Global Carbon Budget: Ocean carbon sink.

CO2 emissions from human activities, the main contributor to global climate change, are set to rise again in 2014 reaching 40 billion tonnes CO2 The natural carbon ‘sinks’ on land and in the ocean absorb on average 55% of the total CO2 emissions, thus slowing the rate of global climate change Increasing CO2 in the oceans is causing ocean acidificatio

Large Contribution of Pteropods to Shallow CaCO3 Export

The literature on the relative contributions of pelagic calcifying taxa to the global ocean export of CaCO3 is divided. Studies based on deep sediment trap data tend to argue that either foraminifers or coccolithophores, both calcite producers, dominate export. However, the compilations of biomass observations for pteropods, coccolithophores, and foraminifers instead show that pteropods dominate the global ocean calcifier biomass and therefore likely also carbonate export. Here we present a new global ocean biogeochemical model that explicitly represents these three groups of pelagic calcifiers. We synthesize databases of the physiology of the three groups to parameterize the model and then tune the unconstrained parameters to reproduce the observations of calcifier biomass and CaCO3 export. The model can reproduce both these observational databases; however, substantial dissolution of aragonite above the aragonite saturation horizon is required to do so. We estimate a contribution of pteropods to shallow (100 m) export of CaCO3 of at least 33% and to pelagic calcification of up to 89%. The high production‐high dissolution configuration that shows closest agreement with all the observations has a CaCO3 production of 4.7 Pg C/year but CaCO3 export at 100 m of only 0.6 Pg C/year

The ocean carbon sink – impacts, vulnerabilities and challenges

Carbon dioxide (CO2) is, next to water vapour, considered to be the most important natural greenhouse gas on Earth. Rapidly rising atmospheric CO2 concentrations caused by human actions such as fossil fuel burning, land-use change or cement production over the past 250 years have given cause for concern that changes in Earth’s climate system may progress at a much faster pace and larger extent than during the past 20 000 years. Investigating global carbon cycle pathways and finding suitable adaptation and mitigation strategies has, therefore, become of major concern in many research fields. The oceans have a key role in regulating atmospheric CO2 concentrations and currently take up about 25% of annual anthropogenic carbon emissions to the atmosphere. Questions that yet need to be answered are what the carbon uptake kinetics of the oceans will be in the future and how the increase in oceanic carbon inventory will affect its ecosystems and their services. This requires comprehensive investigations, including high-quality ocean carbon measurements on different spatial and temporal scales, the management of data in sophisticated databases, the application of Earth system models to provide future projections for given emission scenarios as well as a global synthesis and outreach to policy makers. In this paper, the current understanding of the ocean as an important carbon sink is reviewed with respect to these topics. Emphasis is placed on the complex interplay of different physical, chemical and biological processes that yield both positive and negative air–sea flux values for natural and anthropogenic CO2 as well as on increased CO2 (uptake) as the regulating force of the radiative warming of the atmosphere and the gradual acidification of the oceans. Major future ocean carbon challenges in the fields of ocean observations, modelling and process research as well as the relevance of other biogeochemical cycles and greenhouse gases are discussed

Fingerprint of Climate Change on Southern Ocean Carbon Storage

The Southern Ocean plays a critical role in the uptake, transport, and storage of carbon by the global oceans. It is the ocean's largest sink of CO2, yet it is also among the regions with the lowest storage of anthropogenic carbon. This behavior results from a unique combination of high winds driving the upwelling of deep waters and the subduction and northward transport of surface carbon. Here we isolate the direct effect of increasing anthropogenic CO2 in the atmosphere from the indirect effect of climate variability and climate change on the reorganization of carbon in the Southern Ocean interior using a combination of modeling and observations. We show that the effect of climate variability and climate change on the storage of carbon in the Southern Ocean is nearly as large as the effect of anthropogenic CO2 during the period 1998–2018 compared with the climatology around the year 1995. We identify a distinct climate fingerprint in dissolved inorganic carbon (DIC), with elevated DIC concentration in the ocean at 300–600 m that reinforces the anthropogenic CO2 signal, and reduced DIC concentration in the ocean around 2,000 m that offsets the anthropogenic CO2 signal. The fingerprint is strongest at lower latitudes (30°–55°S). This fingerprint could serve to monitor the highly uncertain evolution of carbon within this critical ocean basin, and better identify its drivers.publishedVersio

Period-doubling scenario and crisis-induced intermittency in natural convection between two vertical differentially heated plates

Nous étudions la transition vers le chaos de l’écoulement entre deux plaques verticales différentiellement chauffées. Nous nous appuyons sur la simulation numérique directe (DNS) pour étudier le comportement spatio-temporel de l’écoulement en faisant augmenter le nombre de Rayleigh. A partir du régime de conduction pure, l’écoulement devient temporellement mono-périodique, après avoir traversé trois bifurcations supercritiques dont deux du type de fourche et une du type de Hopf. Si on restreint le domaine de simulation afin d’admettre une seule longueur critique dans la direction verticale, une cascade de doublement de période est observée. Le comportement temporel de l’écoulement peut être décrit à l’aide d’une itération unidimensionnelle, et correspond physiquement à la déformation périodique d’une structure tourbillonnaire dite en œil de chat. Le régime du chaos temporel est atteint à Ra_infini estimé à 12330. La constante de Feigenbaum est calculée à partir des premiers doublements de période et un accord relatif est obtenu avec la valeur théorique. Au-delà de Ra_infini, des fenêtres correspondant à des régimes périodiques apparaissent à nouveau. Quand Ra est augmenté au delà de Ra = 15500, une intermittence est observée entre deux structures en œil de chat, séparées d’une demi-période. Les observations de l’écoulement sont cohérentes avec un scénario de crise par fusion, et réminiscentes de cycles hétéroclines structurellement stables dus à la présence d’une symétrie O(2). Le temps caractéristique séparant deux passages d’une structure à une autre obéit à une loi exponentielle

Data-based estimates of interannual sea-air CO2 flux variations 1957-2020 and their relation to environmental drivers

This study considers year-to-year and decadal variations in as well as secular trends of the sea-air CO2 flux over the 1957-2020 period, as constrained by the pCO(2) measurements from the SOCATv2021 database. In a first step, we relate interannual anomalies in ocean-internal carbon sources and sinks to local interannual anomalies in sea surface temperature (SST), the temporal changes in SST (dSST/dt), and squared wind speed (u(2)), employing a multi-linear regression. In the tropical Pacific, we find interannual variability to be dominated by dSST/dt, as arising from variations in the upwelling of colder and more carbon-rich waters into the mixed layer. In the eastern upwelling zones as well as in circumpolar bands in the high latitudes of both hemispheres, we find sensitivity to wind speed, compatible with the entrainment of carbon-rich water during wind-driven deepening of the mixed layer and wind-driven upwelling. In the Southern Ocean, the secular increase in wind speed leads to a secular increase in the carbon source into the mixed layer, with an estimated reduction in the sink trend in the range of 17 % to 42 %. In a second step, we combined the result of the multi-linear regression and an explicitly interannual pCO(2)-based additive correction into a "hybrid" estimate of the sea-air CO2 flux over the period 1957-2020. As a pCO(2) mapping method, it combines (a) the ability of a regression to bridge data gaps and extrapolate into the early decades almost void of pCO(2) data based on process-related observables and (b) the ability of an auto-regressive interpolation to follow signals even if not represented in the chosen set of explanatory variables. The "hybrid" estimate can be applied as an ocean flux prior for atmospheric CO2 inversions covering the whole period of atmospheric CO2 data since 1957

Effect of sugar and acid composition, aroma release and assessment conditions on aroma enhancement by taste in model wines

Context: When congruent taste and retronasal aroma are perceived simultaneously, aroma can be enhanced by taste. Different explanations have been proposed: (i) physico-chemical interactions between tastants and aroma compounds, inducing a change of the aroma stimulus before it reaches the receptors, (ii) a contextual bias during sensory tests (dumping), when at least one relevant attribute is not proposed to the panelists to assess a product, (iii) a misunderstanding of the conceptual difference between aroma and taste, or (iv) a perceptual incapability of panelists to distinguish between two congruent percepts. This study was undertaken to better understand aroma enhancement by taste in model wines containing different sugar and acid concentrations but the same volatile composition. Method: We used a twofold approach: model wine retronasal aroma intensity was assessed twice by trained panelists. During the first session, panelists only assessed aroma intensity. During the second session, taste intensity was assessed before aroma intensity, to reduce dumping effects. In-mouth release of volatile compounds was measured by nosespace analysis with the same panelists. Results: Acid concentration influenced aroma compounds release, but it did not impact perceived aroma intensity. Increasing sugar concentration delayed ethyl octanoate (EO) release after swallowing. When taste was not assessed, perceived aroma intensity was not explained by aroma compounds release, but it increased with sugar concentration, probably because of a dumping effect. When taste was assessed, aroma intensity also depended on sugar concentration, but it was significantly correlated to the time of release of EO. Our hypothesis is that when taste declined, late aroma was more easily individualized, and thus assessed with a higher intensity. This entails that panelists focused on aroma to individualize it from taste. We concluded that trained panelists understand the conceptual difference between taste and aroma, but are not completely able to distinguish congruent and simultaneous taste and aroma percepts

Математична залежність точності верстатних пристроїв від їх ступеня гнучкості

Підвищення конкурентоспроможності продукції, що виробляється невеликими підприємствами, забезпечується шляхом скорочення витрат на проектування та виготовлення технологічної оснастки для свердлильно- фрезерно-розточувальних операцій. Це стає можливим за рахунок використання гнучких верстатних пристроїв (ВП), що мають можливість переналагодження у заданому діапазоні розмірів заготовки шляхом регулювання установлювально-затискних елементів