43 research outputs found
Influence of the Cu-Te composition and microstructure on the resistive switching of Cu-Te/Al(2)O(3)/Si cells
In this letter, we explore the influence of the Cu(x)Te(1-x) layer composition (0.2 0.7 leads to large reset power, similar to pure-Cu electrodes, x < 0.3 results in volatile forming properties. The intermediate range 0.5< x < 0.7 shows optimum memory properties, featuring improved control of filament programming using <5 mu A as well as state stability at 85 degrees C. The composition-dependent programming control and filament stability are closely associated with the phases in the Cu(x)Te(1-x) layer and are explained as related to the chemical affinity between Cu and Te. (C) 2011 American Institute of Physics. [doi: 10.1063/1.3621835
Evidence for structural and electronic instabilities at intermediate temperatures in -(BEDT-TTF)X for X=Cu[N(CN)]Cl, Cu[N(CN)]Br and Cu(NCS): Implications for the phase diagram of these quasi-2D organic superconductors
We present high-resolution measurements of the coefficient of thermal
expansion of the quasi-twodimensional
(quasi-2D) salts -(BEDT-TTF)X with X = Cu(NCS), Cu[N(CN)]Br
and Cu[N(CN)]Cl. At intermediate temperatures (B), distinct anomalies
reminiscent of second-order phase transitions have been found at
K and 45 K for the superconducting X = Cu(NCS) and Cu[N(CN)]Br salts,
respectively. Most interestingly, we find that the signs of the uniaxial
pressure coefficients of are strictly anticorrelated with those of
. We propose that marks the transition to a spin-density-wave
(SDW) state forming on minor, quasi-1D parts of the Fermi surface. Our results
are compatible with two competing order parameters that form on disjunct
portions of the Fermi surface. At elevated temperatures (C), all compounds show
anomalies that can be identified with a kinetic, glass-like
transition where, below a characteristic temperature , disorder in the
orientational degrees of freedom of the terminal ethylene groups becomes frozen
in. We argue that the degree of disorder increases on going from the X =
Cu(NCS) to Cu[N(CN)]Br and the Cu[N(CN)]Cl salt. Our results
provide a natural explanation for the unusual time- and cooling-rate
dependencies of the ground-state properties in the hydrogenated and deuterated
Cu[N(CN)]Br salts reported in the literature.Comment: 22 pages, 7 figure
Influence of the Cu-Te composition and microstructure on the resistive switching of Cu-Te/Al 2
Influence of internal disorder on the superconducting state in the organic layered superconductor kappa-(BEDT-TTF)2Cu[N(CN)2]Br
We report high-sensitivity AC susceptibility measurements of the penetration
depth in the Meissner state of the layered organic superconductor
kappa-(BEDT-TTF)2Cu[N(CN)2]Br. We have studied nominally pure single crystals
from the two different syntheses and employed controlled cooling procedures in
order to minimize intrinsic remnant disorder at low temperatures associated
with the glass transition, caused by ordering of the ethylene moieties in
BEDT-TTF molecule at T_G = 75 K. We find that the optimal cooling procedures
(slow cooling of -0.2 K/h or annealing for 3 days in the region of T_G) needed
to establish the ground state, depend critically on the sample origin
indicating different relaxation times of terminal ethylene groups. We show
that, in the ground state, the behavior observed for nominally pure single
crystals from both syntheses is consistent with unconventional d-wave order
parameter. The in-plane penetration depth lambda_in(T) is strongly linear,
whereas the out-of-plane component lambda_out(T) varies as T^2. In contrast,
the behavior of single crystals with long relaxation times observed after slow
(-0.2 K/h) cooling is as expected for a d-wave superconductor with impurities
(i.e. lambda_in(T) propto lambda_out(T) propto T^2) or might be also reasonably
well described by the s-wave model. Our results might reconcile the
contradictory findings previously reported by different authors.Comment: 13 pages, 10 figures, submitted to Phys. Rev.
Cobaloxime complex salts : synthesis, patterning on carbon nanomembranes and heterogeneous hydrogen evolution studies
Cobaloximes are promising, earth-abundant catalysts for the light-driven hydrogen evolution reaction. Typically, these cobalt(III) complexes are prepared in situ or employed in their neutral form, e.g. [Co(dmgH 2 )(py)Cl], even though related complex salts have been reported previously and could in principle offer improved catalytic activity as well as more efficient immobilization on solid support. Here we report an interdisciplinary investigation into complex salts [Co(dmgH) 2 (py) 2 ] + [Co(dmgBPh 2 ) 2 Cl 2 ] - , TBA + [Co(dmgBPh 2 ) 2 Cl 2 ] - and [Co(dmgH) 2 (py) 2 ] + BArF - . We describe their strategic syntheses from commercially available complex [Co(dmgH) 2 (py)Cl] and demonstrate that these double and single complex salts are potent catalysts for the light-driven hydrogen evolution reaction. We also show that scanning electrochemical cell microscopy can be used to deposit arrays of catalysts [Co(dmgH) 2 (py) 2 ] + [Co(dmgBPh 2 ) 2 Cl 2 ] - and [Co(dmgH) 2 (py)Cl] on supported and free-standing amino-terminated ~ 1 nm thick carbon nanomembranes (CNMs). Photocatalytic H 2 evolution at such arrays was quantified with Pd microsensors using scanning electrochemical microscopy, thus providing a new approach for catalytic evaluation and opening up novel routes for the creation and analysis of “designer catalyst arrays”, nano-printed in a desired pattern on a solid support
The Effect of Chemical Doping and Hydrostatic Pressure on Tc of Y1-yCayBa2Cu3Ox Single Crystals
We performed susceptibility measurements on Y1-yCayBa2Cu3Ox single crystals
under high He pressure. For each Ca content various samples with different
oxygen contents have been prepared to probe the influence of Ca on Tc(x),
dTc/dp(x) and Tc,max. Starting from the parabolic Tc(nh) behavior we calculated
nh values from Tc and Tc,max for each sample. It is shown that in the overdoped
region dTc/dp can be described by a pressure induced charge transfer with
dnh/dp = 3.7E-3 [1/GPa] and a dTc,max/dp value of 0.8 K/GPa, irrespective of
the Ca content. In the underdoped region additional pressure effects lead to a
peak in dTc/dp at approximately 0.11 holes/CuO2 plane. However, with increasing
Ca content this peak is strongly depressed. This is explained in terms of an
increasing disorder in the CuO chain system due to doping. Deviations in dTc/dp
at very low nh values can be assigned to the ortho II ordering in the CuO chain
system.Comment: 13 pages with 6 figures, accepted for publication in Physica
Species Delimitation in Taxonomically Difficult Fungi: The Case of Hymenogaster
False truffles are ecologically important as mycorrhizal partners of trees and evolutionarily highly interesting as the result of a shift from epigeous mushroom-like to underground fruiting bodies. Since its first description by Vittadini in 1831, inappropriate species concepts in the highly diverse false truffle genus Hymenogaster has led to continued confusion, caused by a large variety of prevailing taxonomical opinions.In this study, we reconsidered the species delimitations in Hymenogaster based on a comprehensive collection of Central European taxa comprising more than 140 fruiting bodies from 20 years of field work. The ITS rDNA sequence dataset was subjected to phylogenetic analysis as well as clustering optimization using OPTSIL software.Among distinct species concepts from the literature used to create reference partitions for clustering optimization, the broadest concept resulted in the highest agreement with the ITS data. Our results indicate a highly variable morphology of H. citrinus and H. griseus, most likely linked to environmental influences on the phenology (maturity, habitat, soil type and growing season). In particular, taxa described in the 19(th) century frequently appear as conspecific. Conversely, H. niveus appears as species complex comprising seven cryptic species with almost identical macro- and micromorphology. H. intermedius and H. huthii are described as novel species, each of which with a distinct morphology intermediate between two species complexes. A revised taxonomy for one of the most taxonomically difficult genera of Basidiomycetes is proposed, including an updated identification key. The (semi-)automated selection among species concepts used here is of importance for the revision of taxonomically problematic organism groups in general
Certain Families of Multivalent Analytic Functions Associated with Iterations of the Owa-Srivastava Fractional Differintegral Operator
By making use of a multivalent analogue of the
Owa-Srivastava fractional differintegral operator and its
iterations, certain new families of analytic functions are
introduced. Several interesting properties of these function
classes, such as convolution theorems, inclusion theorems, and
class-preserving transforms, are studied
Effect of tilted plate vibration on solidification and microstructural and mechanical properties of semisolid cast and heat-treated A356 Al alloy
Peculiarities of the Electronic Properties of the κ-Phase Structures (BEDT-TTF)Cu(N(CN))X with X=Cl, Br, I
The structure of the title compounds is similar to other κ-phase structures with respect to the checkerboard-like arrangement of the ET dimers (ET = BEDT-TTF) in the conducting planes, but different by the tilt alternation of these dimers in successive planes. The resulting inequivalence of these planes tends to destabilize the metallic state which becomes extremely sensitive to changes in the S-S overlaps of neighbouring ET molecules. Such changes may result from anion substitution, lattice expansion, or also from ordering effects of the ethylene end groups of the ET molecules. They lead to quite different electronic properties of the three isostructural compounds. We focus especially on the strongly pressure-dependent properties of the Cl-compound, where a coexistence of magnetically ordered and superconducting states with rather spectacular superconducting reentrance effects is observed