Interplay of bulk and surface properties for steady-state measurements of minority carrier lifetimes

The measurement of the minority carrier lifetime is a powerful tool in the field of semiconductor material characterization as it is very sensitive to electrically active defects. Furthermore, it is applicable to a wide range of samples such as ingots or wafers. In this work, a systematic theoretical analysis of the steady-state approach is presented. It is shown how the measured lifetime relates to the intrinsic bulk lifetime for a given material quality, sample thickness, and surface passivation. This makes the bulk properties experimentally accessible by separating them from the surface effects. In particular, closed analytical solutions of the most important cases, such as passivated and unpassivated wafers and blocks are given. Based on these results, a criterion for a critical sample thickness is given beyond which a lifetime measurement allows deducing the bulk properties for a given surface recombination. These results are of particular interest for semiconductor material diagnostics especially for photovoltaic applications but not limited to this field.Comment: 17 pages, 3 figure

Evidence for a broadly distributed Samoan-plume signature in the northern Lau and North Fiji Basins

Author Posting. © American Geophysical Union, 2014. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry, Geophysics, Geosystems 15 (2014): 986–1008, doi:10.1002/2013GC005061.Geochemical enrichment of lavas in the northern Lau Basin may reflect the influx of Samoan-plume mantle into the region. We report major and trace element abundances and He-Sr-Nd-Hf-Pb-isotopic measurements for 23 submarine volcanic glasses covering 10 locations in the northern Lau and North Fiji Basins, and for three samples from Wallis Island, which lies between Samoa and the Lau Basin. These data extend the western limit of geochemical observations in the Basins and improve the resolution of North-South variations in isotopic ratios. The Samoan hot spot track runs along the length of the northern trace of the Lau and North Fiji Basins. We find evidence for a Samoan-plume component in lavas as far West as South Pandora Ridge (SPR), North Fiji Basin. Isotopic signatures in SPR samples are similar to those found in Samoan Upolu shield lavas, but show a slight shift toward MORB-like compositions. We explain the origin of the enriched signatures by a model in which Samoan-plume material and ambient depleted mantle undergo decompression melting during upwelling after transiting from beneath the thick Pacific lithosphere to beneath the thin lithosphere in the northern Lau and North Fiji Basins. Other lavas found in the region with highly depleted isotopic signatures may represent isolated pockets of depleted mantle in the basins that evaded this enrichment process. We further find that mixing between the two components in our model, a variably degassed high-3He/4He Samoan component and depleted MORB, can explain the diversity among geochemical data from the northern Lau Basin.M.G.J. acknowledges support from NSF grants OCE-1061134, OCE-1153894, and EAR-1145202 and J.B.T. acknowledges support from the French Agence Nationale de la Recherche (grant ANR-10-BLANC-0603 M&Ms—Mantle Melting—Measurements, Models, Mechanisms).2014-10-1

Multiple expressions of plume-ridge interaction in the Galapagos : volcanic lineaments and ridge jumps

Author Posting. © American Geophysical Union, 2012. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 13 (2012): Q05018, doi:10.1029/2012GC004093.Anomalous volcanism and tectonics between near-ridge mantle plumes and mid-ocean ridges provide important insights into the mechanics of plume-lithosphere interaction. We present new observations and analysis of multibeam, side scan sonar, sub-bottom chirp, and total magnetic field data collected during the R/V Melville FLAMINGO cruise (MV1007; May–June, 2010) to the Northern Galápagos Volcanic Province (NGVP), the region between the Galápagos Archipelago and the Galápagos Spreading Center (GSC) on the Nazca Plate, and to the region east of the Galápagos Transform Fault (GTF) on the Cocos Plate. The NGVP exhibits pervasive off-axis volcanism related to the nearby Galápagos hot spot, which has dominated the tectonic evolution of the region. Observations indicate that ~94% of the excess volcanism in our survey area occurs on the Nazca Plate in three volcanic lineaments. Identified faults in the NGVP are consistent with normal ridge spreading except for those within a ~60 km wide swath of transform-oblique faults centered on the GTF. These transform-oblique faults are sub-parallel to the elongation direction of larger lineament volcanoes, suggesting that lineament formation is influenced by the lithospheric stress field. We evaluate current models for lineament formation using existing and new observations as well as numerical models of mantle upwelling and melting. The data support a model where the lithospheric stress field controls the location of volcanism along the lineaments while several processes likely supply melt to these eruptions. Synthetic magnetic models and an inversion for crustal magnetization are used to determine the tectonic history of the study area. Results are consistent with creation of the GTF by two southward ridge jumps, part of a series of jumps that have maintained a plume-ridge separation distance of 145 km to 215 km since ~5 Ma.This work was supported by NSF grant OCE-0926637 and OCE-1030904 to DF and KH. DG’s work was supported by NSF grants EAR- 0838461 and EAR-1145271. Additional support was provided to E.M. by the Deep Ocean Exploration Institute at the Woods Hole Oceanographic Institution.2012-11-3

Microfluidic systems for the analysis of the viscoelastic fluid flow phenomena in porous media

In this study, two microfluidic devices are proposed as simplified 1-D microfluidic analogues of a porous medium. The objectives are twofold: firstly to assess the usefulness of the microchannels to mimic the porous medium in a controlled and simplified manner, and secondly to obtain a better insight about the flow characteristics of viscoelastic fluids flowing through a packed bed. For these purposes, flow visualizations and pressure drop measurements are conducted with Newtonian and viscoelastic fluids. The 1-D microfluidic analogues of porous medium consisted of microchannels with a sequence of contractions/ expansions disposed in symmetric and asymmetric arrangements. The real porous medium is in reality, a complex combination of the two arrangements of particles simulated with the microchannels, which can be considered as limiting ideal configurations. The results show that both configurations are able to mimic well the pressure drop variation with flow rate for Newtonian fluids. However, due to the intrinsic differences in the deformation rate profiles associated with each microgeometry, the symmetric configuration is more suitable for studying the flow of viscoelastic fluids at low De values, while the asymmetric configuration provides better results at high De values. In this way, both microgeometries seem to be complementary and could be interesting tools to obtain a better insight about the flow of viscoelastic fluids through a porous medium. Such model systems could be very interesting to use in polymer-flood processes for enhanced oil recovery, for instance, as a tool for selecting the most suitable viscoelastic fluid to be used in a specific formation. The selection of the fluid properties of a detergent for cleaning oil contaminated soil, sand, and in general, any porous material, is another possible application

Magmatic plumbing at Lucky Strike volcano based on olivine-hosted melt inclusion compositions

Author Posting. © American Geophysical Union, 2015. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry, Geophysics, Geosystems 16 (2015): 126–147, doi:10.1002/2014GC005517.Here we present volatile, major, and trace element concentrations of 64 olivine-hosted melt inclusions from the Lucky Strike segment on the mid-Atlantic ridge. Lucky Strike is one of two locations where a crustal melt lens has been seismically imaged on a slow-spreading ridge. Vapor-saturation pressures, calculated from CO2 and H2O contents of Lucky Strike melt inclusions, range from approximately 300–3000 bars, corresponding to depths of 0.5–9.9 km below the seafloor. Approximately 50% of the melt inclusions record crystallization depths of 3–4 km, corresponding to the seismically imaged melt lens depth, while an additional ∼35% crystallize at depths > 4 km. This indicates that while crystallization is focused within the melt lens, significant crystallization also occurs in the lower crust and/or upper mantle. The melt inclusions span a range of major and trace element concentrations from normal to enriched basalts. Trace element ratios at all depths are heterogeneous, suggesting that melts are not efficiently homogenized in the mantle or crust, despite the presence of a melt lens. This is consistent with the transient nature of magma chambers proposed for slower-spreading ridges. To investigate the petrogenesis of the melt inclusion compositions, we compare the measured trace element compositions to theoretical melting calculations that consider variations in the melting geometry and heterogeneities in the mantle source. The full range of compositions can be produced by slight variations in the proportion of an Azores plume and depleted upper mantle components and changes in the total extent of melting.thanked for his help with sample preparation. The GRAVILUCK'06 and Bathyluck'08 cruises where financed by the French Ministry of Research. This work was supported by NSF grant OCE-0926422 to A.M.S., OCE-PRF-1226130 to V.D.W., OCE-1333492 to S.A.S., and EAR-09-48666 to M.D.B., and by ANR (France) Mothseim Project NT05-342213 to J.E.2015-07-2

Optimization of KOH etching process to obtain textured substrates suitable for heterojunction solar cells fabricated by HWCVD

In this work, we have studied the texturization process of (100) c-Si wafers using a low concentration potassium hydroxide solution in order to obtain good quality textured wafers. The optimization of the etching conditions have led to random but uniform pyramidal structures with good optical properties. Then, symmetric heterojunctions were deposited by Hot-Wire CVD onto these substrates and the Quasi-Steady-State PhotoConductance technique was used to measure passivation quality. Little degradation in the effective lifetime and implicit open circuit voltage of these devices (< 20 mV) was observed in all cases. It is especially remarkable that for big uniform pyramids, the open-circuit voltage is comparable to the values obtained on flat substrates

Quantitative imaging of concentrated suspensions under flow

We review recent advances in imaging the flow of concentrated suspensions, focussing on the use of confocal microscopy to obtain time-resolved information on the single-particle level in these systems. After motivating the need for quantitative (confocal) imaging in suspension rheology, we briefly describe the particles, sample environments, microscopy tools and analysis algorithms needed to perform this kind of experiments. The second part of the review focusses on microscopic aspects of the flow of concentrated model hard-sphere-like suspensions, and the relation to non-linear rheological phenomena such as yielding, shear localization, wall slip and shear-induced ordering. Both Brownian and non-Brownian systems will be described. We show how quantitative imaging can improve our understanding of the connection between microscopic dynamics and bulk flow.Comment: Review on imaging hard-sphere suspensions, incl summary of methodology. Submitted for special volume 'High Solid Dispersions' ed. M. Cloitre, Vol. xx of 'Advances and Polymer Science' (Springer, Berlin, 2009); 22 pages, 16 fig