Melt inclusion constraints on the magma source of Eyjafjallajökull 2010 flank eruption

International audienc

Bottom-up vs top-down drivers of eruption style: Petro-geochemical constraints from the holocene explosive activity at La Soufrière de Guadeloupe

Signals of volcanic unrest have been used successfully to provide insights into the timing, magnitude, intensity, and style of future eruptions. However, in order to provide context for the subsequent activity, analysis of past eruptions is required. This provides useful information in order to understand processes of magma genesis, storage, evolution and ascent which lead to the onset of eruptions. Here, we examine basaltic-andesitic to andesitic deposits from La Soufrière de Guadeloupe Holocene eruptions, covering a range of explosive eruption styles, ages and magnitudes. Our work is timely given unrest at this system has increased over the last 25 years, with a potential eruption capable of directly impacting up to 80,000 people in Southern Basse-Terre and potentially thousands more indirectly on a regional scale. We report on the geochemistry of pre-eruptive magmas using detailed analyses of glass (melt inclusions and groundmass glass) from four Holocene explosive eruptions: 1657 Cal. CE (Vulcanian, VEI 2), 1530 Cal. CE (sub-Plinian, VEI 3), 1010 Cal. CE (Plinian, VEI 4), and 5680 Cal. BCE (Plinian, VEI 4). Major element concentrations vs SiO2 in whole rock (WR), groundmass glass (GM) and melt inclusions (MI) show a strong linear trend. MIs reveal a relatively homogenous melt composition from the first to the most recent eruptions, ranging from 63.6–78.7 wt% SiO2. Volatiles, including H2O (2.3–4.4 wt%), CO2 (35–866 ppm) and sulphur (30–202 ppm), are also consistent across the various eruptions. The major element and volatile compositional homogeneity across the eruptions indicates that composition and volatiles do not have a direct control on eruption explosivity at this system. Instead, we find differences in ascent rate, groundmass glass viscosity and microlite volume percentage, indicating that explosive eruptive style at La Soufrière is controlled by a combination of ascent rate and top-down controls affecting rock strength, stress distribution and the development of fluid overpressure. Rapid ascent in the absence of top-down controls (processes with a cause external to the magma but affecting the plumbing system) will result in explosive eruptions driven from the bottom-up (internal to magma dynamic response with varying pressure and temperature, e.g., 1010 Cal. CE in the case of very rapid ascent or 1657 Cal. CE in the case of rapid ascent). However, we also highlight the importance of top-down controls, such as conduit sealing which can promote the onset of explosive eruptions, even in the case of slow magma ascent (e.g., 5680 Cal. BCE). External effects (including ingress of water and rapid edifice unloading) can also favour explosive eruptions with flank collapses involved in some scenarios (e.g., 1530 Cal. CE). The multiple controls on explosive eruption style make this system more hazardous and complex to model and monitor. In order to improve early-warning system efficiency, forecast models, eruption scenario crisis response and long-term risk reduction planning, we stress that internal processes such as fracture and host-rock sealing (fluid pore pressure) as well as external processes such as water moving into the system and the mechanical stability of the edifice should be monitored and modelled closely

Sr–Pb isotopes signature of Lascar volcano (Chile): Insight into contamination of arc magmas ascending through a thick continental crust

co-auteur étrangerInternational audienc

Corrigendum to "Gas and aerosol emissions from Lascar volcano (Northern Chile): Insights into the origin of gases and their links with the volcanic activity" [J. Volcanol. Geoth. Res. 287 (2014) 51-67]

International audienceThe authors regret that an error occurred whilst converting the SO2 normalized mass ratios to trace gas fluxes. This implies that Lascar volcanic gas fluxes, shown in Table 6 and discussed in Section 5.1.2.2, are lower than previously estimated. The correct trace element emission rate estimates are now presented in the Table below. The average rates over the 2009-2012 period range from 0.1 g/day (In) to 324 g/day (As), suggesting that Lascar does not represent such a significant local source of pollutants for the environment

How the N-terminal extremity of Saccharomyces cerevisiae IF1 interacts withe ATP synthase : A kinetic approach

AbstractThe N-terminal part of the inhibitory peptide IF1 interacts with the central γ subunit of mitochondrial isolated extrinsic part of ATP synthase in the inhibited complex (J.R. Gledhill, M.G. Montgomery, G.W. Leslie, J.E. Walker, 2007). To explore its role in the different steps of IF1 binding, kinetics of inhibition of the isolated and membrane-bound enzymes were investigated using Saccharomyces cerevisiae IF1 derivatives modified in N-terminal extremity. First, we studied peptides truncated in Nter up to the amino acid immediately preceding Phe17, a well-conserved residue thought to play a key role. These deletions did not affect or even improve the access of IF1 to its target. They decreased the stability of the inhibited complex but much less than previously proposed. We also mutated IF1-Phe17 and found this amino acid not mandatory for the inhibitory effect. The most striking finding came from experiments in which PsaE, a 8kDa globular-like protein, was attached in Nter of IF1. Unexpectedly, such a modification did not appreciably affect the rate of IF1 binding. Taken together, these data show that IF1-Nter plays no role in the recognition step but contributes to stabilize the inhibited complex. Moreover, the data obtained using chimeric PsaE-IF1 suggest that before binding IF1 presents to the enzyme with its middle part facing a catalytic interface and its Nter extremity folded in the opposite direction

The sulfur budget of the 2011 Grimsvötn eruption, Iceland

Sulfur concentrations have been measured in 28 melt inclusions (MIs) in plagioclase, clinopyroxene, and olivine crystals extracted from tephra produced during the explosive eruption of Grímsvötn in May 2011. The results are compared to sulfur concentrations in the groundmass glass in order to estimate the mass of sulfur brought to surface during the eruption. Satellite measurements yield order of magnitude lower sulfur (~0.2 Tg) in the eruption plume than estimated from the difference between MI and the groundmass glass. This sulfur "deficit" is readily explained by sulfur adhering to tephra grains but principally by sulfide globules caused by basalt-sulfide melt exsolution before degassing. A mass balance calculation reveals that approximately ~0.8 Tg of SO2 is present as globules, representing ~50% of the total sulfur budget. Most of the sulfide globules likely reside at depth due to their elevated density, for potential later remobilization by new magma or hydrothermal circulation. Key Points H2S and SO2 degassing is estimated for the 2011 eruption of Grímsvötn Satellite-based SO2 mass loading is lower than from mineral melt inclusions Half of S resides as sulfide globules; 25% enter the stratosphere ©2013. American Geophysical Union. All Rights Reserved.SCOPUS: ar.jFLWINinfo:eu-repo/semantics/publishe