27 research outputs found
Strategies for Oxidation Catalyzed by Polyoxometalates at the Interface of Homogeneous and Heterogeneous Catalysis
No full textKinetics and Mechanism of Oxidation of 2-Mercaptoethanol by the Heteropolyoxovanadate [MnV 13
No full textEnhanced Water Splitting at Thin Film Tungsten Trioxide Photoanodes Bearing Plasmonic Gold-Polyoxometalate Particles
No full textEnhanced Water Splitting at Thin Film Tungsten Trioxide Photoanodes Bearing Plasmonic Gold-Polyoxometalate Particles
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Polyoxometalate-Based Metal-Organic Frameworks as Catalysts for the Selective Oxidation of Alcohols in Micellar Systems
No full textTransfer Hydrogenation Catalysis by a N-Heterocyclic Carbene (NHC) Iridium Complex on a Polyoxometalate Platform
No full textA divacant Keggin polyanion has been decorated with a N-heterocyclic carbene (NHC) iridium(I) organometallic complex to provide a molecular model of an Ir-based supported catalyst. The characterization of the hybrid compound has been performed by multinuclear NMR spectroscopy, infrared spectroscopy, cyclic voltammetry, and mass spectroscopy, and the results are in agreement with a bisfunctionalization of the polyoxometalate scaffold. The resulting supported homogeneous complex has been successfully used to catalyze the transfer hydrogenation from iPrOH to benzophenone [with a turnover number (TON) of 680 and a turnover frequency (TOF) of up to 540 hâ1].European Research CouncilEuropean Science Foundatio
Tungstate promoted vanadium phosphate catalysts for the gas phase oxidation of methanol to formaldehyde
No full textPolyoxometalates adsorbed on metallic surfaces: immediate reduction of [SiW12O40]4â on Ag(100)
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