Theoretical study of the photoconduction and photomagnetism of the BPY[Ni(dmit)2]2 molecular crystal

The BPY[Ni(dmit)2]2 molecular crystal synthesized by Naito and coworkers (J. Am. Chem. Soc., 2012, 134, 18656) was characterized as a photo-magnetic-conductor. This crystal is a nonmagnetic semiconductor in the dark and becomes a magnetic conductor after UV irradiation. This work analyzes the key ingredients of the observed photomagnetism and photoconduction by means of wavefunction-based calculations on selected fragments and periodic calculations on the whole crystal. Our results demonstrate that UV-Vis light induces charge transfer processes between the closest [Ni(dmit)2]− and BPY2+ units, that introduce unpaired electrons on the unoccupied orbitals of the BPY cations. Since the conduction bands present a strong mixing of BPY and Ni(dmit)2, the optically activated anion–cation charge transfer enhances the conductivity. The photoinduced (BPY2+)* radicals can indeed interact with the close Ni(dmit)2 units, with non-negligible spin–spin magnetic couplings, which are responsible for the changes induced by the irradiation on the temperature dependence of the magnetic susceptibility.Ministerio de Economía y Competitividad de España y fondos FEDER. CTQ-2015-69019-

The acute effect of different intensity aerobic and resistance training exercise on the body image in adult women

The purpose of the study was to evaluate the acute effect of different intensity aerobic (AE) and resistance training (RT) exercises on BI in adult women. Participants were 62 adult women (19.47 ± 2.53 yr., range 18 a 33 yr.), who were randomly assigned to three sessions of either: 1) Control group, 2) Low-intensity AE, 3) High-intensity AE, 4) Low-intensity RT, or 5) High-intensity RT. Before and immediately following each experimental intervention, BI, body weight, and arm and leg circumferences were measured. Three familiarization sessions were performed every 7 days before the AE and RT experimental interventions. Also, 5-RM tests were performed one week before the RT experimental interventions. Data were analyzed using mixed 3-way ANOVA, mixed 4-way ANOVA, and post-hoc analysis. An acute effect of RT on BI was observed, regardless of the exercise intensity, women felt more muscular immediately following the RT session. Regardless of the exercise intensity, 30-min of acute RT exercise changed BI perception, contrary to 30 min AE

Multiwavelength characterisation of an ACT-selected, lensed dusty star-forming galaxy at z=2.64

We present \ci\,(2--1) and multi-transition $^{12}$CO observations of a dusty star-forming galaxy, ACT\,J2029+0120, which we spectroscopically confirm to lie at $z$\,=\,2.64. We detect CO(3--2), CO(5--4), CO(7--6), CO(8--7), and \ci\,(2--1) at high significance, tentatively detect HCO$^{+}$(4--3), and place strong upper limits on the integrated strength of dense gas tracers (HCN(4--3) and CS(7--6)). Multi-transition CO observations and dense gas tracers can provide valuable constraints on the molecular gas content and excitation conditions in high-redshift galaxies. We therefore use this unique data set to construct a CO spectral line energy distribution (SLED) of the source, which is most consistent with that of a ULIRG/Seyfert or QSO host object in the taxonomy of the \textit{Herschel} Comprehensive ULIRG Emission Survey. We employ RADEX models to fit the peak of the CO SLED, inferring a temperature of T$\sim$117 K and $n_{\text{H}_2}\sim10^5$ cm$^{-3}$, most consistent with a ULIRG/QSO object and the presence of high density tracers. We also find that the velocity width of the \ci\ line is potentially larger than seen in all CO transitions for this object, and that the $L'_{\rm C\,I(2-1)}/L'_{\rm CO(3-2)}$ ratio is also larger than seen in other lensed and unlensed submillimeter galaxies and QSO hosts; if confirmed, this anomaly could be an effect of differential lensing of a shocked molecular outflow.Comment: Accepted for publication in Ap

Cerámicas prerromanas del castillo de Aroche (Huelva)

Se estudia en este trabajo un conjunto cerámico de época prerromana registrado en las excavaciones del castillo medieval de Aroche (Huelva)._________________________In this work are presented the preroman pottery registered in the archaeological excavation made in the medieval castle of Aroche (Huelva, SW Spain), near to Reina's Gate

Use of antifungal Saponin SC-2 of Solanum chrysotrichum for the treatment of vulvovaginal candidiasis: in vitro studies and clinical experiences

Saponin SC-2 from Solanum chrysotrichum showed antifungal activity, demonstrated in vitro, which inhibited the growth of dermatophytes, and in vivo, to be effective in the treatment against tinea pedis and pityriasis capitis. Fungistatic and fungicidal activity of saponin SC-2 on Candida albicans and other Candida species, fluconazole and ketoconazole resistaent strains was demostrated. SC-2-associated ultrastructural alterations in several Candida species were observed. An exploratoryclinical, randomized, double-blind, and controlled ketoconazole study of ketoconazole was conducted with the aim of assessing the effectiveness and tolerability of an herbal medicinal product containing SC-2, on women with Vulvovaginal candidiasis (VVC). The results exhibited a percentage of therapeutic clinical effectiveness similar to that of ketoconazole (X2, p .0.30), but obtained a smaller percentage of mycological effectiveness, and 100% tolerability. In conclusion, saponin SC-2 possesses fungicidale and fungistatic activity on Candida albicans and other multi resistant Candida species, causes morphological changes and fungal death, and it is an alternative therapy for the treatment of VVC.Key words: Solanum chrysotrichum, saponins, antifungal activity, vulvovaginal candidiasis, alternative therapy

Regeneration of ortho-chlorophenol-exhausted activated carbons with liquid water at high pressure and temperature

[EN]A study was undertaken of the regeneration of three activated carbons exhausted with ortho-chlorophenol. The regeneration process was carried out using liquid water at 623 K and 150 atm in the absence of oxygen. The efficiency of this procedure was analyzed by determining the rate and amount of ortho-chlorophenol adsorbed in successive adsorption–regeneration cycles. The present procedure showed a much greater efficiency than that reported for chemical and/or thermal regeneration. Effects of this regeneration on the adsorption kinetics, adsorption capacity and textural characteristics of the carbon were investigated. The increase in adsorption capacity of the regenerated carbon compared with that of the original carbon seems mainly due to the opening of porosity during the regeneration treatment

Informe de campaña GeoPLOCAN1212

Informe de campaña de los trabajos realizados en la cmpaña oceanográfica GeoPLOCAN1212Esta campaña ha consistido en una prospección por métodos Geofísicos de los fondos que albergarán en un futuro la Infraestructura Científico Técnica Singular (ICTS) PLOCAN; Plataforma Oceánica de Canarias. Los trabajos se han llevado a cabo a bordo del B/O Ángeles Alvariño, y en ellos han participado, junto al IEO, el IHM Instituto Hidrográfico de la Marina, y la UB Universidad de Barcelona. Las tres instituciones han puesto en común el personal participante que ha desarrollado además de la tarea conjunta y compartida de la adquisición de los datos, otras tareas del interés particular de cada organismo como la formativa en el caso de la UB, la de obtención de datos brutos y procesado para la edición de cartas náuticas en el caso del IHM, y la de obtención de datos y procesado con fines científicos desarrollada por el personal del IEOPLOCAN, IEO, IH

SEOM clinical guideline for the diagnosis and treatment of gastric cancer (GC) and gastroesophageal junction adenocarcinoma (GEJA) (2019)

Gastric cancer (GC) is the fifth most common cancer worldwide with a varied geographic distribution and an aggressive behavior. In Spain, it represents the sixth cause of cancer death. In Western countries, the incidence is decreasing slightly, with an increase in gastroesophageal junction adenocarcinoma (GEJA), a different entity that we separate specifically in the guideline. Molecular biology advances have been done recently, but do not yet lead to the choice in treatment approach except in advanced disease with overexpression of HER2. Endoscopic resection in very early stage, perioperative chemotherapy in locally advanced tumors and preliminary immune therapy resulting in advanced disease are the main treatment innovations in the GC/GEJA treatment. We describe the different evidences and recommendations following the statements of the American College of Physicians