Vitesses de réaction de dissolution et précipitation au voisinage de l'interface oxydo-réducteur dans un lac méromictique : le lac Pavin (Puy de Dôme, France)

Une étude à l'échelle centimétrique de l'interface redox situé à la limite entre mixolimnion et monimolimnion d'un lac méromictique (le lac Pavin) a permis d'observer très finement l'évolution de la concentration d'un certain nombre d'éléments chimiques. Nous avons choisi de présenter ici des résultats concernant 5 éléments qui présentent des comportements très contrastés : le rubidium, le fer, le baryum, le vanadium et le manganèse. La comparaison avec un élément conservatif, le sodium, montre que Rb est conservatif, que Fe, Ba et V sont précipités et que Mn est dissous dans cette zone.Une modélisation de ces concentrations en vue de préciser à quelle profondeur et avec quelle vitesse se produisent les réactions concernant ces éléments nécessite la détermination des paramètres de transport au voisinage de cet interface.Une représentation analytique des concentrations de sodium permet de calculer le coefficient de diffusion turbulente Kz en fonction de la profondeur. Au voisinage de l'interface redox, ce coefficient est très petit (0,0017m2/jour) et inférieur au coefficient de diffusion thermique moléculaire.Les concentrations des éléments étudiés ont pu être représentés avec précisions par des polynômes en fonction de la concentration en sodium.Cela permet d'estimer les vitesses des réactions de précipitation dissolution en fonction de la profondeur. Le rubidium n'est affecté par aucune réaction. Le fer précipite entre 63 et 65 m, le baryum entre 68 et 72 m tandis que le vanadium précipite à la fois dans ces 2 zones. Le manganèse réagit dans une zone très étroite : il est précipité entre 61,5 et 62 m et dissous entre 62,8 et 63,1 m.Une étude similaire de tous les éléments majeurs (y compris pH et COD) pourrait permettre d'élucider les processus qui conduisent à ces comportements complexes.Lake Pavin, French Massif Central, is the main meromictic lake in France and has been extensively studied from more than 50 years. The upper part (mixolimnion) at a depth of less than about 60 m behaves as an oligotrophic lake and is oxic during the major part of the year. The lower layer (monimolimnion) has a higher salinity and is permanently anoxic. Unlike the top of the mixolimnion, element concentrations in the monimolimnion can be considered at steady state. The boundary between mixolimnion and monimolimnion is a redox interface. At this interface, an important number of both chemical and biochemical reactions occur. This boundary, where element concentrations vary greatly, was studied at the centimeter scale between 58 and 64 m depth. The present paper is focused on five elements showing very different behaviour: rubidium, iron, manganese, vanadium and barium. Sodium was used as a reference element. Sodium and rubidium concentrations had similar patterns: a progressive increase began at 61 m depth and the maximal gradient was located at 63 m. They continue to increase towards the bottom of the lake. Iron concentrations were low (< 1 µmol/L) at a depth less than 62.8 m and increased very sharply below this depth. Manganese concentrations were very low in the mixolimnion(<0.01 µmol/L), exhibited a peak between 62.4 and 63.5 m depth (up to 60 µmol/L at 63 m) and reached a value of about 30 µmol/L at 85 m. Barium concentrations began to increase only at depths greater than 65-67 m. Vanadium concentrations in the mixolimnion were about 14 nmol/L, decreased to a minimum below the detection limit at 62.2 m and then increase drastically (150 nmol/L at 85 m).In order to derive the accurate location of the chemical reactions and an estimation of their rates from the concentration profiles, knowledge of the transport parameters was needed. As advection can be considered to be negligible, the major parameter of interest is the vertical eddy diffusion coefficient Kz. Na is assumed to be unreactive in the studied layer. Its concentrations can be represented by an analytical function      Cmax - Cmin                 Cmax + CminC = ___________ * th [P(z)] + ___________             2                                    2with P(z)=0.0016 * (z-zo)3 - 0.0493 * (z-zo)2 + 0.5735 * (z-zo) - 0.4811This allows the determination of the coefficient Kz.Kz = λ ch2 [P(z)]/ [P'(z)]λ is determined from the value of Kz at 85 m depth previously obtained from an hydrodynamic study of the lake (Aeshbach-Hertig et al., 1999). This coefficient is about 0.1 m2/day at the bottom of the monimolimnion. It is very low at the redox interface (0.0017 m2/day), far below the molecular thermal diffusion coefficient. It increases very sharply at the bottom of the mixolimnion. The Kz profile is in fair agreement with the results obtained from the earlier hydrodynamic study. A quantitative study of the dissolution-precipitation reactions at the center of the lake at depths between 55 and 85 m can then be undertaken. The 55 m limit corresponds to a depth where inputs of fresh water can occur. The 85 m limit is about 7 m above the bottom of the lake. Below this depth important inputs from the pore waters occur which are not taken into account by the present modeling. Concentrations of Rb, Fe, Ba and V can be accurately represented by polynomial functions of the Na concentration. The parameter u=th[P(z)] represents the concentrations of these 4 elements by polynomials :          NX(u) = Σ an * un          0The rate of dissolution-precipitation for each element as a function of depth can be derived.                                       NR = - λ [P'(z)] * ch-2[P(z)] Σ ann(n-1) * thn-2[P(z)]                                        0Rb concentrations are a linear function of the Na ones and therefore rubidium is not reactive. Fe concentrations can be related to sodium concentrations by a parabolic relationship. From this relationship, it can be derived that strong iron precipitation occurs in the 63 - 65 m depth layer. V concentrations are related to sodium ones by a 4th degree polynomial. It can be derived that V deposition occurs at depths of 63-65 m and at 70 m.Ba precipitates around 70 m depth. Mn concentrations are represented by [Mn]=a0 +a1 u + b1 exp[-(z-z°)2/z*2] and the derivation shows that Mn is strongly dissolved between 62.8 and 63 m and precipitated just above. These results are in good agreement with a previous study of particles fluxes derived from sediment trap analysis (Viollier et al, 1997).This study shows the complexity of this interface and more comprehensive studies including all major elements, dissolved organic carbon (DOC) and pH are needed

A highly parallel Turbo Product Code decoder without interleaving resource

International audienceThis article presents an innovative turbo product code (TPC) decoder architecture without any interleaving resource. This architecture includes a full-parallel SISO decoder able to process n symbols in one clock period. Syntheses show the better efficiency of such an architecture compared with existing previous solutions. Considering a 6-iteration turbo decoder of a (32,26)2 BCH product code, synthetized in a 90 nm CMOS technology, the resulting information throughput is 2.5 Gb/s with an area of 233 Kgates. Finally a second architecture enhancing parallelism rate is described. The information throughput is 33.7 Gb/s while an area estimation gives A=10 mum2

On Theoretical Uncertainties of the W Angular Distribution in W-Pair Production at LEP2 Energies

We discuss theoretical uncertainties of the distribution in the cosine of the W polar angle projected into a measurement of the anomalous triple gauge-boson coupling \lambda=\lambda_{\gamma}=\lambda_Z at LEP2 energies for the tandem of the Monte Carlo event generators KoralW and YFSWW3 and for the Monte Carlo event generator RacoonWW. Exploiting numerical results of these programs and cross-checks with experimental fitting procedures, we estimate that the theoretical uncertainty of the value of \lambda due to electroweak corrections, as obtained at LEP2 with the help of these programs, is ~0.005, about half of the expected experimental error for the combined LEP2 experiments (~0.010). We use certain idealized event selections; however, we argue that these results are valid for realistic LEP2 measurements.Comment: 14 pages, 3 Postscript figure

ATLAS Distributed Data management Operations

ATLAS Distributed Data Management (DDM) service is developed for data transfer between ATLAS sites and for data cataloguing. The Data Management Software (SW) is based on DQ2 and end-users tools (aka dq2_get package). In this paper we address the issue of DDM day-by-day operation, DDM operations team organization, roles and responsibilities of Tier-1s and Tier-2s DDM coordinators

Delayed diagnosis of cystic fibrosis associated with R117H on a background of 7T polythymidine tract at intron 8

AbstractWe report late diagnoses of cystic fibrosis (CF) in two men aged 61 and 65 years. At the time of presentation, both patients had significant pulmonary disease. In each case two CFTR gene mutations were identified, including R117H on a background of a poly T genotype of 7T/9T. Patients with two identified CFTR mutations which include the R117H/7T anomaly should be followed up routinely as they remain susceptible to severe lung disease

Les turbo-codes à roulettes

é - Le problème majeur dans l'implémentation matérielle d'un turbo-décodeur réside dans le manque de parallélisme des algorithmes de décodage MAP. Cet article propose un nouveau procédé de turbo-codage basé sur deux idées: le codage de chaque dimension par P codes convolutifs récursifs circulaires indépendants et des contraintes sur la structure de l'entrelaceur qui permet de décoder en parallèle les P codes convolutifs dans chaque dimension. La construction des codes constituants et de l'entrelaceur est décrite et analysée. Un haut degré de parallélisme est obtenu avec des performances équivalentes ou meilleures que les meilleurs turbo-codes connus. L'architecture parallèle du décodeur permet de réduire la complexité du turbo-décodeur pour des applications à très hauts débits

A topological Dirac insulator in a quantum spin Hall phase : Experimental observation of first strong topological insulator

When electrons are subject to a large external magnetic field, the conventional charge quantum Hall effect \cite{Klitzing,Tsui} dictates that an electronic excitation gap is generated in the sample bulk, but metallic conduction is permitted at the boundary. Recent theoretical models suggest that certain bulk insulators with large spin-orbit interactions may also naturally support conducting topological boundary states in the extreme quantum limit, which opens up the possibility for studying unusual quantum Hall-like phenomena in zero external magnetic field. Bulk Bi$_{1-x}$Sb$_x$ single crystals are expected to be prime candidates for one such unusual Hall phase of matter known as the topological insulator. The hallmark of a topological insulator is the existence of metallic surface states that are higher dimensional analogues of the edge states that characterize a spin Hall insulator. In addition to its interesting boundary states, the bulk of Bi$_{1-x}$Sb$_x$ is predicted to exhibit three-dimensional Dirac particles, another topic of heightened current interest. Here, using incident-photon-energy-modulated (IPEM-ARPES), we report the first direct observation of massive Dirac particles in the bulk of Bi$_{0.9}$Sb$_{0.1}$, locate the Kramers' points at the sample's boundary and provide a comprehensive mapping of the topological Dirac insulator's gapless surface modes. These findings taken together suggest that the observed surface state on the boundary of the bulk insulator is a realization of the much sought exotic "topological metal". They also suggest that this material has potential application in developing next-generation quantum computing devices.Comment: 16 pages, 3 Figures. Submitted to NATURE on 25th November(2007

Breakdown of Conformal Invariance at Strongly Random Critical Points

We consider the breakdown of conformal and scale invariance in random systems with strongly random critical points. Extending previous results on one-dimensional systems, we provide an example of a three-dimensional system which has a strongly random critical point. The average correlation functions of this system demonstrate a breakdown of conformal invariance, while the typical correlation functions demonstrate a breakdown of scale invariance. The breakdown of conformal invariance is due to the vanishing of the correlation functions at the infinite disorder fixed point, causing the critical correlation functions to be controlled by a dangerously irrelevant operator describing the approach to the fixed point. We relate the computation of average correlation functions to a problem of persistence in the RG flow.Comment: 9 page

Relationship Between Serum NMDA Receptor Antibodies and Response to Antipsychotic Treatment in First-Episode Psychosis

Background: When psychosis develops in NMDA receptor (NMDAR) antibody encephalitis, it usually has an acute or subacute onset, and antipsychotic treatment may be ineffective and associated with adverse effects. Serum NMDAR antibodies have been reported in a minority of patients with first-episode psychosis (FEP), but their role in psychosis onset and response to antipsychotic treatment is unclear. Methods: Sera from 387 patients with FEP (duration of psychosis <2 years, minimally or never treated with antipsychotics) undergoing initial treatment with amisulpride as part of the OPTiMiSE (Optimization of Treatment and Management of Schizophrenia in Europe) trial (ClinicalTrials.gov number NCT01248195) were tested for NMDAR IgG antibodies using a live cell–based assay. Symptom severity was assessed using the Positive and Negative Syndrome Scale and the Clinical Global Impressions Scale at baseline and again after 4 weeks of treatment with amisulpride. Results: At baseline, 15 patients were seropositive for NMDAR antibodies and 372 were seronegative. The seropositive patients had similar symptom profiles and demographic features to seronegative patients but a shorter duration of psychosis (median 1.5 vs. 4.0 months; p =.031). Eleven seropositive and 284 seronegative patients completed 4 weeks of amisulpride treatment: after treatment, there was no between-groups difference in improvement in Positive and Negative Syndrome Scale scores or in the frequency of adverse medication effects. Conclusions: These data suggest that in FEP, NMDAR antibody seropositivity alone is not an indication for using immunotherapy instead of antipsychotic medications. Further studies are required to establish what proportion of patients with FEP who are NMDAR antibody seropositive have coexisting cerebrospinal fluid inflammatory changes or other paraclinical evidence suggestive of a likely benefit from immunotherapy

Hadron Energy Reconstruction for the ATLAS Calorimetry in the Framework of the Non-parametrical Method

This paper discusses hadron energy reconstruction for the ATLAS barrel prototype combined calorimeter (consisting of a lead-liquid argon electromagnetic part and an iron-scintillator hadronic part) in the framework of the non-parametrical method. The non-parametrical method utilizes only the known $e/h$ ratios and the electron calibration constants and does not require the determination of any parameters by a minimization technique. Thus, this technique lends itself to an easy use in a first level trigger. The reconstructed mean values of the hadron energies are within $\pm 1$ of the true values and the fractional energy resolution is $[(58\pm3)/\sqrt{E}+(2.5\pm0.3)$. The value of the $e/h$ ratio obtained for the electromagnetic compartment of the combined calorimeter is $1.74\pm0.04$ and agrees with the prediction that $e/h > 1.7$ for this electromagnetic calorimeter. Results of a study of the longitudinal hadronic shower development are also presented. The data have been taken in the H8 beam line of the CERN SPS using pions of energies from 10 to 300 GeV.Comment: 33 pages, 13 figures, Will be published in NIM