447 research outputs found
Dispersion and Reinforcing Potential of Carboxymethylated Nanofibrillated Cellulose Powders Modified with 1-Hexanol in Extruded Poly(Lactic Acid) (PLA) Composites
Bionanocomposites of poly(lactic acid) (PLA) and chemically modified, nanofibrillated cellulose (NFC) powders were prepared by extrusion, followed by injection molding. The chemically modified NFC powders were prepared by carboxymethylation and mechanical disintegration of refined, bleached beech pulp (c-NFC), and subsequent esterification with 1-hexanol (c-NFC-hex). A solvent mix was then prepared by precipitating a suspension of c-NFC-hex and acetone-dissolved PLA in ice-cold isopropanol (c-NFC-hexsm), extruded with PLA into pellets at different polymer/fiber ratios, and finally injection molded. Dynamic mechanical analysis and tensile tests were performed to study the reinforcing potential of dried and chemically modified NFC powders for PLA composite applications. The results showed a faint increase in modulus of elasticity of 10% for composites with a loading of 7.5% w/w of fibrils, irrespective of the type of chemically modified NFC powder. The increase in stiffness was accompanied by a slight decrease in tensile strength for all samples, as compared with neat PLA. The viscoelastic properties of the composites were essentially identical to neat PLA. The absence of a clear reinforcement of the polymer matrix was attributed to poor interactions with PLA and insufficient dispersion of the chemically modified NFC powders in the composite, as observed from scanning electron microscope images. Further explanation was found in the decrease of the thermal stability and crystallinity of the cellulose upon carboxymethylatio
Gliding arc surface modification of carrot nanofibre coating - perspective for composite processing
Reinforcing effect of carboxymethylated nanofibrillated cellulose powder on hydroxypropyl cellulose
Bionanocomposites of hydroxypropyl cellulose (HPC) and nanofibrillated cellulose (NFC) were prepared by solution casting. The various NFC were in form of powders and were prepared from refined, bleached beech pulp (RBP) by mechanical disintegration, optionally combined with a pre- or post mechanical carboxymethylation. Dynamic mechanical analysis (DMA) and tensile tests were performed to compare the reinforcing effects of the NFC powders to those of their never-dried analogues. For unmodified NFC powders an inferior reinforcing potential in HPC was observed that was ascribed to severe hornification and reagglomeration of NFC. In contrast, the composites with carboxymethylated NFC showed similar behaviors, regardless of the NFC suspensions being dried or not prior to composite preparation. SEM characterization confirmed a homogeneous dispersion of dried, carboxymethylated NFC within the HPC matrix. These results clearly demonstrate that drying of carboxymethylated NFC to a powder does not decrease its reinforcing potential in (bio)nanocomposite
Preparation and characterization of water-redispersible nanofibrillated cellulose in powder form
Water-redispersible, nanofibrillated cellulose (NFC) in powder form was prepared from refined, bleached beech pulp (RBP) by carboxymethylation (c) and mechanical disintegration (m). Two routes were examined by altering the sequence of the chemical and mechanical treatment, leading to four different products: RBP-m and RBP-mc (route 1), and RBP-c and RBP-cm (route 2). The occurrence of the carboxymethylation reaction was confirmed by FT-IR spectrometry and 13C solid state NMR (13C CP-MAS) spectroscopy with the appearance of characteristic signals for the carboxylate group at 1,595cm−1 and 180ppm, respectively. The chemical modification reduced the crystallinity of the products, especially for those of route 2, as shown by XRD experiments. Also, TGA showed a decrease in the thermal stability of the carboxymethylated products. However, sedimentation tests revealed that carboxymethylation was critical to obtain water-redispersible powders: the products of route 2 were easier to redisperse in water and their aqueous suspensions were more stable and transparent than those from route 1. SEM images of freeze-dried suspensions from redispersed RBP powders confirmed that carboxymethylation prevented irreversible agglomeration of cellulose fibrils during drying. These results suggest that carboxymethylated and mechanically disintegrated RBP in dry form is a very attractive alternative to conventional NFC aqueous suspensions as starting material for derivatization and compounding with (bio)polymer
Real-time reconstruction of 2D signals with missing observations
In this paper, we propose a new real-time reconstruction method of two-dimensional uniformly sampled signals
with missing observations. A two-dimensional autoregressive model (AR-2D) is adopted. Two cases of causality,
Quarter of Plane (QP) and Non symetric Half Plane (NSHP) are tested. The criterion used to estimate the model
parameters is quadratic, and defined when samples are availables. Due to missing observations, the gradient of the
criterion becomes non-linear. The optimum is reached by means of LMS-like algorithms adapted to 2D non uniformly
sampled signals. Two approximations of the criterion are proposed. They lead to two algorithms whose formal descriptions
and compared performances are provided. The results obtained show the reconstruction performances of
two-dimensional (stationary and non stationary) signals, as a function of the ratio and the distribution law of
missing samples.Dans cet article nous proposons une nouvelle méthode de reconstruction en temps réel de signaux bidimensionnels à échantillons manquants. Un modèle autorégressif bidimensionnel est adopté. On considère deux causalités, quart de plan (QP) et demi-plan asymétrique (NSHP : Non Symetric Half Plane). Le critère à optimiser pour estimer les paramètres du modèle est quadratique en l'erreur d'estimation, et défini aux instants d'arrivées des échantillons. Du fait d'observations manquantes, le gradient du critère devient non linéaire en les paramètres. L'optimum est atteint à l'aide d'algorithmes de type LMS adaptés aux signaux bidimensionnels à échantillons manquants. Deux approximations du critère sont proposées. Elles conduisent à deux algorithmes dont la description formelle est fournie et les performances comparées. Les résultats présentés montrent les performances de la reconstruction (pour des signaux bidimensionnels stationnaires et non stationnaires) en fonction du pourcentage d'échantillons manquants ainsi que de la loi de distribution de ces échantillons
Functional nanocomposite films of poly(Lactic acid) with well-dispersed chitin nanocrystals achieved using a dispersing agent and liquid-assisted extrusion process
The development of bio-based nanocomposites is of high scientific and industrial interest, since they offer excellent advantages in creating functional materials. However, dispersion and distribution of the nanomaterials inside the polymer matrix is a key challenge to achieve high-performance functional nanocomposites. In this context, for better dispersion, biobased triethyl citrate (TEC) as a dispersing agent in a liquid-assisted extrusion process was used to prepare the nanocomposites of poly (lactic acid) (PLA) and chitin nanocrystals (ChNCs). The aim was to identify the effect of the TEC content on the dispersion of ChNCs in the PLA matrix and the manufacturing of a functional nanocomposite. The nanocomposite film’s optical properties; microstructure; migration of the additive and nanocomposites’ thermal, mechanical and rheological properties, all influenced by the ChNC dispersion, were studied. The microscopy study confirmed that the dispersion of the ChNCs was improved with the increasing TEC content, and the best dispersion was found in the nanocomposite prepared with 15 wt% TEC. Additionally, the nanocomposite with the highest TEC content (15 wt%) resembled the mechanical properties of commonly used polymers like polyethylene and polypropylene. The addition of ChNCs in PLA-TEC15 enhanced the melt viscosity, as well as melt strength, of the polymer and demonstrated antibacterial activity
PLA/WOOD BIOCOMPOSITES: IMPROVING COMPOSITE STRENGTH BY CHEMICAL TREATMENT OF THE FIBERS
A resol type phenolic resin was prepared for the impregnation of wood particles used for the reinforcement of PLA. A preliminary study showed that the resin penetrates wood with rates depending on the concentration of the solution and on temperature. Treatment with a solution of 1 wt% resin resulted in a considerable increase of composite strength and decrease of water absorption. Composite strength improved as a result of increased inherent strength of the wood, but interfacial adhesion might be modified as well. When wood was treated with resin solutions of larger concentrations, the strength of the composites decreased, first slightly, then drastically to a very small value. A larger amount of resin results in a thick coating on wood with inferior mechanical properties. At large resin contents the mechanism of deformation changes; the thick coating breaks very easily leading to the catastrophic failure of the composites at very small loads
Biocomposite from polylactic acid and lignocellulosic fibers: structure-property correlations
ABSTRACT
PLA biocomposites were prepared using three corncob fractions and a wood fiber as reference. The composites were characterized by tensile testing, scanning electron (SEM) and polarization optical (POM) microscopy. Micromechanical deformation processes were followed by acoustic emission measurements. The different strength of the components was proved by direct measurements. Two consecutive micromechanical deformation processes were detected in composites containing the heavy fraction of corncob, which were assigned to the fracture of soft and hard particles, respectively. The fracture of soft particles does not result in the failure of the composites that is initi-ated either by the fracture of hard particles or by matrix cracking. Very large particles debond easily from the matrix resulting in catastrophic failure at very low stresses. At sufficiently large shear stresses large particles break easily during compounding, thus reinforcement depending on interfacial adhesion was practically the same in all composites irrespectively of initial fiber characteristics
Fiber association and network formation in PLA/lignocellulosic fiber composites.
PLA composites were prepared in an internal mixer with a lignocellulosic fiber having relatively large aspect ratio. Fiber content changed between 0 and 60 vol% and the homogenized material was compression molded to 1 mm thick plates. The composites showed anomalous behavior above certain fiber content. Their modulus and especially their strength decreased drastically and modeling also proved the loss of reinforcement at large fiber contents. Micromechanical testing showed that the mechanism of deformation and failure changes at a critical fiber content. Microscopic analysis indi-cated the formation of a network purely from geometrical reasons. The inherent strength of the network is very small because of the weak forces acting among the fibers. This weak inherent strength makes the structure of the composites very sensitive to pro-cessing conditions, and decreases strength, reproducibility as well as reliability
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