Evaluación del riesgo de contaminación por metales pesados en sedimentos superficiales de la Laguna Sur de Túnez mediante un procedimiento de extracción secuencial

In this study, the total concentrations and chemical forms of heavy metals (Fe, Zn, Pb, Cu, Cr, Cd, and Ni) in surface sediments of the South Lagoon of Tunis located in northeast Tunisia were investigated. Multiple geochemical indices were applied to assess the potential environmental risks. The South Lagoon is a valuable regional resource for fisheries, tourism and aquaculture. Total metal concentrations exhibited significant spatial variation attributed to the principal water circulation direction (east to west). The chemical speciation of Fe, Cr and Ni shows that they were mostly related to the residual fraction (Fe 34.8%, Cr 37.4% and Ni 37.9%), while Pb, Zn, Cu, and Cd were mostly related to the non-residual fraction (labile fraction Pb 89.4%, Zn 26.1%, Cu 71.8% and Cd 84.3%). Pb, Zn, Cu and Cr are of high potential bioavailability. The highest pollution was found on the west side of the lagoon according to the calculated global contamination factors. Besides, individual contamination factors, Pb followed by Zn and Cu, posed the highest risk of contamination. This study shows that, even after dredging, the persistence of low concentrations of some contaminants may cause environmental problems in certain physico-chemical conditions.En este estudio, se investigaron las concentraciones totales y las formas químicas de los metales pesados (Fe, Zn, Pb, Cu, Cr, Cd y Ni) en los sedimentos superficiales de la Laguna Sur de Túnez, ubicada en el noreste de Túnez. Se aplicaron múltiples índices geoquímicos para evaluar los riesgos ambientales potenciales. La Laguna Sur es un valioso recurso regional para la pesca, el turismo y la acuicultura. Las concentraciones totales de metales exhibieron una variación espacial significativa, atribuida a la dirección principal de circulación del agua (Este a Oeste). La especiación química de Fe, Cr y Ni muestra que están esencialmente relacionados con la fracción residual (Fe: 34,8%, Cr: 37,4% y Ni: 37,9%), mientras que Pb, Zn, Cu y Cd se encontraron mayoritariamente en la fracción no residual. -fracción residual (fracción lábil Pb: 89,4%, Zn: 26,1%, Cu: 71,8% y Cd: 84,3%). Estos elementos (Pb, Zn, Cu y Cr) tienen un alto potencial de biodisponibilidad. La mayor contaminación se encontró en el lado oeste de la laguna, según los factores de contaminación global calculados. Además, los factores de contaminación individuales, Pb seguido de Zn y Cu, presentaron el mayor riesgo de contaminación. Este estudio muestra que, incluso después de la operación de dragado, la persistencia de bajas concentraciones de algunos contaminantes puede causar problemas ambientales en determinadas condiciones físico-químicas

Occurrence, origin and potential ecological risk of dissolved polycyclic aromatic hydrocarbons and organochlorines in surface waters of the Gulf of Gabès (Tunisia, Southern Mediterranean Sea)

International audienceWe investigated the occurrence, origin, and potential ecological risk of dissolved polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyl (PCBs) and organochlorine pesticides (OCPs) in 27 surface water samples collected from a highly anthropized and industrialized area in the Gulf of Gabès (Tunisia, Southern Mediterranean Sea) in October–November 2017. The results demonstrated a wide range of concentrations (ng L−1) with the following decreasing order: Ʃ16 PAHs (17.6–71.2) > Ʃ20 PCBs (2.9–33.7) > Ʃ6 DDTs (1.1–12.1) > Ʃ4 HCHs (1.1–14.8). Selected diagnostic ratios indicated a mixture of both pyrolytic and petrogenic sources of PAHs, with a predominance of petrogenic sources. PCB compositions showed distinct contamination signatures for tetra- to hepta-chlorinated PCBs, characteristic of contamination by commercial (Aroclor) PCB mixtures. The dominant OCP congeners were γ-HCH, 2,4′-DDD and 2,4′-DDE, reflecting past use of Lindane and DDTs in the study area. Agricultural, industrial and domestic activities, as well as atmospheric transport are identified as potential sources of PAHs, PCBs and OCPs in surface waters of the Gulf of Gabès. Toxic equivalents (TEQs) suggested a low carcinogenic potential for PAHs in seawater samples (mean of 0.14 ng TEQ L−1). Evaluation of risk coefficients revealed low risk for PAHs and PCBs, and moderate to severe risk for OCPs

Occurrence, origin and potential ecological risk of dissolved polycyclic aromatic hydrocarbons and organochlorines in surface waters of the Gulf of Gabès (Tunisia, Southern Mediterranean Sea)

International audienc

Hydrocarbons in size-fractionated plankton of the Mediterranean Sea (MERITE-HIPPOCAMPE campaign)

International audienc

Contamination of planktonic food webs in the Mediterranean Sea: Setting the frame for the MERITE-HIPPOCAMPE oceanographic cruise (spring 2019)

International audienceThis paper looks at experiential feedback and the technical and scientific challenges tied to the MERITE-HIPPOCAMPE cruise that took place in the Mediterranean Sea in spring 2019. This cruise proposes an innovative approach to investigate the accumulation and transfer of inorganic and organic contaminants within the planktonic food webs. We present detailed information on how the cruise worked, including 1) the cruise track and sampling stations, 2) the overall strategy, based mainly on the collection of plankton, suspended particles and water at the deep chlorophyll maximum, and the separation of these particles and planktonic organisms into various size fractions, as well as the collection of atmospheric deposition, 3) the operations performed and material used at each station, and 4) the sequence of operations and main parameters analysed. The paper also provides the main environmental conditions that were prevailing during the campaign. Lastly, we present the types of articles produced based on work completed by the cruise that are part of this special issue