Two aspects of decadal ENSO variability modulating the long-term global carbon cycle

The El Niño–Southern Oscillation (ENSO) drives variations in terrestrial carbon fluxes by affecting the terrestrial ecosystem via atmospheric teleconnections and thus plays an important role in interannual variability of the global carbon cycle. However, we lack such knowledge on decadal time scales, that is, how the carbon cycle can be affected by decadal variations of ENSO characteristics. Here we examine how, and by how much, decadal ENSO variability affects decadal variability of the global carbon cycle by analyzing a 1,801‐year preindustrial control simulation. We identify two different aspects, together explaining ~36% of the decadal variations in the global carbon cycle. First, climate variations induced by decadal ENSO‐like variability regulate terrestrial carbon flux and hence atmospheric CO2 on decadal time scales. Second, decadal changes in the asymmetrical response of the terrestrial ecosystem, resulting from decadal modulation of ENSO amplitude and asymmetry, rectify the background mean state, thereby generating decadal variability of land carbon fluxes

Fracture of a Tempofilter II: an Initial Case Report

Tempofilter II is a device that is used for pulmonary embolism prophylaxis. Since the appearance of the Tempofilter II following withdrawal of the Tempofilter I, it has been reported that the Tempofilter II is safe, effective and useful. Here we report on the first case of a fracture of one leg of the filter and this leg was embedded in the inferior vena cava wall in a 62-year-old man with deep vein thrombosis

ENSO and the Carbon Cycle

This is the author accepted manuscript. The final version is available from the American Geophysical Union via the DOI in this recordObservational studies of atmospheric CO2, land ecosystems, and ocean processes show that variability in the carbon cycle is closely related with ENSO. Years with a warm anomaly in the tropical Pacific show a faster CO2 rise due to weaker land carbon sinks, particularly in the tropics, with a partial offset by stronger net uptake by oceans. The opposite happens in years with cool Pacific SST anomalies. This relationship holds for small ENSO SST anomalies as well as large ones and is robust enough for the annual CO2 growth rate anomaly to be highly predictable on the basis of SST observations and forecasts. Generally, variability in the land‐atmosphere carbon flux is mainly driven by physiological processes (photosynthesis and/or respiration), with a smaller contribution from fire. Fire was important in the 1997–1998 El Niño, making a major contribution to the CO2 rise, which can be viewed as anthropogenic in nature since the ignition was caused by humans. However, in the 2015–2016 El Niño event, the change in land carbon flux was mainly due to physiological processes, particularly reduced productivity. In the oceans, El Niño conditions involve decreased upwelling of carbon in the equatorial Pacific due to a weakening of the trade winds, causing this region to become a weaker sink of CO2, or near neutral if the El Niño event is strong. The year‐to‐year variations in the rate of CO2 rise can be successfully reconstructed and predicted on the basis of sea surface temperatures in the Pacific. ENSO‐CO2 relationships may also provide an emergent constraint on the strength of climate‐carbon cycle feedbacks on future anthropogenic climate change

Three-dimensional structure of Schistosoma japonicum glutathione S-transferase fused with a six-amino acid conserved neutralizing epitope of gp41 from HIV

The 3-dimensional crystal structure of glutathione S-transferase (GST) of Schistosoma japonicum (Sj) fused with a conserved neutralizing epitope on gp41 (glycoprotein, 41 kDa) of human immunodeficiency virus type 1 (HIV-1) was determined at 2.5 A resolution. The structure of the 3-3 isozyme rat GST of the mu gene class was used as a molecular replacement model. The structure consists of a 4-stranded beta-sheet and 3 alpha-helices in domain 1 and 5 alpha-helices in domain 2. The space group of the Sj GST crystal is P4(sub 3)2(sub 1)2 with unit cell dimensions of a = b = 94.7 A, and c = 58.1 A. The crystal has 1 GST monomer per asymmetric unit, and 2 monomers that form an active dimer are related by crystallographic 2-fold symmetry. In the binding site, the ordered structure of reduced glutathione is observed. The gp41 peptide (Glu-Leu-Asp-Lys-Trp-Ala) fused to the C-terminus of Sj GST forms a loop stabilized by symmetry-related GSTs. The Sj GST structure is compared with previously determined GST structures of mammalian gene classes mu, alpha, and pi. Conserved amino acid residues among the 4 GSTs that are important for hydrophobic and hydrophilic interactions for dimer association and glutathione binding are discussed

Synthesis and characterisation of pyrene-labelled polydimethylsiloxane networks: towards the in situ detection of strain in silicone elastomers

Pyrene-substituted polyhydromethylsiloxanes (PHMS-Py-x) were synthesised by the hydrosilylation reaction of prop-3-enyloxymethylpyrene with polyhydromethylsiloxane (M-n = 3700). The ratio of pyrene substituent to Si-H unit was varied to afford a range of pyrene-functionalised polysiloxanes. These copolymers were subsequently incorporated into polydimethylsiloxane (PDMS) elastomers by curing via either Pt(0) catalysed hydrosilylation with divinyl-terminated PDMS (M-n = 186) and tetrakis(dimethylsiloxy) silane, or Sn(II) catalysed condensation with alpha,omega-dihydroxyPDMS (M-n = 26 000) and tetraethoxysilane. An alternative method involving the synthesis and integration of [3-(pyren-1-ylmethoxy)propyl]triethoxysilane (Py-TEOS) into PDMS elastomers was also investigated: a mixture of alpha,omega-dihydroxyPDMS (M-n = 26 000), tetraethoxysilane, and Py-TEOS was cured using an Sn( II) catalyst. Certain of the resulting fluorescent pyrene-labelled elastomers were studied by differential scanning calorimetry and dynamic mechanical analysis. No significant changes were observed in the thermal or mechanical properties of the elastomers containing pyrene when compared to otherwise identical samples not containing pyrene. All of the pyrene-containing elastomers were demonstrated to be fluorescent under suitable excitation in a photoluminescent spectrometer. Two of the elastomers were placed in a photoluminescence spectrometer and subjected to cycles of extension and relaxation (strain = 0-16.7%) while changes in the emission spectra were monitored. The resulting spectra of the elastomer containing the PHMS-Py-50 copolymers were variable and inconsistent. However, the emission peaks of elastomers containing Py-TEOS displayed clear and reproducible changes in fluorescence intensity upon stretching and relaxation. The intensity of the monomer and excimer emission peaks was observed to increase with elongation of the sample and decrease upon relaxation. Furthermore, the ratio of the intensities of the excimer : monomer peak decreased with elongation and increased with relaxation. In neither case was there appreciable hysteresis, suggesting that fluorescent labelling of elastomers is a valid approach for the non-invasive in situ monitoring of stress and strain in such materials

Abyssal Atlantic circulation during the Last Glacial Maximum: Constraining the ratio between transport and vertical mixing

The ocean’s role in regulating atmospheric carbon dioxide on glacial‐interglacial timescales remains an unresolved issue in paleoclimatology. Reduced mixing between deep water masses may have aided oceanic storage of atmospheric CO_2 during the Last Glacial Maximum (LGM), but data supporting this idea have remained elusive. The δ^(13)C of benthic foraminifera indicate the Atlantic Ocean was more chemically stratified during the LGM, but the nonconservative nature of δ^(13)C complicates interpretation of the LGM signal. Here we use benthic foraminiferal δ^(18)O as a conservative tracer to constrain the ratio of meridional transport to vertical diffusivity in the deep Atlantic. Our calculations suggest that the ratio was at least twice as large at the LGM. We speculate that the primary cause was reduced mixing between northern and southern component waters, associated with movement of this water mass boundary away from the zone of intense mixing near the seafloor. The shallower water mass boundary yields an order of magnitude increase in the volume of southern component water, suggesting its residence time may have increased substantially. Our analysis supports the idea that an expanded volume of Antarctic Bottom Water and limited vertical mixing enhanced the abyssal ocean’s ability to trap carbon during glacial times

Confounding Factors Affecting the Marginal Quality of an Intra-Oral Scan

Objectives: To assess the effect of clinical factors on the quality of intra-oral scans of crown margins. These factors are; presence of adjacent teeth, proximity to gingivae, encumbrance of wand positioning within oral cavity. Methods: A typodont lower molar (Frasaco, Germany) was prepared for an all-ceramic crown with 1.5 mm supraginigival (lingual) and equigingival (buccal) margins. The tooth was scanned in a model scanner, creating a master scan. An intra-oral scanner (IOS) (Omnicam, Sirona Dental) was used to acquire sets of 5 scans each, under varying conditions; (1) the presence/absence of adjacent teeth, (2) model mounted in manikin head/hand-held, (3) with/without a 1 mm shim to elevate the margin. Every combination was investigated, yielding 40 scans (8 groups of 5). The master scan margin was identified by selecting the highest curvature region (>1.8). The master was aligned to each IOS scan, and 4 regions of each IOS scan margin were extracted, lying within 100 μm of predefined mesial, distal, buccal and lingual sections of the master margin. The mean curvature of each margin section was calculated using Meshlab. The effect of each confounding factor on margin curvature was analysed using ANOVA. Results: Lingual margin curvature remained consistent regardless of scanning conditions. Buccal margin curvature was significantly affected when located equigingivally. Mesial margin curvature was significantly affected in the presence of adjacent teeth and proximity to the gingivae. Distal margin curvature was significantly affected by all three confounding factors. Conclusions: The curvature (sharpness) of the margin recorded by a commercial IOS is significantly affected by clinical factors obscuring visibility

Spatio-temporally Resolved Methane Fluxes From the Los Angeles Megacity

We combine sustained observations from a network of atmospheric monitoring stations with inverse modeling to uniquely obtain spatiotemporal (3‐km, 4‐day) estimates of methane emissions from the Los Angeles megacity and the broader South Coast Air Basin for 2015–2016. Our inversions use customized and validated high‐fidelity meteorological output from Weather Research Forecasting and Stochastic Time‐Inverted Lagrangian model for South Coast Air Basin and innovatively employ a model resolution matrix‐based metric to disentangle the spatiotemporal information content of observations as manifested through estimated fluxes. We partially track and constrain fluxes from the Aliso Canyon natural gas leak and detect closure of the Puente Hills landfill, with no prior information. Our annually aggregated fluxes and their uncertainty excluding the Aliso Canyon leak period lie within the uncertainty bounds of the fluxes reported by the previous studies. Spatially, major sources of CH_4 emissions in the basin were correlated with CH_4‐emitting infrastructure. Temporally, our findings show large seasonal variations in CH_4 fluxes with significantly higher fluxes in winter in comparison to summer months, which is consistent with natural gas demand and anticorrelated with air temperature. Overall, this is the first study that utilizes inversions to detect both enhancement (Aliso Canyon leak) and reduction (Puente Hills) in CH_4 fluxes due to the unintended events and policy decisions and thereby demonstrates the utility of inverse modeling for identifying variations in fluxes at fine spatiotemporal resolution

Organizational culture, internal marketing, and perceived organizational support in portuguese higher education institutions

Changes imposed on public higher education institutions try to adopt some management practices in public organizations. In this study, we intend to understand how organizational culture (support, innovation, goals, rules) and internal marketing can contribute to the organizational support of employees of higher education institutions. The study was developed with a sample of 635 employees. The results show that organizational culture and internal marketing contribute to the explanation of perceived organizational support (POS). Then, through a structural equation model, it was possible to confirm the contribution of support culture and internal marketing to the explanation of POS. More studies are necessary taking students' point of view into account. These results reveal the importance of the fact that organizations need to implement a culture of support and appropriate internal communication networks that allow employees to perceive social support.FCT-Foundation for Science and Technology [UID/SOC/04020/2013