Síntesis y caracterización de pinturas selectivas de Co3O4 para superficies selectivas en colectores solares de baja temperatura

Para aumentar el rendimiento energético de los calefones solares se recubre al colector con superficies selectivas, donde las pinturas selectivas representan una alternativa económica. El Co3O4 utilizado como pigmento en pinturas selectivas se ha obtenido por diferentes métodos, pero mediante síntesis por combustión se han encontrado pocas referencias respecto a la temática. Se obtuvieron micropartículas de Co3O4 mediante una vía de combustión. Luego, por Difracción de Rayos X se determinó la estructura cúbica del Co3O4, además, por Microscopía Electrónica de Barrido, se observó una morfología compacta y aglomeración y mediante Microscopía Electrónica de Transmisión se apreciaron tamaños de partícula de 1m aprox. La absorbancia espectral en un rango de 500 a 1100 nm de longitud de onda de las películas formadas a partir de los pigmentos de Co3O4 sobre vidrio y aluminio está entre 0.92 y 0.96 menor al obtenido para una pintura comercial que está entre 0.95 y 0.97.Fil: Gardey Merino, María Celeste. Universidad Tecnológica Nacional, Facultad Regional Mendoza, CLIOPE,; ArgentinaFil: Belda, R.. Universidad Tecnológica Nacional, Facultad Regional Mendoza, CLIOPE,; ArgentinaFil: Lascalea, Gustavo Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Reg. de Invest. Cientif. y Tecnológicas. Laboratorio de Invest. y Servicios Ambientales Mendoza; ArgentinaFil: Vazquez, Patricia Graciela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentin

Phylogeny-Aware Analysis of Metagenome Community Ecology Based on Matched Reference Genomes while Bypassing Taxonomy

We introduce the operational genomic unit (OGU) method, a metagenome analysis strategy that directly exploits sequence alignment hits to individual reference genomes as the minimum unit for assessing the diversity of microbial communities and their relevance to environmental factors. This approach is independent of taxonomic classification, granting the possibility of maximal resolution of community composition, and organizes features into an accurate hierarchy using a phylogenomic tree. The outputs are suitable for contemporary analytical protocols for community ecology, differential abundance, and supervised learning while supporting phylogenetic methods, such as UniFrac and phylofactorization, that are seldom applied to shotgun metagenomics despite being prevalent in 16S rRNA gene amplicon studies. As demonstrated in two real-world case studies, the OGU method produces biologically meaningful patterns from microbiome data sets. Such patterns further remain detectable at very low metagenomic sequencing depths. Compared with taxonomic unit-based analyses implemented in currently adopted metagenomics tools, and the analysis of 16S rRNA gene amplicon sequence variants, this method shows superiority in informing biologically relevant insights, including stronger correlation with body environment and host sex on the Human Microbiome Project data set and more accurate prediction of human age by the gut microbiomes of Finnish individuals included in the FINRISK 2002 cohort. We provide Woltka, a bioinformatics tool to implement this method, with full integration with the QIIME 2 package and the Qiita web platform, to facilitate adoption of the OGU method in future metagenomics studies. IMPORTANCE Shotgun metagenomics is a powerful, yet computationally challenging, technique compared to 16S rRNA gene amplicon sequencing for decoding the composition and structure of microbial communities. Current analyses of metagenomic data are primarily based on taxonomic classification, which is limited in feature resolution. To solve these challenges, we introduce operational genomic units (OGUs), which are the individual reference genomes derived from sequence alignment results, without further assigning them taxonomy. The OGU method advances current read-based metagenomics in two dimensions: (i) providing maximal resolution of community composition and (ii) permitting use of phylogeny-aware tools. Our analysis of real-world data sets shows that it is advantageous over currently adopted metagenomic analysis methods and the finest-grained 16S rRNA analysis methods in predicting biological traits. We thus propose the adoption of OGUs as an effective practice in metagenomic studies.Peer reviewe

Global patient outcomes after elective surgery: prospective cohort study in 27 low-, middle- and high-income countries.

BACKGROUND: As global initiatives increase patient access to surgical treatments, there remains a need to understand the adverse effects of surgery and define appropriate levels of perioperative care. METHODS: We designed a prospective international 7-day cohort study of outcomes following elective adult inpatient surgery in 27 countries. The primary outcome was in-hospital complications. Secondary outcomes were death following a complication (failure to rescue) and death in hospital. Process measures were admission to critical care immediately after surgery or to treat a complication and duration of hospital stay. A single definition of critical care was used for all countries. RESULTS: A total of 474 hospitals in 19 high-, 7 middle- and 1 low-income country were included in the primary analysis. Data included 44 814 patients with a median hospital stay of 4 (range 2-7) days. A total of 7508 patients (16.8%) developed one or more postoperative complication and 207 died (0.5%). The overall mortality among patients who developed complications was 2.8%. Mortality following complications ranged from 2.4% for pulmonary embolism to 43.9% for cardiac arrest. A total of 4360 (9.7%) patients were admitted to a critical care unit as routine immediately after surgery, of whom 2198 (50.4%) developed a complication, with 105 (2.4%) deaths. A total of 1233 patients (16.4%) were admitted to a critical care unit to treat complications, with 119 (9.7%) deaths. Despite lower baseline risk, outcomes were similar in low- and middle-income compared with high-income countries. CONCLUSIONS: Poor patient outcomes are common after inpatient surgery. Global initiatives to increase access to surgical treatments should also address the need for safe perioperative care. STUDY REGISTRATION: ISRCTN5181700

Numerical simulation of the full-polarimetric emissivity of vines and comparison with experimental

Surface soil moisture is a key variable needed to understand and predict the climate. L-band microwave radiometry seems to be the best technique to remotely measure the soil moisture content, since the influence of other effects such as surface roughness and vegetation is comparatively small. This work describes a numerical model developed to efficiently compute the four elements of the Stokes emission vector (Th, Tv, TU and TV) of vegetation-covered soils at low microwave frequencies, as well as the single-scattering albedo and the extinction coefficient of the vegetation layer over a wide range of incidence angles. A comparison with L-band (1.400–1.427 MHz) experimental radiometric data gathered during the SMOS REFLEX 2003 field experiment over vines is presented and discussed. The measured and simulated emissivities at vertical polarization agree very well. However, at horizontal polarization there is some disagreement introduced by the soil emission model. Important radiometric parameters, such as the albedo, the attenuation and the transmissivity are computed and analyzed in terms of their values and trends, as well as their dependence on the observation and scene parameters. It is found that the vegetation attenuation is mainly driven by the presence of branches and leaves, while the albedo is mainly driven by the branches. The comparison of the simulated parameters with the values obtained by fitting the experimental data with the τ-ω model is very satisfactory