Kinetics of U(VI) reduction control kinetics of U(IV) reoxidation

For the in situ reductive immobilization of U to be an acceptable strategy for the removal of that element from groundwater, the long-term stability of U(IV) must be determined. Rates of biotransformation of Fe species influence the mineralogy of the resulting products (Fredrickson et al., 2003; Senko et al., 2005), and we hypothesize that the rate of U(VI) reduction influences the mineralogy of resultant U(IV) precipitates. We hypothesize that slower rates of U(VI) reduction will yield U(IV) phases that are more resistant to reoxidation, and will therefore be more stable upon cessation of electron donor addition. U(IV) phases formed by relatively slow reduction may be more crystalline or larger in comparison to their relatively rapidly-formed counterparts (Figure 1), thus limiting the reactivity of slowly-formed U(IV) phases toward various oxidants. The physical location of U(IV) precipitates relative to bacterial cells may also limit the reactivity of biogenic U(IV) phases. In this situation, we expect that precipitation of U(IV) within the bacterial cell may protect U(IV) from reoxidation by limiting physical contact between U(IV) and oxidants (Figure 1). We assessed the effect of U(VI) reduction rate on the subsequent reoxidation of biogenic U(IV) and are currently conducting column scale studies to determine whether U(VI) reduction rate can be manipulated by varying the electron donor concentration used to stimulate U(VI) reduction

Sulfate reduction at low pH to remediate acid mine drainage

Industrial activities and the natural oxidation of metallic sulfide-ores produce sulfate-rich waters with low pH and high heavy metals content, generally termed acid mine drainage (AMD). This is of great environmental concern as some heavy metals are highly toxic. Within a number of possibilities, biological treatment applying sulfate-reducing bacteria (SRB) is an attractive option to treat AMD and to recover metals. The process produces alkalinity, neutralizing the AMD simultaneously. The sulfide that is produced reacts with the metal in solution and precipitates them as metal sulfides. Here, important factors for biotechnological application of SRB such as the inocula, the pH of the process, the substrates and the reactor design are discussed. Microbial communities of sulfidogenic reactors treating AMD which comprise fermentative-, acetogenic- and SRB as well as methanogenic archaea are reviewed.Research was financed by grants of the divisions CW (Project 700.55.343) of the Netherlands Science Foundation (NWO) and ERC (Project 323009). Irene Sanchez-Andrea acknowledges the grant from the graduate school WIMEK SENSE

Measurement of trilinear gauge boson couplings WWV, (V = Z, gamma) in e+ e- collisions at 189-GeV

Measurements of the trilinear gauge boson couplings WWgamma and WWZ are presented using the data taken by DELPHI in 1998 at a centre-of-mass energy of 189 GeV and combined with DELPHI data at 183 GeV. Values are determined for Delta(g_1^Z) and Delta(kappa_gamma), the differences of the WWZ charge coupling and of the WWgamma dipole coupling from their Standard Model values, and for lambda_gamma, the WWgamma quadrupole coupling. A measurement of the magnetic dipole and electric quadrupole moment of the W is extracted from the results for Delta(kappa_gamma) and lambda_gamma. The study uses data from the final states jjlv, jjjj, lX, jjX and gammaX, where j represents a quark jet, l an identified lepton and X missing four-momentum. The observations are consistent with the predictions of the Standard Model.Comment: 20 pages, 4 figures, Accepted by Phys. Lett.