1,897 research outputs found

    “ADAPTACIONES ELECTROCARDIOGRÁFICAS Y EL CONSUMO MÁXIMO DE OXÍGENO EN UN EQUIPO DE JUGADORES PROFESIONALES DE FUTBOL ASOCIACIÓN, EVALUADOS A TRAVÉS DE UNA PRUEBA DE ESFUERZO. TOLUCA MÉXICO 2013”

    Get PDF
    El consumo máximo de oxígeno se considera como la mejor medición singular de la capacidad aeróbica, así como el mejor indicador de integridad del sistema cardiovascular. El entrenamiento sistemático genera cambios clínicos, electrocardiográficos, funcionales y morfológicos. OBJETIVO Analizar las adaptaciones electrocardiográficas y determinar el consumo máximo de oxígeno (VO₂Max) en un equipo de futbolistas profesionales

    Experimental and theoretical investigations on structural and vibrational properties of melilite-type Sr2ZnGe2O7 at high pressure and delineation of a high pressure monoclinic phase

    Full text link
    "This document is the Accepted Manuscript version of a Published Work that appeared in final form in Inorganic Chemistry, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://pubs.acs.org/doi/abs/10.1021/acs.inorgchem.5b00937"We report a combined experimental and theoretical study of melilite-type germanate, Sr2ZnGe2O7, under compression. In situ high-pressure X-ray diffraction and Raman scattering measurements up to 22 GPa were complemented with first-principles theoretical calculations of structural and lattice dynamics properties. Our experiments show that the tetragonal structure of Sr2ZnGe2O7 at ambient conditions transforms reversibly to a monoclinic phase above 12.2 Gpa with similar to 1% volume drop at the phase transition pressure. Density functional calculations indicate the transition pressure at, similar to 13 GPa, which agrees well with the experimental value. The structure of the high-pressure monoclinic phase is closely related to the ambient pressure phase and results from a displacive-type phase transition. Equations of state of both tetragonal and monoclinic phases are reported. Both of the phases show anisotropic compressibility with a larger compressibility in the direction perpendicular to the [ZnGe2O7](2-) sheets than along the sheets. Raman-active phonons of both the tetragonal and monoclinic phases and their pressure dependences were also determined. Tentative assignments of the Raman modes of the tetragonal phase were discussed in the light of lattice dynamics calculations. A possible irreversible second phase transition to a highly disordered or amorphous state is detected in Raman scattering measurements above 21 GPa.Research supported by the Spanish government MINECO under Grant Nos. MAT and CSD2007-00045 and MAT2013-46649-C4-1/2/3-P. S.N.A. acknowledges the support provided by Universitat de Valencia during his visit there.Achary, SN.; Errandonea, D.; Santamaría-Pérez, D.; Gomis, O.; Patwe, SJ.; Manjón Herrera, FJ.; Rodríguez Hernández, P.... (2015). Experimental and theoretical investigations on structural and vibrational properties of melilite-type Sr2ZnGe2O7 at high pressure and delineation of a high pressure monoclinic phase. Inorganic Chemistry. 54(13):6594-6605. doi:10.1021/acs.inorgchem.5b00937S65946605541

    Estimation of Indoor 222Rn Concentration in Lima, Peru Using LR-115 Nuclear Track Detectors Exposed in Different Modes

    Get PDF
    Radon is the main source of natural radioactivity, and its measurement is considered extremely important in radioprotection, given its relationship with the occurrence of lung cancer. In the last two years, measurements of this radioactive gas were carried out in Lima considering a grid of 5 km (Formula presented.) and the population density to determine the number of measurements to be carried out. Cellulose nitrate nuclear track detectors exposed in bare mode and diffusion chamber mode were used to estimate (Formula presented.) Rn concentrations. In diffusion chamber mode, non-commercial monitors and commercial monitors were used. The monitoring results are presented for 43 districts of the Lima Province whose population is approximately ten million inhabitants occupying a total area of 2655.15 km (Formula presented.). Measurements were made obtaining an average concentration of 49 Bq·m (Formula presented.) using bare detectors and 66 Bq·m (Formula presented.) using non-commercial diffusion chambers. Average concentrations obtained by both detector exposure modes were below the maximum concentration recommended by the WHO. A radon ((Formula presented.) Rn) map was also obtained as a visual representation of the (Formula presented.) Rn levels in the Lima province using inverse distance weighting (IDW) interpolation

    Overview of the SLOPE I and II campaigns: aerosol properties retrieved with lidar and sun–sky photometer measurements

    Get PDF
    Jose Antonio Benavent-Oltra is funded by the University of Granada through "Plan Propio. Programa 7, Convocatoria 2019". Roberto Roman is funded by MINECO under the postdoctoral programme Juan de la Cierva-Incorporacion (IJCI2016-30007). Juan Andres Casquero-Vera is funded by MINECO under the predoctoral programme FPI (BES-2017-080015). Maria J. Granados-Munoz received funding from the European Union's Horizon 2020 research and innovation programme under the Marie Sklodowska-Curie grant agreement No 796539. Oleg Dubovik was supported by the Labex CaPPA project, which is funded by the French National Research Agency under contract "ANR-11-LABX0005-01". This work was also supported by the Spanish Ministry of Economy and Competitiveness (projects CMT2015-66742-R, CGL2016-81092-R, CGL2017-85344-R, RTI2018-097864-B-I00 and CGL2017-90884-REDT), by the Andalusia Regional Government through project P18-RT-3820 and the Unity of Excellence "Maria de Maeztu" (project MDM-2016-0600) financed by the Spanish State Research Agency (AEI). The authors thankfully ac-knowledge the FEDER programme for the instrumentation used in this work, the University of Granada, which supported this study through the Excellence Units Program, and the Sierra Nevada National Park. We also thank Dr. Grisa Monick who provided the Aethalometer AVIO AE-33 installed on the aircraft. Thanks to AERONET and ACTRIS/AERONET Europe for the scientific and technical support. Finally, the authors would like to acknowledge the use of the GRASP inversion algorithm software (http://www.grasp-open.com, last access: 1 April 2020), in this work.The Sierra Nevada Lidar aerOsol Profiling Experiment I and II (SLOPE I and II) campaigns were intended to determine the vertical structure of aerosols by remote sensing instruments and test the various retrieval schemes for obtaining aerosol microphysical and optical properties with in situ measurements. The SLOPE I and II campaigns were developed during the summers of 2016 and 2017, respectively, combining active and passive remote sensing with in situ measurements at stations belonging to the AGORA observatory (Andalusian Global ObseRvatory of the Atmosphere) in the Granada area (Spain). In this work, we use the in situ measurements of these campaigns to evaluate aerosol properties retrieved by the GRASP code (Generalized Retrieval of Atmosphere and Surface Properties) combining lidar and sun-sky photometer measurements. We show an overview of aerosol properties retrieved by GRASP during the SLOPE I and II campaigns. In addition, we evaluate the GRASP retrievals of total aerosol volume concentration (discerning between fine and coarse modes), extinction and scattering coefficients, and for the first time we present an evaluation of the absorption coefficient. The statistical analysis of aerosol optical and microphysical properties, both column-integrated and vertically resolved, from May to July 2016 and 2017 shows a large variability in aerosol load and types. The results show a strong predominance of desert dust particles due to North African intrusions. The vertically resolved analysis denotes a decay of the atmospheric aerosols with an altitude up to 5 km a.s.l. Finally, desert dust and biomass burning events were chosen to show the high potential of GRASP to retrieve vertical profiles of aerosol properties (e.g. absorption coefficient and single scattering albedo) for different aerosol types. The aerosol properties retrieved by GRASP show good agreement with simultaneous in situ measurements (nephelometer, aethalometer, scanning mobility particle sizer, and aerodynamic particle sizer) performed at the Sierra Nevada Station (SNS) in Granada. In general, GRASP overestimates the in situ data at the SNS with a mean difference lower than 6 mu m(3) cm(-3) for volume concentration, and 11 and 2 Mm(-1)for the scattering and absorption coefficients. On the other hand, the comparison of GRASP with airborne measurements also shows an overestimation with mean absolute differences of 14 +/- 10 and 1.2 +/- 1.2 Mm(-1) for the scattering and absorption coefficients, showing a better agreement for the absorption (scattering) coefficient with higher (lower) aerosol optical depth. The potential of GRASP shown in this study will contribute to enhancing the representativeness of the aerosol vertical distribution and provide information for satellite and global model evaluation.University of GranadaMINECO under the postdoctoral programme Juan de la Cierva-Incorporacion IJCI2016-30007MINECO under the predoctoral programme FPI BES-2017-080015European Commission 796539French National Research Agency (ANR) ANR-11-LABX0005-01Spanish Ministry of Economy and Competitiveness CMT2015-66742-R CGL2016-81092-R CGL2017-85344-R RTI2018-097864-B-I00 CGL2017-90884-REDTAndalusia Regional Government P18-RT-3820Spanish State Research Agency (AEI) MDM-2016-0600Excellence Units ProgramSierra Nevada National Par

    Pressure-induced amorphization of YVO4:Eu3+ nanoboxes

    Full text link
    This is an author-created, un-copyedited version of an article published in Nanotechnology. IOP Publishing Ltd is not responsible for any errors or omissions in this version of the manuscript or any version derived from it. The Version of Record is available online at http://dx.doi.org/10.1088/0957-4484/27/2/025701A structural transformation from the zircon-type structure to an amorphous phase has been found in YVO4:Eu3+ nanoboxes at high pressures above 12.7 GPa by means of x-ray diffraction measurements. However, the pair distribution function of the high-pressure phase shows that the local structure of the amorphous phase is similar to the scheelite-type YVO4. These results are confirmed both by Raman spectroscopy and Eu3+ photoluminescence which detect the phase transition to a scheelite-type structure at 10.1 and 9.1 GPa, respectively. The irreversibility of the phase transition is observed with the three techniques after a maximum pressure in the upstroke of around 20 GPa. The existence of two D-5(0)-> F-7(0) photoluminescence peaks confirms the existence of two local environments for Eu3+, at least for the low-pressure phase. One environment is the expected for substituting Y3+ and the other is likely a disordered environment possibly found at the surface of the nanoboxes.This work has been performed under financial support from Spanish MINECO under the National Program of Materials (MAT2013-46649-C4-1/2/3/4-P) and the Consolider-Ingenio 2010 Program (MALTA CSD2007-00045). Funding by the Fundacion Caja Canarias (ENER-01) and the EU-FEDER funds is also acknowledged. JR-F thanks the Alexander von Humboldt Foundation for a postdoctoral fellowship and NS thanks the German Research Foundation (DFG) for financial support (Project RA2585/1-1). We acknowledge Diamond Light Source for time on beamline I15 under proposals EE3652 and EE6517. Parts of this research were carried out at the light source PETRA III at DESY (Hamburg), a member of the Helmholtz Association (HFG). We would like to thank H-P Liermann and W Morgenroth for assistance in using beamline P02.2.Ruiz Fuertes, J.; Gomis, O.; León Luis, SF.; Schrodt, N.; Manjón Herrera, FJ.; Ray, S.; Santamaría Pérez, D.... (2016). Pressure-induced amorphization of YVO4:Eu3+ nanoboxes. Nanotechnology. 27(2):025701-1-025701-8. https://doi.org/10.1088/0957-4484/27/2/025701S025701-1025701-8272Piot, L., Le Floch, S., Cornier, T., Daniele, S., & Machon, D. (2013). Amorphization in Nanoparticles. The Journal of Physical Chemistry C, 117(21), 11133-11140. doi:10.1021/jp401121cZhang, F. X., Wang, J. W., Lang, M., Zhang, J. M., Ewing, R. C., & Boatner, L. A. (2009). High-pressure phase transitions ofScPO4andYPO4. Physical Review B, 80(18). doi:10.1103/physrevb.80.184114Lacomba-Perales, R., Errandonea, D., Meng, Y., & Bettinelli, M. (2010). High-pressure stability and compressibility ofAPO4(A=La, Nd, Eu, Gd, Er, and Y) orthophosphates: An x-ray diffraction study using synchrotron radiation. Physical Review B, 81(6). doi:10.1103/physrevb.81.064113Yuan, H., Wang, K., Li, S., Tan, X., Li, Q., Yan, T., … Zou., B. (2012). Direct Zircon-to-Scheelite Structural Transformation in YPO4 and YPO4:Eu3+ Nanoparticles Under High Pressure. The Journal of Physical Chemistry C, 116(46), 24837-24844. doi:10.1021/jp3088995Mishra, A. K., Garg, N., Pandey, K. K., Shanavas, K. V., Tyagi, A. K., & Sharma, S. M. (2010). Zircon-monoclinic-scheelite transformation in nanocrystalline chromates. Physical Review B, 81(10). doi:10.1103/physrevb.81.104109Wang, L., Yang, W., Ding, Y., Ren, Y., Xiao, S., Liu, B., … Mao, H. (2010). Size-Dependent Amorphization of NanoscaleY2O3at High Pressure. Physical Review Letters, 105(9). doi:10.1103/physrevlett.105.095701Mukherjee, S., Kim, K., & Nair, S. (2007). Short, Highly Ordered, Single-Walled Mixed-Oxide Nanotubes Assemble from Amorphous Nanoparticles. Journal of the American Chemical Society, 129(21), 6820-6826. doi:10.1021/ja070124cŞopu, D., Albe, K., Ritter, Y., & Gleiter, H. (2009). From nanoglasses to bulk massive glasses. Applied Physics Letters, 94(19), 191911. doi:10.1063/1.3130209Ozawa, L., & Itoh, M. (2003). Cathode Ray Tube Phosphors. Chemical Reviews, 103(10), 3835-3856. doi:10.1021/cr0203490Zhu, Y., Xu, W., Zhang, H., Wang, W., Tong, L., Xu, S., … Song, H. (2012). Highly modified spontaneous emissions in YVO4:Eu3+ inverse opal and refractive index sensing application. Applied Physics Letters, 100(8), 081104. doi:10.1063/1.3688167Khan, A. F., Haranath, D., Yadav, R., Singh, S., Chawla, S., & Dutta, V. (2008). Controlled surface distribution and luminescence of YVO4:Eu3+ nanophosphor layers. Applied Physics Letters, 93(7), 073103. doi:10.1063/1.2973163Cho, Y.-S., & Huh, Y.-D. (2011). Preparation of Transparent Red-Emitting YVO4:Eu Nanophosphor Suspensions. Bulletin of the Korean Chemical Society, 32(1), 335-337. doi:10.5012/bkcs.2011.32.1.335Jayaraman, A., Kourouklis, G. A., Espinosa, G. P., Cooper, A. S., & Van Uitert, L. G. (1987). A high-pressure Raman study of yttrium vanadate (YVO4) and the pressure-induced transition from the zircon-type to the scheelite-type structure. Journal of Physics and Chemistry of Solids, 48(8), 755-759. doi:10.1016/0022-3697(87)90072-2Wang, X., Loa, I., Syassen, K., Hanfland, M., & Ferrand, B. (2004). Structural properties of the zircon- and scheelite-type phases ofYVO4at high pressure. Physical Review B, 70(6). doi:10.1103/physrevb.70.064109Manjón, F. J., Rodríguez-Hernández, P., Muñoz, A., Romero, A. H., Errandonea, D., & Syassen, K. (2010). Lattice dynamics ofYVO4at high pressures. Physical Review B, 81(7). doi:10.1103/physrevb.81.075202Boehler, R. (2006). New diamond cell for single-crystal x-ray diffraction. Review of Scientific Instruments, 77(11), 115103. doi:10.1063/1.2372734Mao, H. K., Xu, J., & Bell, P. M. (1986). Calibration of the ruby pressure gauge to 800 kbar under quasi-hydrostatic conditions. Journal of Geophysical Research, 91(B5), 4673. doi:10.1029/jb091ib05p04673Hammersley, A. P., Svensson, S. O., Hanfland, M., Fitch, A. N., & Hausermann, D. (1996). Two-dimensional detector software: From real detector to idealised image or two-theta scan. High Pressure Research, 14(4-6), 235-248. doi:10.1080/08957959608201408Holland, T. J. B., & Redfern, S. A. T. (1997). Unit cell refinement from powder diffraction data: the use of regression diagnostics. Mineralogical Magazine, 61(404), 65-77. doi:10.1180/minmag.1997.061.404.07Kraus, W., & Nolze, G. (1996). POWDER CELL – a program for the representation and manipulation of crystal structures and calculation of the resulting X-ray powder patterns. Journal of Applied Crystallography, 29(3), 301-303. doi:10.1107/s0021889895014920Toby, B. H. (2001). EXPGUI, a graphical user interface forGSAS. Journal of Applied Crystallography, 34(2), 210-213. doi:10.1107/s0021889801002242Qiu, X., Thompson, J. W., & Billinge, S. J. L. (2004). PDFgetX2: a GUI-driven program to obtain the pair distribution function from X-ray powder diffraction data. Journal of Applied Crystallography, 37(4), 678-678. doi:10.1107/s0021889804011744Chupas, P. J., Qiu, X., Hanson, J. C., Lee, P. L., Grey, C. P., & Billinge, S. J. L. (2003). Rapid-acquisition pair distribution function (RA-PDF) analysis. Journal of Applied Crystallography, 36(6), 1342-1347. doi:10.1107/s0021889803017564Farrow, C. L., Juhas, P., Liu, J. W., Bryndin, D., Božin, E. S., Bloch, J., … Billinge, S. J. L. (2007). PDFfit2 and PDFgui: computer programs for studying nanostructure in crystals. Journal of Physics: Condensed Matter, 19(33), 335219. doi:10.1088/0953-8984/19/33/335219Trenque, I., Mornet, S., Duguet, E., & Gaudon, M. (2013). New Insights into Crystallite Size and Cell Parameters Correlation for ZnO Nanoparticles Obtained from Polyol-Mediated Synthesis. Inorganic Chemistry, 52(21), 12811-12817. doi:10.1021/ic402152fLangford, J. I., & Wilson, A. J. C. (1978). Scherrer after sixty years: A survey and some new results in the determination of crystallite size. Journal of Applied Crystallography, 11(2), 102-113. doi:10.1107/s0021889878012844Klotz, S., Chervin, J.-C., Munsch, P., & Le Marchand, G. (2009). Hydrostatic limits of 11 pressure transmitting media. Journal of Physics D: Applied Physics, 42(7), 075413. doi:10.1088/0022-3727/42/7/075413Jeong, I.-K., Proffen, T., Mohiuddin-Jacobs, F., & Billinge, S. J. L. (1999). Measuring Correlated Atomic Motion Using X-ray Diffraction. The Journal of Physical Chemistry A, 103(7), 921-924. doi:10.1021/jp9836978Frogley, M. D., Sly, J. L., & Dunstan, D. J. (1998). Pressure dependence of the direct band gap in tetrahedral semiconductors. Physical Review B, 58(19), 12579-12582. doi:10.1103/physrevb.58.12579Birch, F. (1978). Finite strain isotherm and velocities for single-crystal and polycrystalline NaCl at high pressures and 300°K. Journal of Geophysical Research, 83(B3), 1257. doi:10.1029/jb083ib03p01257Popescu, C., Sans, J. A., Errandonea, D., Segura, A., Villanueva, R., & Sapiña, F. (2014). Compressibility and Structural Stability of Nanocrystalline TiO2 Anatase Synthesized from Freeze-Dried Precursors. Inorganic Chemistry, 53(21), 11598-11603. doi:10.1021/ic501571uChen, G., Stump, N. A., Haire, R. G., Peterson, J. R., & Abraham, M. M. (1992). Pressure-induced phase transition in YVO4:Eu3+: A luminescence study at high pressure. Journal of Physics and Chemistry of Solids, 53(10), 1253-1257. doi:10.1016/0022-3697(92)90241-5Rivera-López, F., Martín, I. R., Da Silva, I., González-Silgo, C., Rodríguez-Mendoza, U. R., Lavín, V., … Fernández-Urban, J. (2006). Analysis of the Eu3+emission in a SrWO4laser matrix under pressure. High Pressure Research, 26(4), 355-359. doi:10.1080/08957950601105085Dieke, G. H., & Crosswhite, H. M. (1963). The Spectra of the Doubly and Triply Ionized Rare Earths. Applied Optics, 2(7), 675. doi:10.1364/ao.2.000675Lavı́n, V., Babu, P., Jayasankar, C. K., Martı́n, I. R., & Rodrı́guez, V. D. (2001). On the local structure of Eu3+ ions in oxyfluoride glasses. Comparison with fluoride and oxide glasses. The Journal of Chemical Physics, 115(23), 10935-10944. doi:10.1063/1.1420731Peacock, R. D. (s. f.). The intensities of lanthanide f ↔ f transitions. Rare Earths, 83-122. doi:10.1007/bfb0116556Oomen, E. W. J. L., & van Dongen, A. M. A. (1989). Europium (III) in oxide glasses. Journal of Non-Crystalline Solids, 111(2-3), 205-213. doi:10.1016/0022-3093(89)90282-2Song, H., Chen, B., Peng, H., & Zhang, J. (2002). Light-induced change of charge transfer band in nanocrystalline Y2O3:Eu3+. Applied Physics Letters, 81(10), 1776-1778. doi:10.1063/1.1501441Ray, S., León-Luis, S. F., Manjón, F. J., Mollar, M. A., Gomis, Ó., Rodríguez-Mendoza, U. R., … Lavín, V. (2014). Broadband, site selective and time resolved photoluminescence spectroscopic studies of finely size-modulated Y2O3:Eu3+ phosphors synthesized by a complex based precursor solution method. Current Applied Physics, 14(1), 72-81. doi:10.1016/j.cap.2013.07.02

    Different strategies to retrieve aerosol properties at night-time with the GRASP algorithm

    Get PDF
    This study evaluates the potential of the GRASP algorithm (Generalized Retrieval of Aerosol and Surface Properties) to retrieve continuous day-to-night aerosol properties, both column-integrated and vertically resolved. The study is focused on the evaluation of GRASP retrievals during an intense Saharan dust event that occurred during the Sierra Nevada Lidar aerOsol Profiling Experiment I (SLOPE I) field campaign. For daytime aerosol retrievals, we combined the measurements of the ground-based lidar from EARLINET (European Aerosol Research Lidar Network) station and sun–sky photometer from AERONET (Aerosol Robotic Network), both instruments co-located in Granada (Spain). However, for night-time retrievals three different combinations of active and passive remote-sensing measurements are proposed. The first scheme (N0) uses lidar night-time measurements in combination with the interpolation of sun–sky daytime measurements. The other two schemes combine lidar night-time measurements with nighttime aerosol optical depth obtained by lunar photometry either using intensive properties of the aerosol retrieved during sun–sky daytime measurements (N1) or using the Moon aureole radiance obtained by sky camera images (N2).This research has been supported by the European Union through the H2020 programme (ACTRIS-2, grant no. 654109) and the Spanish Ministry of Economy and Competitiveness (projects CMT2015-66742-R, CGL2016-81092- R, CGL2017-85344-R, RTI2018-097864-B-I00 and CGL2017- 90884-REDT)

    A deletion at Adamts9-magi1 Locus is associated with psoriatic arthritis risk

    Get PDF
    Objective: Copy number variants (CNVs) have been associated with the risk to develop multiple autoimmune diseases. Our objective was to identify CNVs associated with the risk to develop psoriatic arthritis (PsA) using a genome-wide analysis approach. Methods: A total of 835 patients with PsA and 1498 healthy controls were genotyped for CNVs using the Illumina HumanHap610 BeadChip genotyping platform. Genomic CNVs were characterised using CNstream analysis software and analysed for association using the χ2 test. The most significant genomic CNV associations with PsA risk were independently tested in a validation sample of 1133 patients with PsA and 1831 healthy controls. In order to test for the specificity of the variants with PsA aetiology, we also analysed the association to a cohort of 822 patients with purely cutaneous psoriasis (PsC). Results: A total of 165 common CNVs were identified in the genome-wide analysis. We found a highly significant association of an intergenic deletion between ADAMTS9 and MAGI1 genes on chromosome 3p14.1 (p=0.00014). Using the independent patient and control cohort, we validated the association between ADAMTS9-MAGI1 deletion and PsA risk (p=0.032). Using next-generation sequencing, we characterised the 26 kb associated deletion. Finally, analysing the PsC cohort we found a lower frequency of the deletion compared with the PsA cohort (p=0.0088) and a similar frequency to that of healthy controls (p>0.3). Conclusions: The present genome-wide scan for CNVs associated with PsA risk has identified a new deletion associated with disease risk and which is also differential from PsC risk
    corecore