature seen in the spectrum. We find that a combination of CO and C_2H_2 gas at an excitation temperature of about 1000 K and column densities of 3x10^21 cm^-2 and 10^19 cm^-2 respectively are able to reproduce the observations. Given that the excitation temperature is close to T_dust(R_in), most of the molecular contribution probably arises from the inner shell region. The luminosity corresponding to the first epoch of SAGE observations is 6580 L_sun. For an effective temperature of about 3000 K, this implies a stellar mass of 1.5-2 M_sun and an age of 1-2.5 Gyr. For a gas:dust ratio of 200, we obtain a gas mass-loss rate of 5.0x10^-7 M_sun yr^-1, consistent with the gas mass-loss rates estimated from the period, color and 8 \mu m flux of the source.Comment: 14 pages, 5 figures, accepted for publication in Astronomy & Astrophysic

Spitzer Analysis of HII Region Complexes in the Magellanic Clouds: Determining a Suitable Monochromatic Obscured Star Formation Indicator

HII regions are the birth places of stars, and as such they provide the best measure of current star formation rates (SFRs) in galaxies. The close proximity of the Magellanic Clouds allows us to probe the nature of these star forming regions at small spatial scales. We aim to determine the monochromatic IR band that most accurately traces the bolometric IR flux (TIR), which can then be used to estimate an obscured SFR. We present the spatial analysis, via aperture/annulus photometry, of 16 LMC and 16 SMC HII region complexes using the Spitzer IRAC and MIPS bands. UV rocket data and SHASSA H-alpha data are also included. We find that nearly all of the LMC and SMC HII region SEDs peak around 70um, from ~10 to ~400 pc from the central sources. As a result, the sizes of HII regions as probed by 70um is approximately equal to the sizes as probed by TIR (about 70 pc in radius); the radial profile of the 70um flux, normalized by TIR, is constant at all radii (70um ~ 0.45 TIR); the 1-sigma standard deviation of the 70um fluxes, normalized by TIR, is a lower fraction of the mean (0.05 to 0.12 out to ~220 pc) than the normalized 8, 24, and 160um normalized fluxes (0.12 to 0.52); and these results are invariant between the LMC and SMC. From these results, we argue that 70um is the most suitable IR band to use as a monochromatic obscured star formation indicator because it most accurately reproduces the TIR of HII regions in the LMC and SMC and over large spatial scales. We also explore the general trends of the 8, 24, 70, and 160um bands in the LMC and SMC HII region SEDs, radial surface brightness profiles, sizes, and normalized (by TIR) radial flux profiles. We derive an obscured SFR equation that is modified from the literature to use 70um luminosity, SFR(Mo/yr) = 9.7(0.7)x10^{-44} L(70)(ergs/s), which is applicable from 10 to 300 pc distance from the center of an HII region.Comment: 21 pages, 12 figures, 4 tables. Will be published in ApJ

Spitzer SAGE Infrared Photometry of Massive Stars in the Large Magellanic Cloud

We present a catalog of 1750 massive stars in the Large Magellanic Cloud, with accurate spectral types compiled from the literature, and a photometric catalog for a subset of 1268 of these stars, with the goal of exploring their infrared properties. The photometric catalog consists of stars with infrared counterparts in the Spitzer SAGE survey database, for which we present uniform photometry from 0.3-24 microns in the UBVIJHKs+IRAC+MIPS24 bands. The resulting infrared color-magnitude diagrams illustrate that the supergiant B[e], red supergiant and luminous blue variable (LBV) stars are among the brightest infrared point sources in the Large Magellanic Cloud, due to their intrinsic brightness, and at longer wavelengths, due to dust. We detect infrared excesses due to free-free emission among ~900 OB stars, which correlate with luminosity class. We confirm the presence of dust around 10 supergiant B[e] stars, finding the shape of their spectral energy distributions (SEDs) to be very similar, in contrast to the variety of SED shapes among the spectrally variable LBVs. The similar luminosities of B[e] supergiants (log L/Lo>=4) and the rare, dusty progenitors of the new class of optical transients (e.g. SN 2008S and NGC 300 OT), plus the fact that dust is present in both types of objects, suggests a common origin for them. We find the infrared colors for Wolf-Rayet stars to be independent of spectral type and their SEDs to be flatter than what models predict. The results of this study provide the first comprehensive roadmap for interpreting luminous, massive, resolved stellar populations in nearby galaxies at infrared wavelengths.Comment: 57 pages, 19 figures, 5 tables, accepted for publication in the Astronomical Journal (v3 corrects typos