228 research outputs found
Spatial fluctuations in transient creep deformation
We study the spatial fluctuations of transient creep deformation of materials
as a function of time, both by Digital Image Correlation (DIC) measurements of
paper samples and by numerical simulations of a crystal plasticity or discrete
dislocation dynamics model. This model has a jamming or yielding phase
transition, around which power-law or Andrade creep is found. During primary
creep, the relative strength of the strain rate fluctuations increases with
time in both cases - the spatially averaged creep rate obeys the Andrade law
, while the time dependence of the spatial
fluctuations of the local creep rates is given by . A similar scaling for the fluctuations is found in the logarithmic
creep regime that is typically observed for lower applied stresses. We review
briefly some classical theories of Andrade creep from the point of view of such
spatial fluctuations. We consider these phenomenological, time-dependent creep
laws in terms of a description based on a non-equilibrium phase transition
separating evolving and frozen states of the system when the externally applied
load is varied. Such an interpretation is discussed further by the data
collapse of the local deformations in the spirit of absorbing state/depinning
phase transitions, as well as deformation-deformation correlations and the
width of the cumulative strain distributions. The results are also compared
with the order parameter fluctuations observed close to the depinning
transition of the 2 Linear Interface Model or the quenched Edwards-Wilkinson
equation.Comment: 27 pages, 18 figure
Hierarchical spin-orbital polarisation of a giant Rashba system
The Rashba effect is one of the most striking manifestations of spin-orbit
coupling in solids, and provides a cornerstone for the burgeoning field of
semiconductor spintronics. It is typically assumed to manifest as a
momentum-dependent splitting of a single initially spin-degenerate band into
two branches with opposite spin polarisation. Here, combining
polarisation-dependent and resonant angle-resolved photoemission measurements
with density-functional theory calculations, we show that the two "spin-split"
branches of the model giant Rashba system BiTeI additionally develop disparate
orbital textures, each of which is coupled to a distinct spin configuration.
This necessitates a re-interpretation of spin splitting in Rashba-like systems,
and opens new possibilities for controlling spin polarisation through the
orbital sector.Comment: 11 pages including supplemental figures, accepted for publication at
Science Advance
The ACS LCID project VII: the blue stragglers population in the isolated dSph galaxies Cetus and Tucana
We present the first investigation of the Blue Straggler star (BSS)
population in two isolated dwarf spheroidal galaxies of the Local Group, Cetus
and Tucana. Deep HST/ACS photometry allowed us to identify samples of 940 and
1214 candidates, respectively. The analysis of the star formation histories of
the two galaxies suggests that both host a population of BSSs. Specifically, if
the BSS candidates are interpreted as young main sequence stars, they do not
conform to their galaxy's age-metallicity relationship. The analysis of the
luminosity function and the radial distributions support this conclusion, and
suggest a non-collisional mechanism for the BSS formation, from the evolution
of primordial binaries. This scenario is also supported by the results of new
dynamical simulations presented here. Both galaxies coincide with the
relationship between the BSS frequency and the absolute visual magnitude Mv
found by Momany et al (2007). If this relationship is confirmed by larger
sample, then it could be a valuable tool to discriminate between the presence
of BSSs and galaxies hosting truly young populations.Comment: Accepted for publication on ApJ. 15 pages, 3 tables, 13 figures. A
version with high resolution figure can be downloaded from
http://rialto.ll.iac.es/proyecto/LCID/?p=publication
FineâTuning the Photophysics of DonorâAcceptor (DâA 3 ) Thermally Activated Delayed Fluorescence Emitters Using Isomerisation
Here two DâA3 regioisomers, comprising three dibenzothiophene-S,S-dioxide acceptor units attached to a central triazatruxene core, are studied. Both molecules show thermally activated delayed fluorescence (TADF), however, the efficiency of the TADF mechanism is strongly affected by the DâA substitution position. The meta- substituted emitter (1âb) shows a slightly higher-lying singlet charge transfer state and a lower-lying triplet state than that observed in the para- substituted emitter (1âa), resulting in a larger singletâtriplet splitting (ÎEST) of 0.28â
eV compared to only 0.01â
eV found in 1âa. As expected, this ÎEST difference strongly impacts the reverse intersystem crossing (rISC) rates and the para- isomer 1âa exhibits a much faster delayed fluorescence emission. Calculations show that the triplet energy difference between the two isomers is due to steric hindrance variances along the donorâacceptor rotation axis in these molecules: as 1âb is less restricted, rotation of its acceptor unit leads to a lower T1 energy, further away from the region of high density of states (the region where larger vibronic coupling is found, favouring rISC). Therefore, our results show how the substitution pattern has a marked effect on triplet state energies and character, verifying the key structural designs for highly efficient TADF materials
Interactions between surfactants and {1,4-phenylene-[9,9-bis(4-phenoxy-butylsulfonate)]fluorene-2,7-diyl}
The interaction between the water-soluble anionic conjugated copolymer poly{1,4-phenylene-[9,9-bis(4-phenoxy-butylsulfonate)]fluorene-2,7-diyl} (PBS-PFP) and various surfactants has been studied in aqueous solution by UV-vis absorption spectra, fluorescence and electrical conductivity. It is suggested from the linear dependence of absorbance, fluorescence and electrical conductivity on concentration that in the absence of surfactant, moderately stable dispersions are formed. These are affected in different ways on adding cationic, anionic or neutral surfactants. With the cationic cetyltrimethylammonium bromide, quenching of fluorescence intensity and lifetime, and formation of a new emission occurs at concentrations well below the critical micelle concentration (cmc). Electrical conductivity measurements indicate a discontinuity at surfactant/polymer ratio corresponding to electroneutrality, due to complexation. With the anionic sodium dodecyl sulfate, fluorescence quenching is also observed, but is attributed to formation of some mixed polymer/surfactant aggregate. The most striking changes are observed with the non-ionic pentaethyleneglycol monododecyl ether (C12E5), where a blue shift in fluorescence emission, dramatic increases in lifetime and quantum yield, and changes in electrical around the cmc are interpreted in terms of incorporation of single polymer chains in elongated cylindrical micelles. This is supported by 1H NMR spectroscopic measurements.http://www.sciencedirect.com/science/article/B6TFR-4GJK86Y-7/1/847da7ebe75424aac8aa097365af1c3
The Blue Straggler Population in Dwarf Galaxies
In this chapter I review the recent developments regarding the study of Blue
Stragglers (BSS) in dwarf galaxies. The loose density environment of dwarf
galaxies resembles that of the Galactic Halo, hence it is natural to compare
their common BSS properties. At the same time, it is unescapable to compare
with the BSS properties in Galactic Globular clusters, which constitute the
reference point for BSS studies. Admittedly, the literature on BSS in dwarf
galaxies is not plentiful. The limitation is mostly due to the large distance
to even the closest dwarf galaxies. Nevertheless, recent studies have allowed a
deeper insight on the BSS photometric properties that are worth examining.Comment: Chapter 6, in Ecology of Blue Straggler Stars, H.M.J. Boffin, G.
Carraro & G. Beccari (Eds), Astrophysics and Space Science Library, Springe
'Reading landscape' : interdisciplinary approaches to understanding place
<p>This paper outlines a collaborative project between a group of Fine Art and Geography students who helped develop and contribute to a conversation about recording âplaceâ. Introducing methodologies from both disciplines, the project started from the premise of all environmental ârecordingsâ being âinputsâ and so questioned what could be defined as âdataâ when encountering a location. Brunelâs Grand Entrance to the Thames Tunnel (London) provided the motivation for 10 objective and subjective ârecordingsâ which were subsequently distilled into a smaller subset and then used to produce a short film that was presented at an international conference. Important to the collaborative nature of the project were ongoing opportunities to share equipment, techniques, material and references across disciplines. It was an experiment to measure the potential for âmappingâ to capture physical and historical information, as well as embodied experience.</p
Resonant inelastic soft-x-ray scattering spectra at the N1s and C1s edges of poly(pyridine-2,5-diyl)
Resonant inelastic scattering measurements of poly(pyridine-2,5-diyl) have
been performed at the N1s and C1s edges using synchrotron radiation. For
comparison, molecular orbital calculations of the spectra have been carried out
with the repeat unit as a model molecule of the polymer chain. The resonant
emission spectra show depletion of the p electron bands which is consistent
with symmetry selection and momentum conservation rules. The depletion is most
obvious in the resonant inelastic scattering spectra of carbon while the
nitrogen spectra are dominated by lone pair n orbital emission of s symmetry
and are less excitation energy dependent. By comparing the measurements to
calculations an isomeric dependence of the resonant spectra is found giving
preference to two of the four possible isomers in the polymer.Comment: 6 pages, 3 figures,
http://www.sciencedirect.com/science/article/pii/S036820489800354
A Real Space Description of Magnetic Field Induced Melting in the Charge Ordered Manganites: I. The Clean Limit
We study the melting of charge order in the half doped manganites using a
model that incorporates double exchange, antiferromagnetic superexchange, and
Jahn-Teller coupling between electrons and phonons. We primarily use a real
space Monte Carlo technique to study the phase diagram in terms of applied
field and temperature , exploring the melting of charge order with
increasing and its recovery on decreasing . We observe hysteresis in
this response, and discover that the `field melted' high conductance state can
be spatially inhomogeneous even without extrinsic disorder. The hysteretic
response plays out in the background of field driven equilibrium phase
separation. Our results, exploring , , and the electronic parameter
space, are backed up by analysis of simpler limiting cases and a Landau
framework for the field response. This paper focuses on our results in the
`clean' systems, a companion paper studies the effect of cation disorder on the
melting phenomena.Comment: 16 pages, pdflatex, 11 png fig
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