579 research outputs found
The influence of electrolyte identity upon the electro-reduction of CO2
AbstractThe influence of supporting electrolyte cations on the voltammetric behaviour and product distribution in N-methylpyrrolidone-based carbon dioxide electroreduction systems is investigated. The reduction potentials associated with TBABF4 (0.1M) and corresponding alkali metal (M+) electrolytes; LiBF4, NaBF4 and RbBF4 (focussing mainly on the reduction of the widely employed Li+ species) were established in both the presence and absence of CO2 at polycrystalline noble metal working electrodes. In situ and ex situ Raman spectroscopy, X-ray photoelectron spectroscopy, scanning electron microscopy and qualitative element identification via flame testing were used to aid the assignment of reduction processes. It was established that CO2 reduction products in the metal cationic systems were formed at a much less negative potential than those found with the non-metal cation (â1.5V vs. Ferrocene, c.f. â2.2V), however the resultant alteration of the surface environment was found to deactivate the electrode to further CO2 reduction. The presence of CO2 in solution was found to affect the potential required for the bulk deposition of metal from the electrolyte through the same process. Where TBA+ and M+ were employed simultaneously in the system, the resultant voltammetry shared the majority of features with the pure M+ system with CO2 reduction suppressed at more negative potentials therefore supporting the conclusion that any âcatalytic effectâ associated with TBA+ is in fact a lack of deactivation given by the M+ system, rather than any enhancement offered by the former
Optimizing the DFCN Broadcast Protocol with a Parallel Cooperative Strategy of Multi-Objective Evolutionary Algorithms
Proceeding of: 5th International Conference, EMO 2009, Nantes, France, April 7-10, 2009This work presents the application of a parallel coopera- tive optimization approach to the broadcast operation in mobile ad-hoc networks (manets). The optimization of the broadcast operation im- plies satisfying several objectives simultaneously, so a multi-objective approach has been designed. The optimization lies on searching the best configurations of the dfcn broadcast protocol for a given manet sce- nario. The cooperation of a team of multi-objective evolutionary al- gorithms has been performed with a novel optimization model. Such model is a hybrid parallel algorithm that combines a parallel island- based scheme with a hyperheuristic approach. Results achieved by the algorithms in different stages of the search process are analyzed in order to grant more computational resources to the most suitable algorithms. The obtained results for a manets scenario, representing a mall, demon- strate the validity of the new proposed approach.This work has been supported by the ec (feder) and the Spanish Ministry of
Education and Science inside the âPlan Nacional de i+d+iâ (tin2005-08818-c04)
and (tin2008-06491-c04-02). The work of Gara Miranda has been developed under
grant fpu-ap2004-2290.Publicad
Cancer care for people with dementia: literature overview and recommendations for practice and research
As many countries experience population aging, patients with cancer are becoming older and have more preexisting comorbidities, which include prevalent, age-related, chronic conditions such as dementia. People living with dementia (PLWD) are vulnerable to health disparities, and dementia has high potential to complicate and adversely affect care and outcomes across the cancer trajectory. This report offers an overview of dementia and its prevalence among patients with cancer and a summary of the research literature examining cancer care for PLWD. The reviewed research indicates that PLWD are more likely to have cancer diagnosed at an advanced stage, receive no or less extensive cancer treatment, and have poorer survival after a cancer diagnosis. These cancer disparities do not necessarily signify inappropriately later diagnosis or lower treatment of people with dementia as a group, and they are arguably less feasible and appropriate targets for care optimization. The reviewed research indicates that PLWD also have an increased risk of cancer-related emergency presentations, lower quality processes of cancer-related decision making, accessibility-related barriers to cancer investigations and treatment, higher experienced treatment burden and higher caregiver burden for families, and undertreated cancer-related pain. The authors propose that optimal cancer care for PLWD should focus on proactively minimizing these risk areas and thus must be highly person-centered, with holistic decision making, individualized reasonable adjustments to practice, and strong inclusion and support of family carers. Comprehensive recommendations are made for clinical practice and future research to help clinicians and providers deliver best and equitable cancer care for PLWD and their families
LHS 2803B: A very wide mid-T dwarf companion to an old M dwarf identified from Pan-STARRS1
We report the discovery of a wide (1400 AU projected separation), common proper motion companion to the nearby M dwarf LHS 2803 (PSO J207.0300-13.7422). This object was discovered during our census of the local T dwarf population using Pan-STARRS1 and Two Micron All Sky Survey data. Using the Infrared Telescope Facility/SpeX near-infrared spectroscopy, we classify the secondary to be spectral type T5.5. University of Hawaii 2.2m/SuperNova Integral Field Spectrograph optical spectroscopy indicates that the primary has a spectral type of M4.5, with approximately solar metallicity and no measurable Hα emission. We use this lack of activity to set a lower age limit for the system of 3.5Gyr. Using a comparison with chance alignments of brown dwarfs and nearby stars, we conclude that the two objects are unlikely to be a chance association. The primary's photometric distance of 21pc and its proper motion implies thin disk kinematics. Based on these kinematics and its metallicity, we set an upper age limit for the system of 10Gyr. Evolutionary model calculations suggest that the secondary has a mass of 72±47 MJup, temperature of 1120 ± 80K, and log g = 5.4 ± 0.1dex. Model atmosphere fitting to the near-IR spectrum gives similar physical parameters of 1100K and log g = 5.0
Search for Higgs bosons decaying to tautau pairs in ppbar collisions at sqrt(s) = 1.96 TeV
We present a search for the production of neutral Higgs bosons decaying into
tautau pairs in ppbar collisions at a center-of-mass energy of 1.96 TeV. The
data, corresponding to an integrated luminosity of 5.4 fb-1, were collected by
the D0 experiment at the Fermilab Tevatron Collider. We set upper limits at the
95% C.L. on the product of production cross section and branching ratio for a
scalar resonance decaying into tautau pairs, and we then interpret these limits
as limits on the production of Higgs bosons in the minimal supersymmetric
standard model (MSSM) and as constraints in the MSSM parameter space.Comment: 7 pages, 5 figures, submitted to PL
Measurement of the photon-jet production differential cross section in collisions at \sqrt{s}=1.96~\TeV
We present measurements of the differential cross section dsigma/dpT_gamma
for the inclusive production of a photon in association with a b-quark jet for
photons with rapidities |y_gamma|< 1.0 and 30<pT_gamma <300 GeV, as well as for
photons with 1.5<|y_gamma|< 2.5 and 30< pT_gamma <200 GeV, where pT_gamma is
the photon transverse momentum. The b-quark jets are required to have pT>15 GeV
and rapidity |y_jet| < 1.5. The results are based on data corresponding to an
integrated luminosity of 8.7 fb^-1, recorded with the D0 detector at the
Fermilab Tevatron Collider at sqrt(s)=1.96 TeV. The measured cross
sections are compared with next-to-leading order perturbative QCD calculations
using different sets of parton distribution functions as well as to predictions
based on the kT-factorization QCD approach, and those from the Sherpa and
Pythia Monte Carlo event generators.Comment: 10 pages, 9 figures, submitted to Phys. Lett.
Limits on anomalous trilinear gauge boson couplings from WW, WZ and Wgamma production in pp-bar collisions at sqrt{s}=1.96 TeV
We present final searches of the anomalous gammaWW and ZWW trilinear gauge
boson couplings from WW and WZ production using lepton plus dijet final states
and a combination with results from Wgamma, WW, and WZ production with leptonic
final states. The analyzed data correspond to up to 8.6/fb of integrated
luminosity collected by the D0 detector in pp-bar collisions at sqrt{s}=1.96
TeV. We set the most stringent limits at a hadron collider to date assuming two
different relations between the anomalous coupling parameters
Delta\kappa_\gamma, lambda, and Delta g_1^Z for a cutoff energy scale Lambda=2
TeV. The combined 68% C.L. limits are -0.057<Delta\kappa_\gamma<0.154,
-0.015<lambda<0.028, and -0.008<Delta g_1^Z<0.054 for the LEP parameterization,
and -0.007<Delta\kappa<0.081 and -0.017<lambda<0.028 for the equal couplings
parameterization. We also present the most stringent limits of the W boson
magnetic dipole and electric quadrupole moments.Comment: 10 pages, 5 figures, submitted to PL
Measurement of three-jet differential cross sections d sigma-3jet / d M-3jet in p anti-p collisions at sqrt(s)=1.96 TeV
We present the first measurement of the inclusive three-jet differential
cross section as a function of the invariant mass of the three jets with the
largest transverse momenta in an event in p anti-p collisions at sqrt(s) = 1.96
TeV. The measurement is made in different rapidity regions and for different
jet transverse momentum requirements and is based on a data set corresponding
to an integrated luminosity of 0.7 fb^{-1} collected with the D0 detector at
the Fermilab Tevatron Collider. The results are used to test the three-jet
matrix elements in perturbative QCD calculations at next-to-leading order in
the strong coupling constant. The data allow discrimination between
parametrizations of the parton distribution functions of the proton.Comment: 10 pages, 4 figures, 2 tables, submitted to Phys. Lett. B, corrected
chi2 values for NNPD
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