Intensity dependences of the nonlinear optical excitation of plasmons in graphene

Recently, we demonstrated an all-optical coupling scheme for plasmons, which takes advantage of the intrinsic nonlinear optical response of graphene. Frequency mixing using free-space, visible light pulses generates surface plasmons in a planar graphene sample, where the phase matching condition can define both the wavevector and energy of surface waves and intraband transitions. Here, we also show that the plasmon generation process is strongly intensity-dependent, with resonance features washed out for absorbed pulse fluences greater than 0.1 J m−2. This implies a subtle interplay between the nonlinear generation process and sample heating. We discuss these effects in terms of a non-equilibrium charge distribution using a two-temperature model.Peer ReviewedPostprint (author's final draft

Chemical Speciation of Copper in a Salt Marsh Estuary and Bioavailability to Thaumarchaeota

The concentrations of dissolved copper (Cud), copper-binding ligands, thiourea-type thiols, and humic substances (HSCu) were measured in estuarine waters adjacent to Sapelo Island, Georgia, USA, on a monthly basis from April to December 2014. Here we present the seasonal cycle of copper speciation within the estuary and compare it to the development of an annually occurring bloom of Ammonia Oxidizing Archaea (AOA), which require copper for many enzymes. Two types of complexing ligands (L1 and L2) were found to dominate with mean complex stabilities (log KCuL′) of 14.5 and 12.8. Strong complexation resulted in lowering the concentration of free cupric ion (Cu2+) to femtomolar (fM) levels throughout the study and to sub-fM levels during the summer months. A Thaumarchaeota bloom during this period suggests that this organism manages to grow at very low Cu2+ concentrations. Correlation of the concentration of the L1 ligand class with a thiourea-type thiol and the L2 ligand class with HSCu provide an interesting dimension to the identity of the ligand classes. Due to the stronger complex stability, 82–99% of the copper was bound to L1. Thiourea-type thiols typically form Cu(I) species, which would suggest that up to ~90% copper could be present as Cu(I) in this region. In view of the very low concentration of free copper (pCu > 15 at the onset and during the bloom) and a reputedly high requirement for copper, it is likely that the Thaumarchaeota are able to access thiol-bound copper directly

“The missing lights of Nairobi”: Cyclists' Perceptions of safety by cycling after-dark in Nairobi, Kenya

Promotion of cycling is important to reach the goals for climate mitigation of the Paris Agreement and Goals ofthe Agenda 2030. Sustainable transport, both rural and urban, could contribute to at least seven of the 17 Sustainable Development Goals (ITDP 2015). There is relatively little research on cycling in Africa, and there is also much less research on cycling at night. Some studies show the importance of road lighting for minimising the reduction in the numbers of cyclists after-dark and suggest 'only a minimal amount of lighting can promote cycling after-dark, making it an attractive mode of transport year-round' (Uttley at el. 2020). So far, these studies have little relation to the situation in developing countries, which is why a first study in Nairobi, Kenya, is carried out here as an example. ... [From: Introduction

Ethnicity, Job Search and Labor Market Reintegration of the Unemployed

This paper is based on recently collected and rich survey data of a representative sample of entrants into unemployment in Germany. Our data include a large number of migration variables, allowing us to adapt a recently developed concept of ethnic identity: the ethnosizer. To shed further light on the native-migrant differences in economic outcomes, we investigate the labor market reintegration, patterns of job search, and reservation wages across unemployed migrants and natives in Germany. Our results indicate that separated migrants have a relatively slow reintegration into the labor market. We explain this finding by arguing that this group exerts a relatively low search effort and that it has reservation wages which are moderate, yet still above the level which would imply similar employment probabilities as other groups of migrants

Practice of spirometry among physicians caring for children with asthma in Portugal - The EspiroPed survey

info:eu-repo/semantics/publishedVersio

Origins of All-Optical Generation of Plasmons in Graphene

This is the final version. Available on open access from Nature Research via the DOI in this recordGraphene, despite its centrosymmetric structure, is predicted to have a substantial second order nonlinearity, arising from non-local effects. However, there is disagreement between several published theories and experimental data. Here we derive an expression for the second order conductivity of graphene in the non-local regime using perturbation theory, concentrating on the difference frequency mixing process, and compare our results with those already published. We find a second-order conductivity (σ (2)≈ 10−17AmV−2 ) that is approximately three orders of magnitude less than that estimated from recent experimental results. This indicates that nonlinear optical coupling to plasmons in graphene cannot be described perturbatively through the electronic nonlinearity, as previously thought. We also show that this discrepancy cannot be attributed to the bulk optical nonlinearity of the substrate. As a possible alternative, we present a simple theoretical model of how a non-linearity can arise from phFundacio Privada Cellex, Spanish MINECO Severo Ochoa ProgrammeCERCA Programme/Generalitat de CatalunyaEngineering and Physical Sciences Research Council (EPSRC)Royal SocietyTATAEuropean Commissio

VEGF preconditioning leads to stem cell remodeling and attenuates age-related decay of adult hippocampal neurogenesis

Several factors are known to enhance adult hippocampal neurogenesis but a factor capable of inducing a long-lasting neurogenic enhancement that attenuates age-related neurogenic decay has not been described. Here, we studied hippocampal neurogenesis following conditional VEGF induction in the adult brain and showed that a short episode of VEGF exposure withdrawn shortly after the generation of durable new vessels (but not under conditions where newly made vessels failed to persist) is sufficient for neurogenesis to proceed at a markedly elevated level for many months later. Continual neurogenic increase over several months was not accompanied by accelerated exhaustion of the neuronal stem cell (NSC) reserve, thereby allowing neurogenesis to proceed at a markedly elevated rate also in old mice. Neurogenic enhancement by VEGF preconditioning was, in part, attributed to rescue of age-related NSC quiescence. Remarkably, VEGF caused extensive NSC remodelling manifested in transition of the enigmatic NSC terminal arbor onto long cytoplasmic processes engaging with and spreading over even remote blood vessels, a configuration reminiscent of early postnatal "juvenile" NSCs. Together, these findings suggest that VEGF preconditioning might be harnessed for long-term neurogenic enhancement despite continued exposure to an "aged" systemic milieu