Formation and Evolution of Single Molecule Junctions

We analyze the formation and evolution statistics of single molecule junctions bonded to gold electrodes using amine, methyl sulfide and dimethyl phosphine link groups by measuring conductance as a function of junction elongation. For each link, maximum elongation and formation probability increase with molecular length, strongly suggesting that processes other than just metal-molecule bond breakage play a key role in junction evolution under stress. Density functional theory calculations of adiabatic trajectories show sequences of atomic-scale changes in junction structure, including shifts in attachment point, that account for the long conductance plateau lengths observed.Comment: 10 pages, 4 figures, submitte

Arkansas\u27 Incendiary Wildfire Record: 1983-1987

All wildfire reports from lands protected by the Arkansas Forestry Commission for the calendar years 1983 through 1987 were studied. The number of wildfires steadily increased from 2,185 in 1983 to 4,150 in 1987, burning a total of 27,146 hectares in 1987. Incendiarism on forested lands in 1987 comprised 77% of the total fires and 84% of the area burned. Incendiarism was responsible for 40% of all fires and 60% of the area burned in 1983, but increased to 54% of all fires and 69% of the area burned in 1987. In 1987, 80% of all incendiary fires on industry lands were started by local residents. Most incendiary fires occurred on Class 3 (52%) and Class-2 (27%) fire-danger class-days. More incendiary fires (64%) occurred during the spring fire season (January through June). The general public reported 66% the non-incendiary fires, but only 56% of the incendiary-caused fires. Implications of these findings for wildfire prevention programs are discussed

Magnetic phase transition in V2O3 nanocrystals

V2O3 nanocrystals can be synthesized through hydrothermal reduction of VO(OH)2 using hydrazine as a reducing agent. Addition of different ligands to the reaction produces nanoparticles, nanorods and nanoplatelets of different sizes. Small nanoparticles synthesized in this manner show suppression of the magnetic phase transition to lower temperatures. Using muon spin relaxation spectroscopy and synchrotron x-ray diffraction, it is determined that the volume fraction of the high-temperature phase, characterized by a rhombohedral structure and paramagnetism, gradually declines with decreasing temperature, in contrast to the sharp transition observed in bulk V2O3.Comment: 6 pages, 6 figure

Determination of the structure and geometry of N-heterocyclic carbenes on Au(111) using high-resolution spectroscopy

N-heterocyclic carbenes (NHCs) bind very strongly to transition metals due to their unique electronic structure featuring a divalent carbon atom with a lone pair in a highly directional sp(2)-hybridized orbital. As such, they can be assembled into monolayers on metal surfaces that have enhanced stability compared to their thiol-based counterparts. The utility of NHCs to form such robust self-assembled monolayers (SAMs) was only recently recognized and many fundamental questions remain. Here we investigate the structure and geometry of a series of NHCs on Au(111) using high-resolution X-ray photoelectron spectroscopy and density functional theory calculations. We find that the N-substituents on the NHC ring strongly affect the molecule-metal interaction and steer the orientation of molecules in the surface layer. In contrast to previous reports, our experimental and theoretical results provide unequivocal evidence that NHCs with N-methyl substituents bind to undercoordinated adatoms to form flat-lying complexes. In these SAMs, the donor-acceptor interaction between the NHC lone pair and the undercoordinated Au adatom is primarily responsible for the strong bonding of the molecules to the surface. NHCs with bulkier N-substituents prevent the formation of such complexes by forcing the molecules into an upright orientation. Our work provides unique insights into the bonding and geometry of NHC monolayers; more generally, it charts a clear path to manipulating the interaction between NHCs and metal surfaces using traditional coordination chemistry synthetic strategies

Synthesis of CdS and CdSe nanocrystallites using a novel single-molecule precursors approach

The synthesis of CdS and CdSe nanocrystallites using the thermolysis of several dithioor diselenocarbamato complexes of cadmium in trioctylphosphine oxide (TOPO) is reported. The nanodispersed materials obtained show quantum size effects in their optical spectra and exhibit near band-edge luminescence. The influence of experimental parameters on the properties of the nanocrystallites is discussed. HRTEM images of these materials show well-defined, crystalline nanosized particles. Standard size fractionation procedures can be performed in order to narrow the size dispersion of the samples. The TOPO-capped CdS and CdSe nanocrystallites and simple organic bridging ligands, such as 2,2¢-bipyrimidine, are used as the starting materials for the preparation of novel nanocomposites. The optical properties shown by these new nanocomposites are compared with those of the starting nanodispersed materials

Up-regulation of NMDA receptor subunit and post-synaptic density protein expression in the thalamus of elderly patients with schizophrenia

Numerous studies have described structural and functional abnormalities of the thalamus in schizophrenia, but surprisingly few studies have examined neurochemical abnormalities that accompany these pathological changes. We previously identified abnormalities of multiple molecules associated with glutamatergic neurotransmission, including changes in NMDA receptor subunit transcripts and binding sites and NMDA receptor-associated post-synaptic density (PSD) protein transcripts in the thalamus of elderly patients with schizophrenia. In the present study, we performed western blot analysis to determine whether protein levels of NMDA receptor subunits (NR1, NR2A, NR2B) and associated PSD proteins (NF-L, PSD95, SAP102) are altered in schizophrenia. Thalamic tissue from each subject was grossly dissected into two regions: a dorsomedial region containing limbic-associated dorsomedial, anterior and central medial thalamic nuclei; and a ventral thalamus region that primarily consisted of the ventral lateral nucleus. We observed increased protein expression of the NR2B NMDA receptor subunit and its associated intracellular protein, PSD95, in the dorsomedial thalamus of patients with schizophrenia, but the other molecules were unchanged, and we found no changes in the ventral thalamus. These data provide additional evidence of thalamic neurochemical abnormalities, particularly in thalamic nuclei which project to limbic regions of the brain. Further, these findings provide additional evidence of NMDA receptor alterations in schizophrenia, which may play an important role in the neurobiology of the illness.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/65970/1/j.1471-4159.2006.03954.x.pd

First results of undersea muography with the Tokyo-Bay Seafloor Hyper-Kilometric Submarine Deep Detector

Tidal measurements are of great significance since they may provide us with essential data to apply towards protection of coastal communities and sea traffic. Currently, tide gauge stations and laser altimetry are commonly used for these measurements. On the other hand, muography sensors can be located underneath the seafloor inside an undersea tunnel where electric and telecommunication infrastructures are more readily available. In this work, the world’s first under-seafloor particle detector array called the Tokyo-bay Seafloor Hyper-Kilometric Submarine Deep Detector (TS-HKMSDD) was deployed underneath the Tokyo-Bay seafloor for conducting submarine muography. The resultant 80-day consecutive time-sequential muographic data were converted to the tidal levels based on the parameters determined from the first-day astronomical tide height (ATH) data. The standard deviation between ATH and muographic results for the rest of a 79-day measurement period was 12.85 cm. We anticipate that if the length of the TS-HKMSDD is extended from 100 m to a full-scale as large as 9.6 km to provide continuous tidal information along the tunnel, this muography application will become an established standard, demonstrating its effectiveness as practical tide monitor for this heavy traffic waterway in Tokyo and in other important sea traffic areas worldwide

First measurement of the Gerasimov-Drell-Hearn integral for Hydrogen from 200 to 800 MeV

A direct measurement of the helicity dependence of the total photoabsorption cross section on the proton was carried out at MAMI (Mainz) in the energy range 200 < E_gamma < 800 MeV. The experiment used a 4$\pi$ detection system, a circularly polarized tagged photon beam and a frozen spin target. The contributions to the Gerasimov-Drell-Hearn sum rule and to the forward spin polarizability $\gamma_0$ determined from the data are 226 \pm 5 (stat)\pm 12(sys) \mu b and -187 \pm 8 (stat)\pm 10(sys)10^{-6} fm^4, respectively, for 200 < E_\gamma < 800 MeV.Comment: 6 pages, 3 figures, 3 table

The VIMOS Public Extragalactic Redshift Survey (VIPERS): Ωm0\Omega_{\rm m_0} from the galaxy clustering ratio measured at z∼1z \sim 1

We use a sample of about 22,000 galaxies at $0.65<z<1.2$ from the VIPERS PDR-1 catalogue, to constrain the cosmological model through a measurement of the galaxy {\it clustering ratio} $\eta_{g,R}$. This statistic has favourable properties, being defined as the ratio of two quantities characterizing the smoothed density field in spheres of given radius $R$: the value of its correlation function on a multiple of this scale, $\xi(nR)$, and its variance $\sigma^2(R)$. For sufficiently large values of $R$, this is a universal number, capturing 2-point clustering information independently of the linear bias and linear redshift-space distortions of the specific galaxy tracers. In this paper we discuss in detail how to extend the application of $\eta_{g,R}$ to quasi-linear scales and how to control and remove observational selection effects which are typical of redshift surveys as VIPERS. We verify the accuracy and efficiency of these procedures using mock catalogues that match the survey selection process. These results evidence the robustness of $\eta_{g,R}$ to non-linearities and observational effects, which is related to its very definition as a ratio of quantities that are similarly affected. We measure $\Omega_{m,0}=0.270_{-0.025}^{+0.029}$. In addition to the great precision achieved on our estimation of $\Omega_m$ using VIPERS PDR-1, this result is remarkable because it appears to be in good agreement with a recent estimate $z\simeq 0.3$, obtained applying the same technique to the SDSS-LRG catalogue. It, therefore, suports the robustness of the present analysis. Moreover, the combination of these two measurements at $z\sim 0.3$ and $z\sim 0.9$ provides us with a very precise estimate $\Omega_{m,0}=0.274\pm0.017$ which highlights the great consistency between our estimation and other cosmological probes such as BAOs, CMB and Supernovae.Comment: 18 pages, 17 figures, accepted for publication in A&A, references adde

Interaction of molecular and atomic hydrogen with (5,5) and (6,6) single-wall carbon nanotubes

Abstract Carbon nanostructure compounds in an attractive variation of structures and wonderful forms have been synthesized and identified. One of these structures is the carbon nanotubes. These structures have several rings that share number of carbons. Study about properties of nanotubes with medicinal and electronic applications have been made the highly useful and effective results for applications in different areas of science. One of the main recognized structures of nanotubes is (5,5) single-walled tube (SWCN). Topological indices are the digital value combined with chemical constitution purporting for correlation of chemical structures with various chemical and physical properties that have constructed the effective and useful mathematical methods for finding good relationship between several data of the properties in these materials. One of the useful numerical and structural items in unsaturated compounds is degree of unsaturation (D U ) which is illustrated here. In this study, the relationship between this index (D U ), Fermi energy (E f ), chemical hardness, and relative energetic stability all show the length periodicity seen in the HOMO-LUMO gap, in contrast to the optical &quot;charge transfer&quot; transition are represented as some of the important properties of nanotubes (5,5) armchair SWCN. By the simple model presented here, in good approximation can calculate the structural and electronic properties of these nanotubes and can be used the approximated values in electronic structures and electrical properties studies of this type of nanotubes. The interesting results of relationship among D U and the properties of these nanotubes are presented