405 research outputs found
Importance of Vanadium-Catalyzed Oxidation of SO2 to SO3 in Two-Stroke Marine Diesel Engines
Low-speed marine diesel engines are mostly operated on heavy fuel oils, which have a high content of sulfur and ash, including trace amounts of vanadium, nickel, and aluminum. In particular, vanadium oxides could catalyze in-cylinder oxidation of SO2 to SO3, promoting the formation of sulfuric acid and enhancing problems of corrosion. In the present work, the kinetics of the catalyzed oxidation was studied in a fixed-bed reactor at atmospheric pressure. Vanadium oxide nanoparticles were synthesized by spray flame pyrolysis, i.e., by a mechanism similar to the mechanism leading to the formation of the catalytic species within the engine. Experiments with different particle compositions (vanadium/sodium ratio) and temperatures (300–800 °C) show that both the temperature and sodium content have a major impact on the oxidation rate. Kinetic parameters for the catalyzed reaction are determined, and the proposed kinetic model fits well with the experimental data. The impact of the catalytic reaction is studied with a phenomenological zero-dimensional (0D) engine model, where fuel oxidation and SOx formation is modeled with a comprehensive gas-phase reaction mechanism. Results indicate that the oxidation of SO2 to SO3 in the cylinder is dominated by gas-phase reactions and that the vanadium-catalyzed reaction is at most a very minor pathway
Modeling approach to regime shifts of primary production in shallow coastal ecosystems
Pristine coastal shallow systems are usually dominated by extensive meadows
of seagrass species, which are assumed to take advantage of nutrient supply
from sediment. An increasing nutrient input is thought to favour phytoplankton,
epiphytic microalgae, as well as opportunistic ephemeral macroalgae that
coexist with seagrasses. The primary cause of shifts and succession in the
macrophyte community is the increase of nutrient load to water; however
temperature plays also an important role. A competition model between rooted
seagrass (Zostera marina), macroalgae (Ulva sp), and phytoplankton has been
developed to analyse the succession of primary producer communities in these
systems. Successions of dominance states, with different resilience
characteristics, are found when modifying the input of nutrients and the
seasonal temperature and light intensity forcing.Comment: 33 pages, including 10 figures. To appear in Ecological Complexit
Precision Primordial He Measurement with CMB Experiments
Big bang nucleosynthesis (BBN) and the cosmic microwave background (CMB) are
two major pillars of cosmology. Standard BBN accurately predicts the primordial
light element abundances (He, D, He and Li), depending on one
parameter, the baryon density. Light element observations are used as a
baryometers. The CMB anisotropies also contain information about the content of
the universe which allows an important consistency check on the Big Bang model.
In addition CMB observations now have sufficient accuracy to not only determine
the total baryon density, but also resolve its principal constituents, H and
He. We present a global analysis of all recent CMB data, with special
emphasis on the concordance with BBN theory and light element observations. We
find and
(fraction of baryon mass as He) using CMB data alone, in agreement with
He abundance observations. With this concordance established we show that
the inclusion of BBN theory priors significantly reduces the volume of
parameter space. In this case, we find
and . We also find that the inclusion of deuterium
abundance observations reduces the and ranges by a factor
of 2. Further light element observations and CMB anisotropy experiments
will refine this concordance and sharpen BBN and the CMB as tools for precision
cosmology.Comment: 7 pages, 3 color figures made minor changes to bring inline with
journal versio
Quasicondensate and superfluid fraction in the 2D charged-boson gas at finite temperature
The Bogoliubov - de Gennes equations are solved for the Coulomb Bose gas
describing a fluid of charged bosons at finite temperature. The approach is
applicable in the weak coupling regime and the extent of its quantitative
usefulness is tested in the three-dimensional fluid, for which diffusion Monte
Carlo data are available on the condensate fraction at zero temperature. The
one-body density matrix is then evaluated by the same approach for the
two-dimensional fluid with e^2/r interactions, to demonstrate the presence of a
quasi-condensate from its power-law decay with increasing distance and to
evaluate the superfluid fraction as a function of temperature at weak coupling.Comment: 9 pages, 2 figure
Isospin Asymmetry in Nuclei and Neutron Stars
The roles of isospin asymmetry in nuclei and neutron stars are investigated
using a range of potential and field-theoretical models of nucleonic matter.
The parameters of these models are fixed by fitting the properties of
homogeneous bulk matter and closed-shell nuclei. We discuss and unravel the
causes of correlations among the neutron skin thickness in heavy nuclei, the
pressure of beta-equilibrated matter at a density of 0.1 fm, the
derivative of the nuclear symmetry energy at the same density and the radii of
moderate mass neutron stars. Constraints on the symmetry properties of nuclear
matter from the binding energies of nuclei are examined. The extent to which
forthcoming neutron skin measurements will further delimit the symmetry
properties is investigated. The impact of symmetry energy constraints for the
mass and moment of inertia contained within neutron star crusts and the
threshold density for the nucleon direct Urca process, all of which are
potentially measurable, is explored. We also comment on the minimum neutron
star radius, assuming that only nucleonic matter exists within the star.Comment: 49 pages, 17 figures, Phys. Rep. (in press); made improvements to
"RAPR" and corrected transition densitie
Bifurcation treatment with novel, highly flexible drug-eluting coronary stents in all-comers: 2-year outcome in patients of the DUTCH PEERS trial
Background: Percutaneous coronary intervention (PCI) in bifurcated lesions with second-generation drug-eluting stents (DES) was associated with increased myocardial infarction (MI) rates. Flexible stent designs that accommodate well to vessel tapering may be of benefit in challenging anatomies such as bifurcated target lesions, but so far data are scarce.Methods: We analyzed the 2-year follow-up data of the DUTCH PEERS (TWENTE II) trial, which randomized 1811 all-comer patients to PCI with newer generation resolute integrity zotarolimus-eluting (Medtronic) or promus element everolimus-eluting stents (Boston Scientific). In bifurcated lesions, provisional stenting was generally performed. Target vessel failure is a composite endpoint, consisting of cardiac death, target vessel MI, or target vessel revascularization.Results: Patients with at least one bifurcated lesion (n = 465, 25.7 %) versus patients with non-bifurcated target lesions only (n = 1346, 74.3 %) showed similar rates of clinical endpoints including target vessel failure (9.2 versus 7.9 %, p = 0.36) and definite stent thrombosis (0.4 versus 1.0 %, p = 0.38). Target vessel MI was more common in patients with bifurcated lesions (3.4 versus 1.6 %, p = 0.02); but after multivariate analysis with propensity score adjustment, bifurcation treatment was found not to be an independent predictor of target vessel MI (HR 1.40, 95 % CI 0.71–2.76; p = 0.34). Among patients with bifurcated lesions, DES type and side-branch size did not affect outcome, but periprocedural MI occurred more often after two-stent approaches (9.0 versus 2.1 %; p = 0.002).Conclusion: All-comer patients treated for bifurcated and non-bifurcated target lesions showed similar and low rates of clinical endpoints, suggesting that the DES used are efficacious and safe for treating bifurcated target lesions
Hopf algebras and Markov chains: Two examples and a theory
The operation of squaring (coproduct followed by product) in a combinatorial
Hopf algebra is shown to induce a Markov chain in natural bases. Chains
constructed in this way include widely studied methods of card shuffling, a
natural "rock-breaking" process, and Markov chains on simplicial complexes.
Many of these chains can be explictly diagonalized using the primitive elements
of the algebra and the combinatorics of the free Lie algebra. For card
shuffling, this gives an explicit description of the eigenvectors. For
rock-breaking, an explicit description of the quasi-stationary distribution and
sharp rates to absorption follow.Comment: 51 pages, 17 figures. (Typographical errors corrected. Further fixes
will only appear on the version on Amy Pang's website, the arXiv version will
not be updated.
Observation of hard scattering in photoproduction events with a large rapidity gap at HERA
Events with a large rapidity gap and total transverse energy greater than 5
GeV have been observed in quasi-real photoproduction at HERA with the ZEUS
detector. The distribution of these events as a function of the
centre of mass energy is consistent with diffractive scattering. For total
transverse energies above 12 GeV, the hadronic final states show predominantly
a two-jet structure with each jet having a transverse energy greater than 4
GeV. For the two-jet events, little energy flow is found outside the jets. This
observation is consistent with the hard scattering of a quasi-real photon with
a colourless object in the proton.Comment: 19 pages, latex, 4 figures appended as uuencoded fil
Have Superheavy Elements been Produced in Nature?
We discuss the possibility whether superheavy elements can be produced in
Nature by the astrophysical rapid neutron capture process. To this end we have
performed fully dynamical network r-process calculations assuming an
environment with neutron-to-seed ratio large enough to produce superheavy
nuclei. Our calculations include two sets of nuclear masses and fission
barriers and include all possible fission channels and the associated fission
yield distributions. Our calculations produce superheavy nuclei with A ~ 300
that however decay on timescales of days.Comment: 12 pages, 11 figure
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