Quantitative plane-resolved crystal growth and dissolution kinetics by coupling in situ optical microscopy and diffusion models : the case of salicylic acid in aqueous solution

The growth and dissolution kinetics of salicylic acid crystals are investigated in situ by focusing on individual microscale crystals. From a combination of optical microscopy and finite element method (FEM) modeling, it was possible to obtain a detailed quantitative picture of dissolution and growth dynamics for individual crystal faces. The approach uses real-time in situ growth and dissolution data (crystal size and shape as a function of time) to parametrize a FEM model incorporating surface kinetics and bulk to surface diffusion, from which concentration distributions and fluxes are obtained directly. It was found that the (001) face showed strong mass transport (diffusion) controlled behavior with an average surface concentration close to the solubility value during growth and dissolution over a wide range of bulk saturation levels. The (1̅10) and (110) faces exhibited mixed mass transport/surface controlled behavior, but with a strong diffusive component. As crystals became relatively large, they tended to exhibit peculiar hollow structures in the end (001) face, observed by interferometry and optical microscopy. Such features have been reported in a number of crystals, but there has not been a satisfactory explanation for their origin. The mass transport simulations indicate that there is a large difference in flux across the crystal surface, with high values at the edge of the (001) face compared to the center, and this flux has to be redistributed across the (001) surface. As the crystal grows, the redistribution process evidently can not be maintained so that the edges grow at the expense of the center, ultimately creating high index internal structures. At later times, we postulate that these high energy faces, starved of material from solution, dissolve and the extra flux of salicylic acid causes the voids to close

Bedbugs evolved before their bat hosts and did not co-speciate with ancient humans

All 100+ bedbug species (Cimicidae) are obligate blood-sucking parasites [1, 2]. In general, blood sucking (hematophagy) is thought to have evolved in generalist feeders adventitiously taking blood meals [3, 4], but those cimicid taxa currently considered ancestral are putative host specialists [1, 5]. Bats are believed to be the ancestral hosts of cimicids [1], but a cimicid fossil [6] predates the oldest known bat fossil [7] by >30 million years (Ma). The bedbugs that parasitize humans [1, 8] are host generalists, so their evolution from specialist ancestors is incompatible with the "resource efficiency" hypothesis and only partially consistent with the "oscillation" hypothesis [9-16]. Because quantifying host shift frequencies of hematophagous specialists and generalists may help to predict host associations when vertebrate ranges expand by climate change [17], livestock, and pet trade in general and because of the previously proposed role of human pre-history in parasite speciation [18-20], we constructed a fossil-dated, molecular phylogeny of the Cimicidae. This phylogeny places ancestral Cimicidae to 115 mya as hematophagous specialists with lineages that later frequently populated bat and bird lineages. We also found that the clades, including the two major current urban pests, Cimex lectularius and C. hemipterus, separated 47 mya, rejecting the notion that the evolutionary trajectories of Homo caused their divergence [18-21]

Carbon dioxide fluxes increase from day to night across European streams

Globally, inland waters emit over 2 Pg of carbon per year as carbon dioxide, of which the majority originates from streams and rivers. Despite the global significance of fluvial carbon dioxide emissions, little is known about their diel dynamics. Here we present a large-scale assessment of day- and night-time carbon dioxide fluxes at the water-air interface across 34 European streams. We directly measured fluxes four times between October 2016 and July 2017 using drifting chambers. Median fluxes are 1.4 and 2.1 mmol m−2 h−1 at midday and midnight, respectively, with night fluxes exceeding those during the day by 39%. We attribute diel carbon dioxide flux variability mainly to changes in the water partial pressure of carbon dioxide. However, no consistent drivers could be identified across sites. Our findings highlight widespread day-night changes in fluvial carbon dioxide fluxes and suggest that the time of day greatly influences measured carbon dioxide fluxes across European streams

Approximate Bounds and Expressions for the Link Utilization of Shortest-Path Multicast Network Traffic

Multicast network traffic is information with one source node, but many destination nodes. Rather than setting up individual connections between the source node and each destination node, or broadcasting the information to the entire network, multicasting efficiently exploits link capacity by allowing the source node to transmit a small number of copies of the information to mutually-exclusive groups of destination nodes. Multicasting is an important topic in the fields of networking (video and audio conferencing, video on demand, local-area network interconnection) and computer architecture (cache coherency, multiprocessor message passing). In this paper, we derive approximate expressions for the minimum cost (in terms of link utilization) of shortestpath multicast traffic in arbitrary tree networks. Our results provide a theoretical best-case scenario for link utilization of multicast distribution in tree topologies overlaid onto arbitrary graphs. In real networks such as the Interne..

Approximate bounds and expressions for the link utilization of shortest-path multicast network traffic

Multicast network traffic is information with one source node, but many destination nodes. Rather than setting up individual connections between the source node and each destination node, or broadcasting the information to the entire network, multicasting efficiently exploits link capacity by allowing the source node to transmit a small number of copies of the information to mutually-exclusive groups of destination nodes. Multicasting is an important topic in the fields of networking (video and audio conferencing, video on demand, local-area network interconnection) and computer architecture (cache coherency, multiprocessor message passing). In this paper, we derive approximate expressions for the minimum cost (in terms of link utilization) of shortest-path multicast traffic in arbitrary tree networks. Our results provide a theoretical best-case scenario for link utilization of multicast distribution in tree topologies overlaid onto arbitrary graphs. In real networks such as the Internet MBONE, multicast distribution paths are often tree-like, but contain some cycles for purposes of fault tolerance. We find that even for richly-connected graphs such as the shufflenet and the hypercube, our expression provides a good prediction of the cost (in terms of link utilization) of multicast communication. Thus, this theoretical result has two applications: (1) a lower bound on the link capacity required for multicasting in random tree topologies, and (2) an approximation of the cost o

Ion -Beam Induced Crystallization and Amorphization in Zn+ implanted Silicon

The microstructural changes which occur during high dose Zn+ irradiation of (100) Si have been studied by electron microscopy both in diffraction (TEM) and in phase contrast (HRTEM) together with other experimental techniques and computer simulation of the implantation process. The samples have bee implanted at 50 keV with a current density of 10 microA/cm^2 and a dose ranging from 10^15 cm^-2 to 10^18 cm^-2. The characterization evidences that Zn-Si superlattice is formed depending on the implanted dose

Ion-Beam Assisted Nanocrystal Formation in Silicon Implanted with High doses of Pb+ and Bi+ Ions

In this paper we discuss ion-beam-assisted nanocrystal nucleation in amorphized silicon (a-Si) layers produced by high-dose implantation of Pb+ and Bi+. (100)-oriented Si wafers were implanted at room temperature (RT) with 50 keV Pb+ and Bi+ ions at doses ranging from 5×1013 to 1×1018 cm-2 and a constant ion current density of 10 µA cm-2. The resulting structures were studied by conventional transmission electron microscopy (CTEM), high resolution transmission electron microscopy (HRTEM) and Rutherford backscattering spectroscopy (RBS) in combination with computer simulations. The dynamics of the ion-beam-induced crystallization of new phases and precipitates evolution in the implanted layer were studied as a function of implant dose. It is established that the front of the new phase crystallization (cubic Pb and hexagonal Bi nanocrystals) starts approximately at the peaks of the implanted species profiles; the crystallography of the nucleated nanocrystal is examined as a function of the dose