Comparison of two models for bridge-assisted charge transfer

Based on the reduced density matrix method, we compare two different approaches to calculate the dynamics of the electron transfer in systems with donor, bridge, and acceptor. In the first approach a vibrational substructure is taken into account for each electronic state and the corresponding states are displaced along a common reaction coordinate. In the second approach it is assumed that vibrational relaxation is much faster than the electron transfer and therefore the states are modeled by electronic levels only. In both approaches the system is coupled to a bath of harmonic oscillators but the way of relaxation is quite different. The theory is applied to the electron transfer in ${\rm H_2P}-{\rm ZnP}-{\rm Q}$ with free-base porphyrin (${\rm H_2P}$) being the donor, zinc porphyrin (${\rm ZnP}$) being the bridge and quinone (${\rm Q}$) the acceptor. The parameters are chosen as similar as possible for both approaches and the quality of the agreement is discussed.Comment: 12 pages including 4 figures, 1 table, 26 references. For more info see http://eee.tu-chemnitz.de/~kili

Marked changes in electron transport through the blue copper protein azurin in the solid state upon deuteration

Measuring electron transport (ETp) across proteins in the solid-state offers a way to study electron transfer (ET) mechanism(s) that minimizes solvation effects on the process. Solid state ETp is sensitive to any static (conformational) or dynamic (vibrational) changes in the protein. Our macroscopic measurement technique extends the use of ETp meas-urements down to low temperatures and the concomitant lower current densities, because the larger area still yields measurable currents. Thus, we reported previously a surprising lack of temperature-dependence for ETp via the blue copper protein azurin (Az), from 80K till denaturation, while ETp via apo-(Cu-free) Az was found to be temperature de-pendent \geq 200K. H/D substitution (deuteration) can provide a potentially powerful means to unravel factors that affect the ETp mechanism at a molecular level. Therefore, we measured and report here the kinetic deuterium isotope effect (KIE) on ETp through holo-Az as a function of temperature (30-340K). We find that deuteration has a striking effect in that it changes ETp from temperature independent to temperature dependent above 180K. This change is expressed in KIE values between 1.8 at 340K and 9.1 at \leq 180K. These values are particularly remarkable in light of the previously reported inverse KIE on the ET in Az in solution. The high values that we obtain for the KIE on the ETp process across the protein monolayer are consistent with a transport mechanism that involves through-(H-containing)-bonds of the {\beta}-sheet structure of Az, likely those of am-ide groups.Comment: 15 pages, 3 figures, 2 Supplementary figure

Constraints on relaxation rates for N-level quantum systems

We study the constraints imposed on the population and phase relaxation rates by the physical requirement of completely positive evolution for open N-level systems. The Lindblad operators that govern the evolution of the system are expressed in terms of observable relaxation rates, explicit formulas for the decoherence rates due to population relaxation are derived, and it is shown that there are additional, non-trivial constraints on the pure dephasing rates for N>2. Explicit experimentally testable inequality constraints for the decoherence rates are derived for three and four-level systems, and the implications of the results are discussed for generic ladder-, Lambda- and V-systems, and transitions between degenerate energy levels.Comment: 10 pages, RevTeX, 4 figures (eps/pdf

Vibrating Cavities - A numerical approach

We present a general formalism allowing for efficient numerical calculation of the production of massless scalar particles from vacuum in a one-dimensional dynamical cavity, i.e. the dynamical Casimir effect. By introducing a particular parametrization for the time evolution of the field modes inside the cavity we derive a coupled system of first-order linear differential equations. The solutions to this system determine the number of created particles and can be found by means of numerical methods for arbitrary motions of the walls of the cavity. To demonstrate the method which accounts for the intermode coupling we investigate the creation of massless scalar particles in a one-dimensional vibrating cavity by means of three particular cavity motions. We compare the numerical results with analytical predictions as well as a different numerical approach.Comment: 28 pages, 19 figures, accepted for publication in J. Opt. B: Quantum Semiclass. Op

An empirical investigation of dance addiction

Although recreational dancing is associated with increased physical and psychological well-being, little is known about the harmful effects of excessive dancing. The aim of the present study was to explore the psychopathological factors associated with dance addiction. The sample comprised 447 salsa and ballroom dancers (68% female, mean age: 32.8 years) who danced recreationally at least once a week. The Exercise Addiction Inventory (Terry, Szabo, & Griffiths, 2004) was adapted for dance (Dance Addiction Inventory, DAI). Motivation, general mental health (BSI-GSI, and Mental Health Continuum), borderline personality disorder, eating disorder symptoms, and dance motives were also assessed. Five latent classes were explored based on addiction symptoms with 11% of participants belonging to the most problematic class. DAI was positively associated with psychiatric distress, borderline personality and eating disorder symptoms. Hierarchical linear regression model indicated that Intensity (ß=0.22), borderline (ß=0.08), eating disorder (ß=0.11) symptoms, as well as Escapism (ß=0.47) and Mood Enhancement (ß=0.15) (as motivational factors) together explained 42% of DAI scores. Dance addiction as assessed with the Dance Addiction Inventory is associated with indicators of mild psychopathology and therefore warrants further research

The Effects of Sitting and Walking in Green Space on State Mindfulness and Connectedness to Nature

People report feeling connected to nature while spending time in green space. The modulators of this relationship are unclear. One modulator may be state mindfulness, which is how mindful someone is in a specific moment. The first step of studying state mindfulness as a potential modulator is describing how state mindfulness and connectedness to nature respond to acute exposure to green space. PURPOSE: This study aimed to determine whether sitting and walking in green space change state mindfulness and connectedness to nature in tandem. METHODS: Participants arrived at one of two green spaces: the Thunderbird Gardens Trailhead in Cedar City, UT, or the Clark County Wetlands Park in Las Vegas, NV. After giving verbal and written consent, the participants completed the State Mindfulness Scale (SMS) and Love and Care of Nature Scale (LCN). The participants then sat alone and undisturbed for 10 minutes near the trailhead and completed the SMS and LCN again. Next, the participants walked alone for 10 minutes on the trail and completed the SMS and LCN once more. The SMS and LCN scores were compared among pre-sit, post-sit, and post-walk via two separate one-way repeated-measures ANOVAs. Population effect sizes were estimated as partial omega squared (ωp2; large effect \u3e 0.14). After each ANOVA, the post hoc pairwise comparisons were dependent-samples t-tests with Bonferroni adjustments. The α-level was 0.05 for all the statistical analyses. RESULTS: Forty-two participants completed the study (22 females, 20 males, 0 intersex; 4 African American/Black, 4 Asian, 19 Caucasian/White, 9 Hispanic/Latino, 1 Mediterranean, 1 Middle Eastern, 3 Multi-Racial, 1 Polynesian; 26 ± 9 years, 170 ± 9 cm, 69 ± 16 kg, 24 ± 4 kg/m2). The SMS scores significantly increased from pre-sit to post-sit (+29 arbitrary units [AU], 95% CI: 20, 38; p \u3c 0.001) but not from post-sit to post-walk (p = 0.23). The LCN scores significantly increased from pre-sit to post-sit (+5 AU, 95% CI: 2, 8; p = 0.003) and from post-sit to post-walk (+4 AU, 95% CI: 1, 6; p = 0.002). CONCLUSION: Sitting for 10 minutes in green space increases state mindfulness and connectedness to nature. Walking for 10 minutes further increases connectedness to nature but not state mindfulness. The next step is determining whether state mindfulness predicts connectedness to nature while in green space

SU(16) grandunification: breaking scales, proton decay and neutrino magnetic moment

We give a detailed renormalization group analysis for the SU(16) grandunified group with general breaking chains in which quarks and leptons transform separately at intermediate energies. Our analysis includes the effects of Higgs bosons. We show that the grandunification scale could be as low as $\sim 10^{8.5}$ GeV and give examples where new physics could exist at relatively low energy ($\sim 250$ GeV). We consider proton decay in this model and show that it is consistent with a low grandunification scale. We also discuss the possible generation of a neutrino magnetic moment in the range of $10^{-11}$ to $10^{-10}\mu_B$ with a very small mass by the breaking of the embedded SU(2)$_\nu$ symmetry at a low energy.Comment: (16 pages in REVTEX + 6 figures not included) OITS-49

The characteristic blue spectra of accretion disks in quasars as uncovered in the infrared

Quasars are thought to be powered by supermassive black holes accreting surrounding gas. Central to this picture is a putative accretion disk which is believed to be the source of the majority of the radiative output. It is well known, however, that the most extensively studied disk model -- an optically thick disk which is heated locally by the dissipation of gravitational binding energy -- is apparently contradicted by observations in a few major respects. In particular, the model predicts a specific blue spectral shape asymptotically from the visible to the near-infrared, but this is not generally seen in the visible wavelength region where the disk spectrum is observable. A crucial difficulty was that, toward the infrared, the disk spectrum starts to be hidden under strong hot dust emission from much larger but hitherto unresolved scales, and thus has essentially been impossible to observe. Here we report observations of polarized light interior to the dust-emiting region that enable us to uncover this near-infrared disk spectrum in several quasars. The revealed spectra show that the near-infrared disk spectrum is indeed as blue as predicted. This indicates that, at least for the outer near-infrared-emitting radii, the standard picture of the locally heated disk is approximately correct. The model problems at shorter wavelengths should then be directed toward a better understanding of the inner parts of the revealed disk. The newly uncovered disk emission at large radii, with more future measurements, will also shed totally new light on the unanswered critical question of how and where the disk ends.Comment: published in Nature, 24 July 2008 issue. Supplementary Information can be found at http://www.mpifr-bonn.mpg.de/div/ir-interferometry/suppl_info.pdf Published version can be accessed from http://www.nature.com/nature/journal/v454/n7203/pdf/nature07114.pd

Straight and Divergent Pathways to Cognitive State: Seven Decades of Follow-Up in the British 1946 Birth Cohort

BACKGROUND: Using the British 1946 birth cohort we previously estimated life course paths to the Addenbrooke's Cognitive Examination (ACE-III). OBJECTIVE: We now compared those whose ACE-III scores were expected, worse and better than predicted from the path model on a range of independent variables including clinical ratings of cognitive impairment and neuroimaging measures. METHODS: Predicted ACE-III scores were categorized into three groups: those with Expected (between -1.5 and 1.5 standard deviation; SD); Worse (1.5 SD) scores. Differences in the independent variables were then tested between these three groups. RESULTS: Compared with the Expected group, those in the Worse group showed independent evidence of progressive cognitive impairment: faster memory decline, more self-reported memory difficulties, more functional difficulties, greater likelihood of being independently rated by experienced specialist clinicians as having a progressive cognitive impairment, and a cortical thinning pattern suggestive of preclinical Alzheimer's disease. Those in the Better group showed slower verbal memory decline and absence of independently rated progressive cognitive impairment compared to the Expected group, but no differences in any of the other independent variables including the neuroimaging variables. CONCLUSION: The residual approach shows that life course features can map directly to clinical diagnoses. One future challenge is to translate this into a readily usable algorithm to identify high-risk individuals in preclinical state, when preventive strategies and therapeutic interventions may be most effective