Bending light to our will

This article is based on the Fred Kavli Distinguished Lectureship in Nanoscience presentation given by Harry Atwater (California Institute of Technology) on April 5, 2010 at the Materials Research Society Spring Meeting in San Francisco, CA. The Kavli Foundation supports scientific research, honors scientific achievement, and promotes public understanding of scientists and their work. Its particular focuses are astrophysics, nanoscience, and neuroscience. Solar energy is currently enjoying substantial growth and investment, owing to worldwide sensitivity to energy security and climate change. Solar energy is an inexhaustible resource and is in abundant supply on all continents of the world. The power density of sunlight (~1000 W/m 2 ) and the effi ciency of photovoltaic devices (~10–25%) are high enough so that land use does not limit photovoltaic deployment at the terawatt scale. However solar photovoltaics are currently too expensive to achieve parity with other forms of electricity generation based on fossil fuels. This is largely due to the cost (and for some cases, the abundance) of materials used in photovoltaic modules and systems, and the cost of deploying in current form. This economic and social context has created the present situation where there is widespread interest in photovoltaic technology for power generation, but the cumulative installed world capacity for photovoltaics is <50 GW, and it appears to be very challenging for photovoltaics to play a very substantial role in large-scale (terawatt) electricity generation in the short term

Plasmonics: Chip-based component devices and metamaterials

Dispersion control and active materials integration have yielded plasmonic components including i) three-dimensional single layer plasmonic metamaterials ii) all-optical, electro-optic and field effect modulation of plasmon propagation iii) plasmon-enhanced absorption in solar cells

Cooperative behavior of quantum dipole emitters coupled to a zero-index nanoscale waveguide

We study cooperative behavior of quantum dipole emitters coupled to a rectangular waveguide with dielectric core and silver cladding. We investigate cooperative emission and inter-emitter entanglement generation phenomena for emitters whose resonant frequencies are near the frequency cutoff of the waveguide, where the waveguide effectively behaves as zero-index metamaterial. We show that coupling emitters to a zero-index waveguide allows one to relax the constraint on precision positioning of emitters for observing inter-emitter entanglement generation and extend the spatial scale at which the superradiance can be observed

Plasmonic Rainbow Trapping Structures for Light Localization and Spectrum Splitting

“Rainbow trapping” has been proposed as a scheme for localized storage of broadband electromagnetic radiation in metamaterials and plasmonic heterostructures. Here, we articulate the dispersion and power flow characteristics of rainbow trapping structures, and show that tapered waveguide structures composed of dielectric core and metal cladding are best suited for light trapping. A metal-insulator-metal taper acts as a cascade of optical cavities with different resonant frequencies, exhibiting a large quality factor and small effective volume comparable to conventional plasmonic resonators

Water-Splitting Photoelectrolysis Reaction Rate via Microscopic Imaging of Evolved Oxygen Bubbles

Bubble formation and growth on a water-splitting semiconductor photoelectrode under illumination with above-bandgap radiation provide a direct measurement of the gas-evolving reaction rate. Optical microscopy was used to record the bubble growth on single-crystal strontium titanate immersed in basic aqueous electrolyte and illuminated with UV light at 351/364 nm from a focused argon laser. By analyzing the bubble size as a function of time, the water-splitting reaction rate was determined for varying light intensities and was compared to photocurrent measurements. Bubble nucleation was explored on an illuminated flat surface, as well as the subsequent light scattering and electrode shielding due to the bubble. This technique allows a quantitative examination of the actual gas evolution rate during photoelectrochemical water splitting, independent of current measurements

Design of a film surface roughness-minimizing molecular beam epitaxy

Molecular beam epitaxy of germanium was used along with kinetic Monte Carlo simulations to study time-varying processing parameters and their effect on surface morphology. Epitaxial Ge films were deposited on highly oriented Ge(001) substrates, with reflection high-energy electron diffraction as a real-time sensor. The Monte Carlo simulations were used to model the growth process, and physical parameters were determined during growth under time-varying flux. A reduced version of the simulations was generated, enabling the application on an optimization algorithm. Temperature profiles were then computed that minimize surface roughness subject to various experimental constraints. The final roughness after two layers of growth was reduced to 0.32, compared to 0.36 at the maximum growth temperature. The study presented here is an initial demonstration of a general approach that could also be used to optimize properties in other materials and deposition processes

Purcell Enhancement of Parametric Luminescence: Bright and Broadband Nonlinear Light Emission in Metamaterials

Single-photon and correlated two-photon sources are important elements for optical information systems. Nonlinear downconversion light sources are robust and stable emitters of single photons and entangled photon pairs. However, the rate of downconverted light emission, dictated by the properties of low-symmetry nonlinear crystals, is typically very small, leading to significant constrains in device design and integration. In this paper, we show that the principles for spontaneous emission control (i.e. Purcell effect) of isolated emitters in nanoscale structures, such as metamaterials, can be generalized to describe the enhancement of nonlinear light generation processes such as parametric down conversion. We develop a novel theoretical framework for quantum nonlinear emission in a general anisotropic, dispersive and lossy media. We further find that spontaneous parametric downconversion in media with hyperbolic dispersion is broadband and phase-mismatch-free. We predict a 1000-fold enhancement of the downconverted emission rate with up to 105 photon pairs per second in experimentally realistic nanostructures. Our theoretical formalism and approach to Purcell enhancement of nonlinear optical processes, provides a framework for description of quantum nonlinear optical phenomena in complex nanophotonic structures.Comment: 29 pages, 10 figure