16 research outputs found
Probing weak force induced parity violation by high resolution mid-infrared molecular spectroscopy
To date no experiment has reached the level of sensitivity required to
observe weak nuclear force induced parity violation (PV) energy differences in
chiral molecules. In this paper, we present the approach, adopted at
Laboratoire de Physique des Lasers (LPL), to measure frequency differences in
the vibrational spectrum of enantiomers. We review different spectroscopic
methods developed at LPL leading to the highest resolutions, as well as 20
years of CO2 laser stabilization work enabling such precise measurements. After
a first attempt to observe PV vibrational frequency shifts using sub-Doppler
saturated absorption spectroscopy in a cell, we are currently aiming at an
experiment based on Doppler-free two-photon Ramsey interferometry on a
supersonic beam. We report on our latest progress towards observing PV with
chiral organo-metallic complexes containing a heavy rhenium atom
A revised uncertainty budget for measuring the Boltzmann constant using the Doppler Broadening Technique on ammonia
We report on our on-going effort to measure the Boltzmann constant, kB, using
the Doppler Broadening Technique. The main systematic effects affecting the
measurement are discussed. A revised error budget is presented in which the
global uncertainty on systematic effects is reduced to 2.3 ppm. This
corresponds to a reduction of more than one order of magnitude compared to our
previous Boltzmann constant measurement. Means to reach a determination of kB
at the part per million accuracy level are outlined
A widely tunable 10-m quantum cascade laser phase-locked to a state-of-the-art mid-infrared reference for precision molecular spectroscopy
We report the coherent phase-locking of a quantum cascade laser (QCL) at
10-m to the secondary frequency standard of this spectral region, a CO2
laser stabilized on a saturated absorption line of OsO4. The stability and
accuracy of the standard are transferred to the QCL resulting in a line width
of the order of 10 Hz, and leading to our knowledge to the narrowest QCL to
date. The locked QCL is then used to perform absorption spectroscopy spanning 6
GHz of NH3 and methyltrioxorhenium, two species of interest for applications in
precision measurements.Comment: 5 pages, 4 figure
Characterising molecules for fundamental physics: an accurate spectroscopic model of methyltrioxorhenium derived from new infrared and millimetre-wave measurements
Precise spectroscopic analysis of polyatomic molecules enables many striking
advances in physical chemistry and fundamental physics. We use several new
high-resolution spectroscopic devices to improve our understanding of the
rotational and rovibrational structure of methyltrioxorhenium (MTO), the
achiral parent of a family of large oxorhenium compounds that are ideal
candidate species for a planned measurement of parity violation in chiral
molecules. Using millimetre-wave and infrared spectroscopy in a pulsed
supersonic jet, a cryogenic buffer gas cell, and room temperature absorption
cells, we probe the ground state and the Re=O antisymmetric and symmetric
stretching excited states of both CH3 187 ReO3 and CH3 185 ReO3 isotopologues
in the gas phase with unprecedented precision. By extending the rotational
spectra to the 150-300 GHz range, we characterize the ground state rotational
and hyperfine structure up to J = 43 and K = 41, resulting in refinements to
the rotational, quartic and hyperfine parameters, and the determination of
sextic parameters and a centrifugal distortion correction to the quadrupolar
hyperfine constant. We obtain rovibrational data for temperatures between 6 and
300 K in the 970-1015 cm-1 range, at resolutions down to 8 MHz and accuracies
of 30 MHz. We use these data to determine more precise excited-state
rotational, Coriolis and quartic parameters, as well as the ground-state
centrifugal distortion parameter D K of the 187 Re isotopologue. We also
account for hyperfine structure in the rovibrational transitions and hence
determine the upper state rhenium atom quadrupole coupling constant eQq'
Absorption line shape recovery beyond the detection bandwidth limit: application to the precision spectroscopic measurement of the Boltzmann constant
22 pagesInternational audienceA theoretical model of the influence of detection bandwidth properties on observed line shapes in laser absorption spectroscopy is described. The model predicts artificial frequency shifts, extra broadenings and line asymmetries which must be taken into account in order to obtain accurate central frequencies and other spectroscopic parameters. This reveals sources of systematic effects most probably underestimated so far potentially affecting spectroscopic measurements. This may impact many fields of research, from atmospheric and interstellar physics to precision spectroscopic measurements devoted to metrological applications, tests of quantum electrodynamics or other fundamental laws of nature. Our theoretical model is validated by linear absorption experiments performed on H2O and NH3 molecular lines recorded by precision laser spectroscopy in two distinct spectral regions, near- and mid-infrared. Possible means of recovering original line shape parameters or experimental conditions under which the detection bandwidth has a negligible impact, given a targeted accuracy, are proposed. Particular emphasis is put on the detection bandwidth adjustments required to use such high-quality molecular spectra for a spectroscopic determination of the Boltzmann constant at the 1 ppm level of accuracy
GA4GH: International policies and standards for data sharing across genomic research and healthcare.
The Global Alliance for Genomics and Health (GA4GH) aims to accelerate biomedical advances by enabling the responsible sharing of clinical and genomic data through both harmonized data aggregation and federated approaches. The decreasing cost of genomic sequencing (along with other genome-wide molecular assays) and increasing evidence of its clinical utility will soon drive the generation of sequence data from tens of millions of humans, with increasing levels of diversity. In this perspective, we present the GA4GH strategies for addressing the major challenges of this data revolution. We describe the GA4GH organization, which is fueled by the development efforts of eight Work Streams and informed by the needs of 24 Driver Projects and other key stakeholders. We present the GA4GH suite of secure, interoperable technical standards and policy frameworks and review the current status of standards, their relevance to key domains of research and clinical care, and future plans of GA4GH. Broad international participation in building, adopting, and deploying GA4GH standards and frameworks will catalyze an unprecedented effort in data sharing that will be critical to advancing genomic medicine and ensuring that all populations can access its benefits
Valence-shell photoelectron circular dichroism of ruthenium(III)-tris-(acetylacetonato) gas-phase enantiomers
International audienceChiral transition-metal complexes are of interest in many fields ranging from asymmetric catalysis and molecular materials science to optoelectronic applications or fundamental physics including parity violation effects. We present here a combined theoretical and experimental investigation of gas-phase valence-shell photoelectron circular dichroism (PECD) on the challenging open-shell ruthenium(iii)-tris-(acetylacetonato) complex, Ru(acac)(3). Enantiomerically pure Delta- or ?-Ru(acac)(3), characterized by electronic circular dichroism (ECD), were vaporized and adiabatically expanded to produce a supersonic beam and photoionized by circularly-polarized VUV light from the DESIRS beamline at Synchrotron SOLEIL. Photoelectron spectroscopy (PES) and PECD experiments were conducted using a double imaging electron/ion coincidence spectrometer, and compared to density functional theory (DFT) and time-dependent DFT (TDDFT) calculations. The open-shell character of Ru(acac)(3), which is not taken into account in our DFT approach, is expected to give rise to a wide multiplet structure, which is not resolved in our PES signals but whose presence might be inferred from the additional striking features observed in the PECD curves. Nevertheless, the DFT-based assignment of the electronic bands leads to the characterisation of the ionized orbitals. In line with other recent works, the results confirm that PECD persists independently on the localization and/or on the achiral or chiral nature of the initial orbital, but is rather a probe of the molecular potential as a whole. Overall, the measured PECD signals on Ru(acac)(3), a system exhibiting D-3 propeller-type chirality, are of similar magnitude compared to those on asymmetric-carbon-based chiral organic molecules which constitute the vast majority of species investigated so far, thus suggesting that PECD is a universal mechanism, inherent to any type of chirality
Characterising molecules for fundamental physics: an accurate spectroscopic model of methyltrioxorhenium derived from new infrared and millimetre-wave measurements
Periodic sea-level oscillation in Tokyo Bay detected with the Tokyo-Bay seafloor hyper-kilometric submarine deep detector (TS-HKMSDD)
Abstract
Meteorological-tsunami-like (or meteotsunami-like) periodic oscillation was muographically detected with the Tokyo-Bay Seafloor Hyper-Kilometric Submarine Deep Detector (TS-HKMSDD) deployed in the underwater highway called the Trans-Tokyo Bay Expressway or Tokyo Bay Aqua-Line (TBAL). It was detected right after the arrival of the 2021 Typhoon-16 that passed through the region 400 km south of the bay. The measured oscillation period and decay time were respectively 3 h and 10 h. These measurements were found to be consistent with previous tide gauge measurements. Meteotsunamis are known to take place in bays and lakes, and the temporal and spatial characteristics of meteotsunamis are similar to seismic tsunamis. However, their generation and propagation mechanisms are not well understood. The current result indicates that a combination of muography and trans-bay or trans-lake underwater tunnels will offer an additional tool to measure meteotsunamis at locations where tide gauges are unavailable