Décomposition chimique et isotopique d'un hydrogramme de crue d'un torrent méditerranéen - Réflexions méthodologiques

La décomposition chimique et isotopique d'un hydrogramme de crue d'un petit torrent méditerranéen (Cannone, Corse, France), a été tentée dans un cas simple, en confrontant les résultats des deux méthodes et en discutant leurs limites. L'outil isotopique permet de bien différencier l'eau préexistante et l'eau nouvelle. L'analyse de la variation des éléments chimiques met en évidence la participation d'eau du soi, sans qu'il soit possible de quantifier sa contribution; elle démontre que la composition de la pluie n'est pas conservative; le rôle du pluviolessivage est mis en évidence, conjointement à celui du transfert dans la zone non-saturée. Ainsi les décompositions chimiques des hydrogrammes (en particulier celles réalisées avec la conductivité) reposent le plus souvent sur des approximations théoriquement contestables et conduisent à des erreurs notables, à l'exception toutefois de celles réalisées avec la silice.Problems of environmental water quality such as transfer of pollutants and ecosystem acidification call for a new insight to the path and the contact time of water in the different subsurface reservoirs. An isotopic and chemical hydrograph separation is carried out for a flood in a small upland watershed in the Mediterranean region (Cannone, Corsica Island, France) with special attention to a comparison between the two methods and discussion of their limits. Here, old and new water are clearly distinguished by isotopic composition. The pattern of the dissolved constituents of stream water shows the contribution of ground water, often assumed to be negligible. The non-conservative behaviour of rain-water chemistry during its path to the stream channel due to enrichment by throughfall and leaching of soils, is the main obstacle to chemical separation. Chemical separation, especially through specific conductance seems generally to be hazardous, except perhaps for dissolved silica. Checking the variation of all dissolved constituents would prevent questionable approximations

Eutrophisation récente d'un lac de montagne sans occupation humaine (lac de Bastani, Corset : Conséquence d'agents atmosphériques?

Le Lac de Bastani (Corse - France), petit lac d'altitude (2089 m) à bassin versant rocheux, est dépourvu de toute implantation ou activité humaine. Ce lac est mésotrophe à eutrophe par certains de ses caractères alors que 4 autres lacs étudiés dans le même contexte sont oligotrophes. De plus, il était décrit au début du siècle comme oligotrophe.Dans ce type de lacs, les apports atmosphériques constituent la majeure partie de la source externe de nutriments. L'apport d'azote inorganique dissous atmosphérique au bassin versant est important, de l'ordre de 0,8 g.N.m-2 par an, soit l'équivalent du rejet d'une trentaine d'habitants permanents. Les trois-quarts sont relargués à la fonte, pendant environ un mois; cela représente l'équivalent des rejets d'environ 300 habitants sur le bassin qui, du fait de la faible activité biologique dans les sols à cette température, arrive pratiquement en entier au lac. Ces apports de nutriments à la fonte sont responsables du démarrage très précoce de la production primaire.En l'absence d'un bilan complet des nutriments la comparaison du lac de Bastani avec les autres lacs oligotrophes et en particulier avec celui de Capitello, aux caractéristiques voisines, permet de cerner les facteurs responsables de la différence de leur niveau de trophie. Bastani et Capitello recevant une charge externe semblable, la source interne est probablement responsable de la situation de Bastani. Les concentrations estivales de N-NO3 notables (0,2-0,3 mg.l-1) des lacs oligotrophes sont un indice de la limitation de leur production primaire par le phosphore. Par contre à Bastani, l'azote étant pratiquement entièrement consommé en été le lac ne semble pas limité par le phosphore. Le vent violent et fréquent qui règne à Bastani semble le facteur déterminant de son niveau trophique supérieur : il assure le brassage de l'eau du lac et la remontée du phosphore (et aussi de l'azote) libéré des sédiments jusque dans la zone photique. Le phytoplancton consomme presque entièrement l'azote, alors que dans les lacs oligotrophes abrités du vent où le phosphore est limitant, les nitrates restent à des teneurs notables.L'eutrophisation récente du lac de Bastani peut s'expliquer par l'accroissement des apports atmosphériques, les seuls qui aient varié. Le phosphore étant disponible la production primaire devait être limitée auparavant par l'azote. Les apports d'azote inorganique dissous ont été dans cette région multipliés par 2 au moins par la pollution à longue distance. Cette dernière pourrait entraîner à elle seule l'évolution trophique d'un lac de haute montagne, dans un site vierge de toute occupation humaine, lorsque le brassage par le vent assure la mobilisation du phosphore des sédiments.Lake Bastani (Corsica, France), a small alpine lake (2089 m), is located in a pristine rocky watershed. It presents some characteristics of eutrophic lakes, whereas four other similar lakes are oligotrophic or ultraoligotrophic. Moreover, at the beginning of the century it was described as being oligotrophic.The lake is ice-covered from November to June. Intense phytoplankton activity begins before the ice melts completely and goes on until fall freezing. Consequently Secchi disk transparency is between 3.2 m in June and 1.8 m in August. The algal biomass, as expressed by chlorophyll-a content, is maximum at the bottom. Chlorophyll-a is about 4-5 mg-m-3 at ice melting and reaches a maximum of 46 mg.m-3 in August. Primary production is highest in the upper levels of water with 41 mg.C.m-3.d-1 at - 5 m. These values are 20 to 80 times that of the other Corsican lakes. Regarding the different trophic classifications this lake presents some features of eutrophic lakes.In 1923 a survey of phytoplankton by Pestalozzi showed that the lake was oligotrophic. This trophic evolution is therefore recent; it is shown by the complete disappearance of Desmidiaceae, the near disappearance of Diatoms, the appearance of green algae with Oedogonium and Spirogyra dominant in summer and autumn, and the development of blue-green algae with Oscillatoria.The seasonal pattern of phytoplankton composition displays diatom development at ice- and snow-melting with the green algae Oedogonium. During the summer warmth, green algae are dominant with the blue-green Oscillatoria. Green algae Oedogonium and Spirogyra increase until the fall turnover.The lake is 2nd-order dimictic with two turnovers in spring and autumn, and two periods of thermal stratification. A strong and frequent wind stirs the lake water inducing homogeneisation of the epilimnion and sometimes the disappearance of the hypolimnion. Dissolved oxygen is always present even at the bottom where O2 saturation is about 50% in winter. Nitrogen is very low - 0.01-0.04 mg.l-1 N-NO3 - and phosphorus (PO4) is below the detection level in the epilimnion during summer, due to intense phytoplankton activity, The hypolimnion is richer in NH4, NO2 and PO4. In spring when the snow begins to melt the surficial waters are enriched with N (NO3 + NH4) and P-PO4, showing the contribution of concentrated snow water.In fact atmospheric input is the dominant external loading in such a watershed. Nitrogen atmospheric input is extrapolated from data obtained at Lake Bavella 30 km southwards for 3 years - 1984 to 1986. The dissolved inorganic nitrogen input is about 0.8 g.m-2 .y-1 , equivalent to wastes from some 30 permanent inhabitants for the whole watershed, About 80 % of annual rainfall is stored in the snowpack, as are ¾ of the dissolved inorganic nitrogen. This nitrogen returns to the lake during a period of about one month which represents 100 kg and a loading of 80 mg.m-2.d-1 for 30 days; it is equivalent to wastes from some three hundred capita during one month. Moreover it is known that the first melwaters are considerably enriched with several ions, especially those of ecological concern, H+, SO4--, NO3¯, NH4+. Using findings from literature we can estimate that in the first two weeks of melting, up to half the annual atmospheric input of dissolved inorganic nitrogen reaches the lake with meltwater concentrations of more than 1 mg.N.l-1. The total dissolved nitrogen input is estimated at 1.2 g.m-2.y-1 and the total nitrogen input at 1.3 g.m-2 .y-1.No data are available for the phosphorus atmospheric input but estimations from literature are about 10 mg.m-2 .y-1 for orthophosphate and 60 mg.m-2 .y-1 for total phosphorus. The release of P-PO4 from the melting snowcover and from ice, added to the tremendous release of inorganic nitrogen, explains the start of vigorous phytoplankton production before the ice melts completely. By this early start primary production may avoid the flush of nutriments resulting from the flow of melting water.Trophic conditions in Lake Bastani are a matter of question as the other four lakes studied with the same edaphic conditions are oligo- or ultraoligotrophic. A comparison between Lake Bastani and the ultraoligotrophic Capitello Lake, which has the same geomorphological and ecological environment, reveals the determining factors of this paradoxical situation, though a nutrient budget is still not available.A low flushing rate (17 months) cannot be the explanation, as that of Lake Capitello is similar (12 months).The external loading (from watershed and atmosphere)being the same, the difference between the two lakes is to be found in the internal loading.The fact that Lake Capitelto and the other oligotrophic lakes present notable N concentrations in summer (0.2-0.3 mg.l-1 ), when Bastani displays N- concentrations 10 times lower, is a sign that they are limited in phosphorus. Conversely Lake Bastani is not phosphorus-limited.The determining factor in this situation seems to be windstirring. Lake Bastani is downwind of a pass in the axial range of Corsica and is submitted to strong frequent winds. Windstirring induces an epilimnion homogeneisation, the downward migration of the thermo- and chemoclines. Thus phosphorus from the sediments can be transferred to the photic zone and is not limiting for phytoplankton. Phytoplankton exhausts nitrogen which is very low at the end of summer. In Lake Capitello as in the other lakes, shielded from the wind by rockwall screens, no mixing occurs, phosphorus cannot be supplied from the sediments and is limiting : nitrogen is not used up and remains at relatively high levels of 0.2-0.3 mg.l -1.Recent eutrophication cannot be explained by an increase of nutrient availability from the sediments due to windstirring, as no climatic change has occurred in the fast century. The probability that internal loading had reached a threshold by progressive accumulation of nutrients in the sediment is very slight if there is no change in the external loading (the unique source of "new" nutrients) and/or the trophic status of the lake. Thus an increase in the external loading seems to be responsible for the eutrophication of Lake Bastani. The atmospheric inupt is the only external reason for a change in the nutrient rate. An increase in the phosphorus atmospheric input by local (forest fires) and regional (long range pollution) human activities is suspected, but does not seem sufficient to change the trophic status of the lake as it has no effect on other lakes, which remain oligotrophic. Moreover, atmospheric P loading is well below the level of phosphorus release from sediments, as estimated from literature. Conversely, an atmospheric inorganic nitrogen input has increased at least twice due to long range pollution (agricultural, industrial and domestic activities). This was estimated from a typologic classification of rain events in Corsica. This increase in atmospheric nitrogen loading might explain the change in the trophic status of the lake, N having been limiting. In the other P-limited lakes the increased atmospheric N input has only increased the N-NO3 concentration in lake water. This explanation being the most realistic, it is of great interest to note that long range atmospheric pollution could induce the eutrophication of a pristine oligotrophic lake

Role of desert aerosol in metal fluxes in the Mediterranean area.

Aerosols and precipitations collected over Sardinia are mainly controlled by two end-members: Saharan and European. European background aerosols in Sardinia show a 3 to 25-fold decrease in EFcrust values for Cd, Zn, Pb, and Cr compared with coastal stations in the Western Mediterranean. Partitioning of total atmospheric deposition between the soluble and the insoluble phases shows that Al, Si, Fe and Pb originating from the atmosphere are mostly in the insoluble form. For Ca, Cd, Cr metals the dissolved fraction represents 50-90 % of the total input. Aerosol dissolution experiments performed at particle concentrations ranging from 3 to 300 mg l-1 show Cd and Pb exhibiting low solubility at the high mass particle concentration. Solubility of Pb increases with the EFcrust values and the finest grain-size of the aerosols (<1µm), and is less affected by pH. Al and Fe solubilities appear to be mainly controlled by the particulate load. Dissolution of both metals decreases significantly from 30% (13 % for Fe) at aerosol loads lower than 5 mg l-1, to less than 1% for both metals, at total aerosol concentrations greater than 50 mg l-1, which are encountered during Saharan transport. Fluxes (dry +wet) of metals at Sardinia show that ~ 30% for Cd and Pb, to more than 80 % for Fe and Al are due to Saharan contribution

22. -Les pluies et crues exceptionnelles de la Toussaint 1993 en Corse

Des pluies et des crues dévastatrices ont touché la Corse le 31 octobre et le 1er novembre 1993. L'intensité des précipitations et leur répartition spatiale ont été étudiées particulièrement dans le bassin-versant de la Solenzara (Bassin Versant Représentatif Expérimental). Des pluies de 923 mm en 39 h ont été enregistrées et un pluviomètre totalisateur indique 1150 mm+/-30 mm pour l'épisode. La station de jaugeage ayant été détruite, la crue corrélative a été estimée par diverses méthodes, qui convergent vers un débit de pointe de l'ordre de 1500 m3/s, soit 14 m3/s/km². La période de retour probable se situe, selon les méthodes d'estimation, entre 100 et 200 ans. Des débits spécifiques de crue supérieurs à 10 m3/s/km² et de période de retour probables supérieures à 100 ans ont été observés pour 4 bassins versants du Sud de la Corse.Loye-Pilot M. D., Pasquier C. 22. -Les pluies et crues exceptionnelles de la Toussaint 1993 en Corse. In: Crues et inondations. 23emes journées de l'hydraulique. Congrès de la Société Hydrotechnique de France. Nîmes, 14-15-16 septembre 1994. Tome 1, 1994

Conception of a synthesis pozzolan from sediment dams calcined (Case: Gargar dams)

Silting of dams is undoubtedly the most dramatic consequence of the erosion problem in Algeria. In spite of the great ways implemented for the construction of retaining structures, the storage of water remains confronted with the difficulties of their management. It is as important to be invested to prevent silting as to build a new dam. There are two levels of Investigations: that is to say to prevent the solid matters from arriving in reserve. There, it is a question of putting obstacles to break the forces strength of surface waters but one can expect only partial results. The second solution is the evacuation of the sediments by a suitable management of the basic matters and desilting by dredging which requires the use of an external energy. But considering the great quantity of the sediments of silting, we sought to make profitable the vases recovered with an aim of dumping down the costs associated with desilting. The research work undertaken herein concern the case of Gargar dam, as a real case of silted dams in Algeria and whose rate of silting is important. The significant amounts of rejected silts present environmental problems and their use as local raw materials for the manufacturing of materials in civil engineering contributes to its resolution. The results of the physical and mineralogical characteristics of the sediments of Gargar dam directed us towards the design of a synthetic pozzolan. For, we carried out calcination of the silt at different temperatures up to 750 °C and prepared micro test samples of calcined silt-cement mixtures. The results show that the addition of 30% of sediments calcined at 750°C to cement permit to obtain a pozzolanic cement having similar characteristics with ordinary cement. This study shows therefore the possibility to value dam sediments as materials in the construction domain. The analysis by the diffraction of x-rays (X-ray) and the differential thermal analysis (DTA) show that the chemical reactions between principal minerals of the vase used and cement give the formation of new products such as the freezing of HSC and the tobermorite

Role of the climatological and current variability on shelf-slope exchanges of particulate matter: Evidence from the Rhone continental margin (NW Mediterranean)

Climatological, current and particulate flux data were gathered in the Grand-Rhone canyon on the Gulf of Lions continental margin for one year (Jan. 1988-Jan 1989). Time series were analyzed to determine the influence of physical exchange processes on particulate matter at the shelf-edge, with a special emphasis on the Northern Current variability. The synoptic variability of the Northern Current was linked to meanders of 2-5 day period. Its meso-scale activity presented a seasonal signal with maximum values in early spring. Peaks of particulate fluxes in the upper traps were little affected by large river and atmospheric inputs, but rather by enhanced shelf-slope exchanges at the shelf edge due to intense cross-slope fluctuations of the Northern Current. These fluctuations caused cross-isobath flows near the bottom, which appeared to be a potential mechanism in transporting particles off the shelf. At 900 m depth, high-flux events measured by sediment traps were primarily linked to periods of higher cross-slope current oscillations. This correlation suggests that vertical motions caused by these oscillations contribute to the suspended particulate matter transport through the process of bringing higher suspended material concentrations from above to greater depths. Vertical velocity estimates were derived through temperature fluctuations combined with vertical temperature gradient and from the kinematic boundary condition. A simple diffusion model indicates that the vertical turbulent mixing of suspended particulate matter, induced by the cross-slope current oscillations, yields downward fluxes of particles comparable to those collected by sediment trap

Conception of a synthesis pozzolan from sediment dams calcined (Case: Gargar dams)

Silting of dams is undoubtedly the most dramatic consequence of the erosion problem in Algeria. In spite of the great ways implemented for the construction of retaining structures, the storage of water remains confronted with the difficulties of their management. It is as important to be invested to prevent silting as to build a new dam. There are two levels of Investigations: that is to say to prevent the solid matters from arriving in reserve. There, it is a question of putting obstacles to break the forces strength of surface waters but one can expect only partial results. The second solution is the evacuation of the sediments by a suitable management of the basic matters and desilting by dredging which requires the use of an external energy. But considering the great quantity of the sediments of silting, we sought to make profitable the vases recovered with an aim of dumping down the costs associated with desilting. The research work undertaken herein concern the case of Gargar dam, as a real case of silted dams in Algeria and whose rate of silting is important. The significant amounts of rejected silts present environmental problems and their use as local raw materials for the manufacturing of materials in civil engineering contributes to its resolution. The results of the physical and mineralogical characteristics of the sediments of Gargar dam directed us towards the design of a synthetic pozzolan. For, we carried out calcination of the silt at different temperatures up to 750 °C and prepared micro test samples of calcined silt-cement mixtures. The results show that the addition of 30% of sediments calcined at 750°C to cement permit to obtain a pozzolanic cement having similar characteristics with ordinary cement. This study shows therefore the possibility to value dam sediments as materials in the construction domain. The analysis by the diffraction of x-rays (X-ray) and the differential thermal analysis (DTA) show that the chemical reactions between principal minerals of the vase used and cement give the formation of new products such as the freezing of HSC and the tobermorite

The impact of Saharan dust on the particulate export in the water column of the North Western Mediterranean Sea

Simultaneous measurements of atmospheric deposition and of sinking particles at 200 and 1000 m depth, were performed in the Ligurian Sea (North-Western Mediterranean) between 2003 and 2007, along with phytoplanktonic activity derived from satellite images. Atmospheric deposition of Saharan dust particles was very irregular and confirmed the importance of sporadic high magnitude events over the annual average (11.4 g m(-2) yr(-1) for the 4 years). The average marine total mass flux was 31 g m(-2) yr(-1), the larger fraction being the lithogenic one (similar to 37%). The marine total mass flux displayed a seasonal pattern with a maximum in winter, occurring before the onset of the spring bloom. The highest POC fluxes did not occur during the spring bloom nor could they be directly related to any noticeable increase in the surface phytoplanktonic biomass. Over the 4 years of the study, the strongest POC fluxes were concomitant with large increases of the lithogenic marine flux, which had originated from either recent Saharan fallout events (February 2004 and August 2005), from 'old' Saharan dust 'stored' in the upper water column layer (March 2003 and February 2005), or alternatively from lithogenic material originating from Ligurian riverine flooding (December 2003, Arno, Roya and Var rivers). Those associated export fluxes defined as 'lithogenic events', are believed to result from a combination of forcing (winter mixing or Saharan events, in particular extreme ones), biological (zooplankton) activity, and also organic-mineral aggregation inducing a ballast effect. By fertilising the surface layer, mixed Saharan dust events were shown to be able to induce 'lithogenic events' during the stratification period. These events would be more efficient in transferring POC to the deeper layers than the spring bloom itself. The extreme Saharan event of February 2004 exported similar to 45% of the total annual POC, compared to an average of similar to 25% for the bloom period. This emphasises the role played by these 'lithogenic events', and in particular those that are induced by the more extreme Saharan events, in the carbon export efficiency in the North-western Mediterranean Sea