Tunable white light emission from glass-ceramics containing Eu2+, Tb3+, Eu3+ co-doped SrLaF5 nanocrystals

International audienceThe Eu2 +/Tb3 +/Eu3 + co-doped fluorosilicate glass ceramics containing SrLaF5 nanocrystals were prepared. XRD results showed the rare earth ions were enriched into the precipitated nanophase. It deduced efficient energy transfers (ET) from Eu2 + to Tb3 + and Eu3 + and intense warm white luminescence of the glass ceramics. Comparing the glass, the luminescence quantum yield (QY) of the glass ceramics was enlarged by about 3 times. That demonstrated the potential WLED application of the present glass ceramics

White light generation of glass ceramics containing Ba2LaF7: Eu2+,Tb3+ and Sm3+ nanocrystals

International audienceThe Eu2+/Tb3+/Sm3+ co-doped oxyfluoride glass ceramics containing Ba2LaF7 nanocrystals are prepared in the reducing atmosphere. The X-ray diffraction results show that Eu2+, Tb3+ and Sm3+ ions are enriched into the precipitated Ba2LaF7 nanophase after the annealing process. It deduces efficient energy transfers from Eu2+ to Tb3+ and Sm3+ and intenses warm white luminescence of the glass ceramics. Comparing with the glass, the luminescence quantum yield of the glass ceramics is also enlarged by about 3 times. This demonstrates the potential white light-emitting diode application of the glass ceramics produced in this letter

Preparation and photoluminescence properties of fluorosilicate glass ceramics containing CeOF: Dy3+ nanocrystals

International audienceThe Ce3+ and Dy3+ co-doped oxyfluoride glasses and glass ceramics containing CeOF or CeF3 nanocrystals have been prepared in the reducing atmosphere. The crystallinity increased significantly with the Ce3+ concentration, while the crystal size of nanocrystals is mainly influenced by the annealing temperatures. The glasses and glass ceramics emitted white light, deriving from a combination of the Ce3+ blue and the Dy3+ yellow light. The emission intensity and CIE chromaticity coordinates of the Ce3+ and Dy3+ co-doped glasses can be tuned by adjusting the ratio of Ce3+/Dy3+ concentration or the annealing temperature

Preparation and luminescence properties of Ce3+/Dy3+-codoped fluorosilicate glass ceramics

International audienceThe Ce3+and Dy3+ co-doped fluorosilicate glass and glass ceramics containing SrF2 or CeF3 nanocrystals were prepared under reducing atmosphere. The precipitated nano-crystalline phase shifted from cubic SrF2 to hexagonal CeF3 gradually with the heat treatment temperature increasing from 620 to 680 °C. The glass and glass ceramics emitted white light, deriving from a combination of the Ce3+ blue and the Dy3+ yellow light. The CIE coordinates could be tuned by adjusting the ratio of Ce3+/Dy3+ concentration. The luminescence could be enhanced significantly by annealing the samples at the temperatures lower than 640 °C