Effect of Cluster Formation on Isospin Asymmetry in the Liquid-Gas Phase Transition Region

Nuclear matter within the liquid-gas phase transition region is investigated in a mean-field two-component Fermi-gas model. Following largely analytic considerations, it is shown that: (1) Due to density dependence of asymmetry energy, some of the neutron excess from the high-density phase could be expelled into the low-density region. (2) Formation of clusters in the gas phase tends to counteract this trend, making the gas phase more liquid-like and reducing the asymmetry in the gas phase. Flow of asymmetry between the spectator and midrapidity region in reactions is discussed and a possible inversion of the flow direction is indicated.Comment: 9 pages,3 figures, RevTe

Atmospheric and oceanic impacts of Antarctic glaciation across the Eocene-Oligocene transition

The glaciation of Antarctica at the Eocene–Oligocene transition (approx. 34 million years ago) was a major shift in the Earth’s climate system, but the mechanisms that caused the glaciation, and its effects, remain highly debated. A number of recent studies have used coupled atmosphere–ocean climate models to assess the climatic effects of Antarctic glacial inception, with often contrasting results. Here, using the HadCM3L model, we show that the global atmosphere and ocean response to growth of the Antarctic ice sheet is sensitive to subtle variations in palaeogeography, using two reconstructions representing Eocene and Oligocene geological stages. The earlier stage (Eocene; Priabonian), which has a relatively constricted Tasman Seaway, shows a major increase in sea surface temperature over the Pacific sector of the Southern Ocean in response to the ice sheet. This response does not occur for the later stage (Oligocene; Rupelian), which has a more open Tasman Seaway. This difference in temperature response is attributed to reorganization of ocean currents between the stages. Following ice sheet expansion in the earlier stage, the large Ross Sea gyre circulation decreases in size. Stronger zonal flow through the Tasman Seaway allows salinities to increase in the Ross Sea, deep-water formation initiates and multiple feedbacks then occur amplifying the temperature response. This is potentially a model-dependent result, but it highlights the sensitive nature of model simulations to subtle variations in palaeogeography, and highlights the need for coupled ice sheet–climate simulations to properly represent and investigate feedback processes acting on these time scales

The UMIST Database for Astrochemistry 2012

We present the fifth release of the UMIST Database for Astrochemistry (UDfA). The new reaction network contains 6173 gas-phase reactions, involving 467 species, 47 of which are new to this release. We have updated rate coefficients across all reaction types. We have included 1171 new anion reactions and updated and reviewed all photorates. In addition to the usual reaction network, we also now include, for download, state-specific deuterated rate coefficients, deuterium exchange reactions and a list of surface binding energies for many neutral species. Where possible, we have referenced the original source of all new and existing data. We have tested the main reaction network using a dark cloud model and a carbon-rich circumstellar envelope model. We present and briefly discuss the results of these models

Effects of accretion flow on the chemical structure in the inner regions of protoplanetary disks

We have studied the dependence of the profiles of molecular abundances and line emission on the accretion flow in the hot (\ga 100K) inner region of protoplanetary disks. The gas-phase reactions initiated by evaporation of the ice mantle on dust grains are calculated along the accretion flow. We focus on methanol, a molecule that is formed predominantly through the evaporation of warm ice mantles, to show how the abundance profile and line emission depend on the accretion flow. Our results show that some evaporated molecules keep high abundances only when the accretion velocity is large enough, and that methanol could be useful as a diagnostic of the accretion flow by means of ALMA observations at the disk radius of \la 10AU.Comment: 6 pages, 5 figures, Accepted for publication in A&

CH radio emission from heiles cloud 2 as a tracer of molecular cloud evolution

A mapping observation of the $J=1/2$ $\Lambda$-type doubling transition (3.3 GHz) of CH has been conducted toward Heiles Cloud 2 (HCL2) in the Taurus molecular cloud complex to reveal its molecular cloud-scale distribution. The observations were carried out with the Effelsberg 100 m telescope. The CH emission is found to be extended over the whole region of HCL2. It is brighter in the southeastern part, which encloses the TMC-1 cyanopolyyne peak than in the northwestern part. Its distribution extends continuously from the peak of the neutral carbon emission (CI peak) to the TMC-1 ridge, as if it were connecting the distributions of the [C I] and C$^{18}$O emissions. Since CH is an intermediate in gas-phase chemical reactions from C to CO, its emission should trace the transition region. The above distribution of the CH emission is consistent with this chemical behavior. Since the CH abundance is subject to the chemical evolutionary effect, the CH column density in HCL2 no longer follows a linear correlation wit the H$_2$ column density reported for diffuse and translucent clouds. More importantly, the CH line profile is found to be composed of the narrow and broad components. Although the broad component is dominant around the CI peak, the narrow component appears in the TMC-1 ridge and dense core regions such as L1527 and TMC-1A. This trend seems to reflect a narrowing of the line width during the formation of dense cores. These results suggest that the 3.3 GHz CH line is a useful tool for tracing the chemical and physical evolution of molecular clouds.Comment: 8 page

Mid-infrared spectra of PAH emission in Herbig AeBe stars

We present spectra of four Herbig AeBe stars obtained with the Infrared Spectrograph (IRS). on the Spitzer Space Telescope. All four of the sources show strong emission from polycyclic aromatic hydrocarbons (PAHs), with the 6.2 um emission feature shifted to 6.3 um and the strongest C-C skeletal-mode feature occuring at 7.9 um instead of at 7.7 um as is often seen. Remarkably, none of the four stars have silicate emission. The strength of the 7.9 um feature varies with respect to the 11.3 um feature among the sources, indicating that we have observed PAHs with a range of ionization fractions. The ionization fraction is higher for systems with hotter and brighter central stars. Two sources, HD 34282 and HD 169142, show emission features from aliphatic hydrocarbons at 6.85 and 7.25 um. The spectrum of HD 141569 shows a previously undetected emission feature at 12.4 um which may be related to the 12.7 um PAH feature. The spectrum of HD 135344, the coolest star in our sample, shows an unusual profile in the 7-9 um region, with the peak emission to the red of 8.0 um and no 8.6 um PAH feature.Comment: Accepted by ApJ 23 June, 2005, 8 pages (emulateapj), 5 figures (3 in color

W Hya : molecular inventory by ISO-SWS

Infrared spectroscopy is a powerful tool to probe the inventory of solid state and molecular species in circumstellar ejecta. Here we analyse the infrared spectrum of the Asymptotic Giant Branch star W Hya, obtained by the Short and Long Wavelength Spectrometers on board of the Infrared Satellite Observatory. These spectra show evidence for the presence of amorphous silicates, aluminum oxide, and magnesium-iron oxide grains. We have modelled the spectral energy distribution using laboratory measured optical properties of these compounds and derive a total dust mass loss rate of 3E-10 Msol/yr. We find no satisfactory fit to the 13 micron dust emission feature and the identification of its carrier is still an open issue. We have also modelled the molecular absorption bands due to H2O, OH, CO, CO2, SiO, and SO2 and estimated the excitation temperatures for different bands which range from 300 to 3000K. It is clear that different molecules giving rise to these absorption bands originate from different gas layers. We present and analyse high resolution Fabry-Perot spectra of the three CO2 bands in the 15 micron region. In these data, the bands are resolved into individual Q-lines in emission, which allows the direct determination of the excitation temperature and column density of the emitting gas. This reveals the presence of a warm (about 450K) extended layer of CO2, somewhere between the photosphere and the dust formation zone. The gas in this layer is cooler than the 1000K CO2 gas responsible for the low-resolution absorption bands at 4.25 and 15 micron. The rotational and vibrational excitation temperatures derived from the individual Q-branch lines of CO2 are different (450K and 150K, respectively) so that the CO2 level population is not in LTE.Comment: To appear in Astronomy and Astrophysics A reference is adde

Constraint methods for determining pathways and free energy of activated processes

Activated processes from chemical reactions up to conformational transitions of large biomolecules are hampered by barriers which are overcome only by the input of some free energy of activation. Hence, the characteristic and rate-determining barrier regions are not sufficiently sampled by usual simulation techniques. Constraints on a reaction coordinate r have turned out to be a suitable means to explore difficult pathways without changing potential function, energy or temperature. For a dense sequence of values of r, the corresponding sequence of simulations provides a pathway for the process. As only one coordinate among thousands is fixed during each simulation, the pathway essentially reflects the system's internal dynamics. From mean forces the free energy profile can be calculated to obtain reaction rates and insight in the reaction mechanism. In the last decade, theoretical tools and computing capacity have been developed to a degree where simulations give impressive qualitative insight in the processes at quantitative agreement with experiments. Here, we give an introduction to reaction pathways and coordinates, and develop the theory of free energy as the potential of mean force. We clarify the connection between mean force and constraint force which is the central quantity evaluated, and discuss the mass metric tensor correction. Well-behaved coordinates without tensor correction are considered. We discuss the theoretical background and practical implementation on the example of the reaction coordinate of targeted molecular dynamics simulation. Finally, we compare applications of constraint methods and other techniques developed for the same purpose, and discuss the limits of the approach

The time variation in infrared water-vapour bands in Mira variables

The time variation in the water-vapour bands in oxygen-rich Mira variables has been investigated using multi-epoch ISO/SWS spectra of four Mira variables in the 2.5-4.0 micron region. All four stars show H2O bands in absorption around minimum in the visual light curve. At maximum, H2O emission features appear in the ~3.5-4.0 micronm region, while the features at shorter wavelengths remain in absorption. These H2O bands in the 2.5-4.0 micron region originate from the extended atmosphere. The analysis has been carried out with a disk shape, slab geometry model. The observed H2O bands are reproduced by two layers; a `hot' layer with an excitation temperature of 2000 K and a `cool' layer with an excitation temperature of 1000-1400 K. The radii of the `hot' layer (R_hot) are ~1 R_* at visual minimum and 2 R_* at maximum, where R_* is a radius of background source of the model. The time variation of R_hot/R_* from 1 to 2 is attributed to the actual variation in the radius of the H2O layer. A high H2O density shell occurs near the surface of the star around minimum, and moves out with the stellar pulsation. This shell gradually fades away after maximum, and a new high H2O density shell is formed in the inner region again at the next minimum. Due to large optical depth of H2O, the near-infrared variability is dominated by the H2O layer, and the L'-band flux correlates with the area of the H2O shell. The infrared molecular bands trace the structure of the extended atmosphere and impose appreciable effects on near-infrared light curve of Mira variables.Comment: 15 pages, 16 figures, accepted by A&