Solar silicon from directional solidification of MG silicon produced via the silicon carbide route

A process of metallurgical grade (MG) silicon production is presented which appears particularly suitable for photovoltaic (PV) applications. The MG silicon is prepared in a 240 KVA, three electrode submerged arc furnace, starting from high grade quartz and high purity silicon carbide. The silicon smelted from the arc furnace was shown to be sufficiently pure to be directionally solidified to 10 to 15 kg. After grinding and acid leaching, had a material yield larger than 90%. With a MG silicon feedstock containing 3 ppmw B, 290 ppmw Fe, 190 ppmw Ti, and 170 ppmw Al, blended with 50% of off grade electronic grade (EG) silicon to reconduct the boron content to a concentration acceptable for solar cell fabrication, the 99% of deep level impurities were concentrated in the last 5% of the ingot. Quite remarkably this material has OCV values higher tham 540 mV and no appreciable shorts due to SiC particles

Influence of bunch exposure on anthocyanins extractability from grapes skins (Vitis vinifera L.)

In relation to bunch exposure to solar irradiance (sun exposed vs. leaf shaded conditions), anthocyanin ripening and extractability were studied in two grape cultivars ('Croatina' and 'Pinot Noir') coming from three different vineyards in Northern Italy. Analysis of anthocyanin content were carried out by HPLC and spectrophotometry, and a simulated maceration process was developed. Pigments extraction occurred mainly in the first few hours of the maceration process. Anthocyanins with disubstituted B-ring showed a faster extractability than the trisubsituted ones. Bunch exposure to sunlight seemed to be important for pigment extractability timing in winemaking, showing a delay in pigments release. This delay was only partially explained by the different pigments profile, with higher percentage of disubstituted compounds in shaded berries, because all the molecules indicated a similar extraction trend during maceration.

Phenotyping under extreme weather conditions and microsatellite based genotyping of some Hungarian grape cultivars

Phenology is an indicator of plant response to the environment. In viticulture growth stages timing is important for site and cultivar selection, vineyard planning and cultural practices management. In the last years, autochthonous cultivars obtained an increased interest and, therefore, in this work we studied the phenological performances of Hungarian old varieties. The data recorded in 2012 were compared with the ones published 60 years ago. The examined genotypes were identified by SSR markers. Extremely high temperature and low precipitation occurred during the 2012 vintage. The uncommon weather conditions affected the length of the vegetation period less than expected. However, the time period between flowering and harvest decreased significantly. In general, minor varieties seem to be more sensitive to extreme conditions than international cultivars, according to their eno-carpological characteristics

Land mammal colonisation of islands is a multifactorial product; a critic to the unwise use of models

The colonization of islands by terrestrial mammals has been the topic of a flurry of studies. Contributions normally tend to oversimplify the subject, focusing on specific key factors which are allegedly considered the best to explain why, how and when non volant terrestrial mammals reached islands and which are used to devise models. The subjectivity in the choice of key factors understandably leads to controversy and debate. Insular faunas are the multifactorial result of complex combinations of facts, conditions and processes. Hence, the faunal assemblages of each island should be inquired individually, on a case-by-case basis. Models, by definition, are simplified representations of reality, which turn into oversimplifications when reality is so overly complex as it is in islands; yet models are usually considered the unavoidable starting point of investigations. An evidence-based, multidisciplinary approach, instead, is highly recommended. Besides obvious paleontological evidence, we need to carefully inspect geological and stratigraphical information, climatological factors, sealevel evolution, paleogeographic characteristics, ecological, physiological and environmental factors, behavioral characters and ecological preferences, genetics and densities of colonizing populations, as well as taphonomic, sampling and analytical biases. The lack of some of this indispensable information seriously affects the reliability of interpretations and reconstructions

The cellular and synaptic architecture of the mechanosensory dorsal horn

The deep dorsal horn is a poorly characterized spinal cord region implicated in processing low-threshold mechanoreceptor (LTMR) information. We report an array of mouse genetic tools for defining neuronal components and functions of the dorsal horn LTMR-recipient zone (LTMR-RZ), a role for LTMR-RZ processing in tactile perception, and the basic logic of LTMR-RZ organization. We found an unexpectedly high degree of neuronal diversity in the LTMR-RZ: seven excitatory and four inhibitory subtypes of interneurons exhibiting unique morphological, physiological, and synaptic properties. Remarkably, LTMRs form synapses on between four and 11 LTMR-RZ interneuron subtypes, while each LTMR-RZ interneuron subtype samples inputs from at least one to three LTMR classes, as well as spinal cord interneurons and corticospinal neurons. Thus, the LTMR-RZ is a somatosensory processing region endowed with a neuronal complexity that rivals the retina and functions to pattern the activity of ascending touch pathways that underlie tactile perception

Unraveling the performance of dispersion-corrected functionals for the accurate description of weakly bound natural polyphenols

Long-range non-covalent interactions play a key role in the chemistry of natural polyphenols. We have previously proposed a description of supramolecular polyphenol complexes by the B3P86 density functional coupled with some corrections for dispersion. We couple here the B3P86 functional with the D3 correction for dispersion, assessing systematically the accuracy of the new B3P86-D3 model using for that the well-known S66, HB23, NCCE31, and S12L datasets for non-covalent interactions. Furthermore, the association energies of these complexes were carefully compared to those obtained by other dispersion-corrected functionals, such as B(3)LYP-D3, BP86-D3 or B3P86-NL. Finally, this set of models were also applied to a database composed of seven non-covalent polyphenol complexes of the most interest.FDM acknowledges financial support from the Swedish Research Council (Grant No. 621-2014-4646) and SNIC (Swedish National Infrastructure for Computing) for providing computer resources. The work in Limoges (IB and PT) is supported by the “Conseil Régional du Limousin”. PT gratefully acknowledges the support by the Operational Program Research and Development Fund (project CZ.1.05/2.1.00/03.0058 of the Ministry of Education, Youth and Sports of the Czech Republic). IB gratefully acknowledges financial support from “Association Djerbienne en France”

Description of the Vitis vinifera L. phenotypic variability in eno-carpological traits by a Euro-Asiatic collaborative network among ampelographic collections

The grapevine intra-specific variability captured an increasing interest during the last decades, as demonstrated by the number of recently funded European projects focused on the grapevine biodiversity preservation. However, nowadays, crop plants are mainly characterized by genotyping methods. The present work summarizes the phenotype data collected among 20 ampelographic collections spread in 15 countries, covering mostly of the viticultural areas in the Euro-Asiatic range: from Portugal to Armenia and from Cyprus to Luxembourg. Together with agro-climatic characterization of the experimental site, in two years, about 2400 accessions were described, following a common experimental protocol mainly focused on the carpological and oenological traits, obtaining a general overview of the distribution of the considered phenotypic traits in the cultivated Vitis vinifera species. The most replicated cultivars were selected and, for the subset of these reference cultivars, their behavior in the different environmental conditions over sites and years was described by ANOVA methods

Description of the vitis vinifera L. Phenotypic variability in eno-carpological traits by a Euro-Asiatic collaborative network among ampelographic collections

The grapevine intra-specific variability captured an increasing interest during the last decades, as demonstrated by the number of recently funded European projects focused on the grapevine biodiversity preservation. However, nowadays, crop plants are mainly characterized by genotyping methods. The present work summarizes the phenotype data collected among 20 ampelographic collections spread over 15 countries, covering most of the viticultural areas in the Euro-Asiatic region: from Portugal to Armenia and from Cyprus to Luxembourg. Together with agro-climatic characterization of the experimental site, over two years about 2,400 accessions were described. A common experimental protocol mainly focused on the carpological and oe-nological traits was followed, obtaining a general overview of the distribution of the considered phenotypic traits in the cultivated Vitis vinifera species. The most replicated cultivars were selected and, for the subset of these reference cultivars, their behavior in the different environmental conditions over sites and years was described by ANOVA methods