Recent advances in metallic glass nanostructures: synthesis strategies and electrocatalytic applications

Recent advances in metallic glass nanostructures (MGNs) are reported, covering a wide array of synthesis strategies, computational discovery, and design solutions that provide insight into distinct electrocatalytic applications. A brief introduction to the development and unique features of MGNs with an overview of top-down and bottom-up synthesis strategies is presented. Specifically, the morphology and structural analysis of several examples applying MGNs as electrodes are highlighted. Subsequently, a comprehensive discussion of commonly employed kinetic parameters and their connection with the unique material structures of MGNs on individual electrocatalytic reactions is made, including the hydrogen evolution reaction, oxygen reduction reaction, and alcohol (methanol or ethanol) oxidation reaction. Finally, a summary of the challenges and perspective on the future research and development relevant to MGNs as electrocatalysts is provided.317FAPESP – FUNDAÇÃO DE AMPARO À PESQUISA DO ESTADO DE SÃO PAULO2017/11958‐

The Molecular Condensations Ahead of Herbig-Haro Objects. III. Radiative and dynamical perturbations of the HH 2 condensation

We have carried out an extensive observational study (from BIMA data) and made a preliminary theoretical investigation of the molecular gas around HH2. The molecular maps show a very complex morphological, kinematical and chemical structure. The overall main conclusion of this work confirms the findings of Paper I and II, by demonstrating that in addition to the strong photochemical effects caused by penetration of the UV photons from HH2 into molecular cloud, a range of complex radiative and dynamical interactions occur. Thus, despite the apparent `quiescent' nature of the molecular cloud ahead of HH2, the kinematical properties observed within the field of view suggest that it is possibly being driven out by powerful winds from the VLA 1 protostar.Comment: 20 pages. Accepted for publication to Astronomy & Astrophysic

The prestellar and protostellar population of R Coronae Australis

We present 450 and 850 um maps of R Coronae Australis. We compare the maps to previous surveys of the region, and shed new light on the previously unknown nature of the protostellar sources at the centre of the cloud. We clarify the nature of two millimetre sources previously discovered in lower resolution data. We identify one new Class 0 protostar that we label SMM 1B, and we measure the envelope masses of a number of more evolved protostars. We identify two new prestellar cores that we call SMM 1A and SMM 6.Comment: 8 page

Receptivity to freestream acoustic noise in hypersonic flow over a generic forebody

Direct numerical simulations of the Navier–Stokes equations have been performed to investigate the receptivity and breakdown mechanisms in a Mach 6 flow over a generic forebody geometry with freestream acoustic disturbances. The simulations are based on transition experiments carried out in April 2015 in the Boeing/U.S. Air Force Office of Scientific Research Mach 6 facility at Purdue University. A three-dimensional model for both fast and slow freestream acoustic waves with multiple frequencies and spanwise wave numbers has been adopted in the numerical simulations, for which high-amplitude disturbances have been considered in order to simulate noisy wind-tunnel conditions. The numerical results revealed similarities in comparison to the experimental observations, especially when slow acoustic waves were considered as freestream disturbances. In particular, slow acoustic waves have been found to induce the breakdown process via crossflow instabilities located in the off-centerline region, with formation of streamwise streaks. Fast acoustic waves, in contrast, appeared more efficient in inducing earlier nonlinear growth through destabilization of the boundary layer along the symmetry plane of the body.Published versio

Visualizing sound emission of elephant vocalizations: evidence for two rumble production types

Recent comparative data reveal that formant frequencies are cues to body size in animals, due to a close relationship between formant frequency spacing, vocal tract length and overall body size. Accordingly, intriguing morphological adaptations to elongate the vocal tract in order to lower formants occur in several species, with the size exaggeration hypothesis being proposed to justify most of these observations. While the elephant trunk is strongly implicated to account for the low formants of elephant rumbles, it is unknown whether elephants emit these vocalizations exclusively through the trunk, or whether the mouth is also involved in rumble production. In this study we used a sound visualization method (an acoustic camera) to record rumbles of five captive African elephants during spatial separation and subsequent bonding situations. Our results showed that the female elephants in our analysis produced two distinct types of rumble vocalizations based on vocal path differences: a nasally- and an orally-emitted rumble. Interestingly, nasal rumbles predominated during contact calling, whereas oral rumbles were mainly produced in bonding situations. In addition, nasal and oral rumbles varied considerably in their acoustic structure. In particular, the values of the first two formants reflected the estimated lengths of the vocal paths, corresponding to a vocal tract length of around 2 meters for nasal, and around 0.7 meters for oral rumbles. These results suggest that African elephants may be switching vocal paths to actively vary vocal tract length (with considerable variation in formants) according to context, and call for further research investigating the function of formant modulation in elephant vocalizations. Furthermore, by confirming the use of the elephant trunk in long distance rumble production, our findings provide an explanation for the extremely low formants in these calls, and may also indicate that formant lowering functions to increase call propagation distances in this species'

Strong-coupling study of the Gribov ambiguity in lattice Landau gauge

We study the strong-coupling limit beta=0 of lattice SU(2) Landau gauge Yang-Mills theory. In this limit the lattice spacing is infinite, and thus all momenta in physical units are infinitesimally small. Hence, the infrared behavior can be assessed at sufficiently large lattice momenta. Our results show that at the lattice volumes used here, the Gribov ambiguity has an enormous effect on the ghost propagator in all dimensions. This underlines the severity of the Gribov problem and calls for refined studies also at finite beta. In turn, the gluon propagator only mildly depends on the Gribov ambiguity.Comment: 14 pages, 22 figures; minor changes, matches version to appear in Eur. Phys. J.

Infrared exponents and the strong-coupling limit in lattice Landau gauge

We study the gluon and ghost propagators of lattice Landau gauge in the strong-coupling limit beta=0 in pure SU(2) lattice gauge theory to find evidence of the conformal infrared behavior of these propagators as predicted by a variety of functional continuum methods for asymptotically small momenta $q^2 \ll \Lambda_\mathrm{QCD}^2$. In the strong-coupling limit, this same behavior is obtained for the larger values of a^2q^2 (in units of the lattice spacing a), where it is otherwise swamped by the gauge field dynamics. Deviations for a^2q^2 < 1 are well parameterized by a transverse gluon mass $\propto 1/a$. Perhaps unexpectedly, these deviations are thus no finite-volume effect but persist in the infinite-volume limit. They furthermore depend on the definition of gauge fields on the lattice, while the asymptotic conformal behavior does not. We also comment on a misinterpretation of our results by Cucchieri and Mendes in Phys. Rev. D81 (2010) 016005.Comment: 17 pages, 12 figures. Revised version (mainly sections I and II); references and comments on subsequent work on the subject added

Measured optical constants of Pd_(77.5)Cu_6Si_(16.5) bulk metallic glass

Optical constants of Pd_(77.5)Cu_6Si_(16.5) alloy were determined experimentally using spectroscopic ellipsometry measurements on bulk specimens. Values of the complex refractive index of the glassy metallic alloys are compared to their crystalline counterparts and to pure crystalline Pd. The presence of Cu and Si increase the occurrence of defects in the crystal lattice resulting in reduced refractive index in the crystalline alloy when compared to pure crystalline Pd. Moreover, we show the conduction band energy of each specimen using Tauc’s plot. The obtained complex refractive index across the spectrum (250 – 1500nm) allows for accurate prediction of optical performance within the investigated spectral range providing optimal design for optical devices

Can a CPT Violating Ether Solve ALL Electron (Anti)Neutrino Puzzles?

Assuming that CPT is violated in the neutrino sector seems to be a viable alternative to sterile neutrinos when it comes to reconciling the LSND anomaly with the remainder of the neutrino data. There are different (distinguishable) ways of incorporating CPT violation into the standard model, including postulating m different from \bar{m}. Here, I investigate the possibility of introducing CPT violation via Lorentz-invariance violating effective operators (``Ether'' potentials) which modify neutrino oscillation patterns like ordinary matter effects. I argue that, within a simplified two-flavor like oscillation analysis, one cannot solve the solar neutrino puzzle and LSND anomaly while still respecting constraints imposed by other neutrino experiments, and comment on whether significant improvements should be expected from a three-flavor analysis. If one turns the picture upside down, some of the most severe constrains on such CPT violating terms can already be obtained from the current neutrino data, while much more severe constraints can arise from future neutrino oscillation experiments.Comment: 10 pages, 1 eps figure; version to appear in PRD. Comment added, mistake corrected, results and conclusions unchange