153 research outputs found
Dielectric anomalies and spiral magnetic order in CoCr2O4
We have investigated the structural, magnetic, thermodynamic, and dielectric
properties of polycrystalline CoCrO, an insulating spinel exhibiting
both ferrimagnetic and spiral magnetic structures. Below = 94 K the
sample develops long-range ferrimagnetic order, and we attribute a sharp phase
transition at 25 K with the onset of long-range spiral magnetic
order. Neutron measurements confirm that while the structure remains cubic at
80 K and at 11 K; there is complex magnetic ordering by 11 K. Density
functional theory supports the view of a ferrimagnetic semiconductor with
magnetic interactions consistent with non-collinear ordering. Capacitance
measurements on CoCrO, show a sharp decrease in the dielectric constant
at , but also an anomaly showing thermal hysteresis falling between
approximately = 50 K and = 57 K. We tentatively attribute the
appearance of this higher temperature dielectric anomaly to the development of
\textit{short-range} spiral magnetic order, and discuss these results in the
context of utilizing dielectric spectroscopy to investigate non-collinear
short-range magnetic structures.Comment: & Figure
Magnetodielectric coupling in Mn3O4
We have investigated the dielectric anomalies associated with spin ordering
transitions in the tetragonal spinel MnO, using thermodynamic,
magnetic, and dielectric measurements. We find that two of the three magnetic
ordering transitions in MnO lead to decreases in the temperature
dependent dielectric constant at zero applied field. Applying a magnetic field
to the polycrystalline sample leaves these two dielectric anomalies practically
unchanged, but leads to an increase in the dielectric constant at the
intermediate spin-ordering transition. We discuss possible origins for this
magnetodielectric behavior in terms of spin-phonon coupling. Band structure
calculations suggest that in its ferrimagnetic state, MnO corresponds
to a semiconductor with no orbital degeneracy due to strong Jahn-Teller
distortion.Comment: 6 pages, 7 figure
Knowledge, attitudes and practices about vaccination in Trentino, Italy in 2019
Vaccination is among the most important areas of progress in the worldwide history of public health. However, a crescent wave of anti-vaccine groups has grown in Western countries, especially in Italy, in the last two decades. Our aim was to evaluate adult's hesitancy and knowledge about vaccines and related diseases in Trentino-Alto Adige -the Italian region with the lowest vaccination coverages
Nova edició del workshop sobre "Mètodes Ràpids i Automatització en Microbiologia Alimentària" - memorial DYCFung
El XIX workshop sobre Mètodes Ràpids i Automatització en Microbiologia Alimentària (MRAMA) - memorial DYCFung, va ser organitzat en línia des de la Facultat de Veterinària de la UAB el mes de novembre passat. Celebrat anualment, amb un contingut aplicat i de futur, el MRAMA amplia i difon els coneixements teòrics i pràctics sobre mètodes innovadors per a detectar, comptar, aïllar i caracteritzar ràpidament els microorganismes, i els seus metabòlits, habituals en els aliments i l'aigua.El XIX workshop sobre Métodos Rápidos y Automatización en Microbiología Alimentaria (MRAMA) - memorial DYCFung, fue organizado en línea desde la Facultad de Veterinaria de la UAB el pasado mes de noviembre. Celebrado anualmente, con un contenido aplicado y de futuro, el MRAMA amplía y difunde los conocimientos teóricos y prácticos sobre métodos innovadores para detectar, contar, aislar y caracterizar rápidamente los microorganismos, y sus metabolitos, habituales en los alimentos y el agua
Risks management and cobots. Identifying critical variables
Trabajo presentado en: 29th European Safety and Reliability Conference (ESREL), 22–26 September 2019, HannoverA collaborative robot or a "Cobot" is the name of a robot that can share a workspace with operators
in the absence of a protective fence or with only partial protection. They represent a new and expanding sector of
industrial robotics. This investigation draws from the latest international rules and safety parameters related to
work with collaborative robots. Its detailed research is motivated by the design of a collaborative industrial robot
system, hazard elimination, risk reduction, and different collaborative operations, such as power and force
limiting, collaborative operation design, and end-effector safety requirements, among others. The purpose of our
study is to analyze the most important variables that must be controlled in accordance with the desired use of the
Cobot, according to ISO / TS 15066, ISO / TR 20218-1and some other generic safety regulations on machines and
industrial robots. A series of observations and appreciations on the use of the Cobot will also be presented
Structural and magnetic characterization of the complete delafossite solid solution (CuAlO2){1-x}(CuCrO2){x}
We have prepared the complete delafossite solid solution series between
diamagnetic CuAlO2 and the t2g^3 frustrated antiferromagnet CuCrO2. The
evolution with composition x in CuAl(1-x)Cr(x)O2 of the crystal structure and
magnetic properties has been studied and is reported here. The room-temperature
unit cell parameters follow the Vegard law and increase with x as expected. The
effective moment is equal to the Cr^3+ spin-only S = 3/2 value throughout the
entire solid solution. Theta is negative, indicating that the dominant
interactions are antiferromagnetic, and its magnitude increases with Cr
substitution. For dilute Cr compositions, J_BB was estimated by mean-field
theory to be 2.0 meV. Despite the sizable Theta, long-range antiferromagnetic
order does not develop until very large x, and is preceeded by glassy behavior.
Data presented here, and that on dilute Al-substitution from Okuda et al.,
suggest that the reduction in magnetic frustration due to the presence of
non-magnetic Al does not have as dominant an effect on magnetism as chemical
disorder and dilution of the magnetic exchange. For all samples, the 5 K
isothermal magnetization does not saturate in fields up to 5 T and minimal
hysteresis is observed. The presence of antiferromagnetic interactions is
clearly evident in the sub-Brillouin behavior with a reduced magnetization per
Cr atom. An inspection of the scaled Curie plot reveals that significant
short-range antiferromagnetic interactions occur in CuCrO2 above its Neel
temperature, consistent with its magnetic frustration. Uncompensated
short-range interactions are present in the Al-substituted samples and are
likely a result of chemical disorder
Understanding the role of crystallographic shear on the electrochemical behavior of niobium oxyfluorides
The effects of shear planes in perovskite materials have been studied in order to identify their role in the electrochemical behavior of Li⁺ intercalation hosts. These planes modulate the structural stability and ionic transport pathways and therefore play an intimate role in the characteristics and performance of shear compounds. Herein, two Nb-based compounds, NbO₂F and Nb₃O₇F, were chosen as representative perovskite and shear derivatives respectively to investigate the role of crystallographic shear. A series of operando measurements, including X-ray diffraction and X-ray absorption spectroscopy, in conjunction with structural analysis, Raman spectroscopy, and detailed electrochemical studies identified the effect of shear planes. It was found that shear planes led to increased structural stability during Li⁺ (de)intercalation with shear layers being maintained, while perovskite layers were seen to degrade rapidly. However, disordering in the shear plane stacking introduced during delithiation ultimately led to poor capacity retention despite structural maintenance as Li⁺ diffusion channels are disrupted
Application of a general discrete adjoint method for draft tube optimization
ABSTRACT: Automatic optimization is becoming increasingly important in turbomachinery design to improve the performance of machine components and Evolutionary Algorithms (EAs) play a very important role in this task. The main drawback of EAs is the large number of evaluations that are required to obtain an "optimal" result. Consequently, in order to keep the computational time in an affordable frame for design purposes, either the mesh size has to be limited, thus reducing the resolution of the flow phenomena, or the number of free parameters must be kept small. Adjoint optimization does not suffer from these restrictions, i.e. the optimization time is not affected by the number of parameters. The computational effort for the adjoint method scales only with the grid size and is usually in the range of two times the CFD simulation alone. In this paper, a discrete adjoint method based on a coupled pressure based RANS solver is presented and applied to draft tube optimization. The adjoint solver is general and can therefore deal with any turbulence model supported by the CFD solver as well as any boundary condition, including mixing planes and mesh interfaces needed for multi-stage simulations. Furthermore, there is no restriction on the choice of objective function. The adjoint method is first applied to a baseline draft tube geometry and then again to its EA optimized geometry where the objective function was the minimization of losses in the draft tube. To reduce the complexity for this proof of concept but still including multiple operating points in the optimization, only peak efficiency and full-load were optimized simultaneously. The adjoint optimization can significantly improve the draft tube performance in both cases (baseline and EA optimization). The interplay between local and global optimization seems to be a promising strategy to find optimal geometries for multi-operating point/multi-objective optimization and will be further investigated in subsequent research
The role of static disorder in negative thermal expansion in ReO3
Time-of-flight neutron powder diffraction and specific heat measurements were
used to study the nature of thermal expansion in rhenium trioxide, an
electrically conducting oxide with cubic symmetry. The temperature evolution of
the lattice parameters show that ReO3 can exhibit negative thermal expansion at
low temperatures and that the transition from negative to positive thermal
expansion depends on sample preparation; the single crystal sample demonstrated
the highest transition temperature, 300 K, and largest negative value for the
coefficient of thermal expansion, alpha = -1.1(1)x 10^-6 K^-1. For the oxygen
atoms, the atomic displacement parameters are strongly anisotropic even at 15
K, indicative of a large contribution of static disorder to the displacement
parameters. Further inspection of the temperature evolution of the oxygen
displacement parameters for different samples reveals that the static disorder
contribution is greater for the samples with diminished NTE behavior. In
addition, specific heat measurements show that ReO3 lacks the low energy
Einstein-type modes seen in other negative thermal expansion oxides such as
ZrW2O8.Comment: 6 pages, 5 figure
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