Interplay of gas and ice during cloud evolution

During the evolution of diffuse clouds to molecular clouds, gas-phase molecules freeze out on surfaces of small dust particles to form ices. On dust surfaces, water is the main constituent of the icy mantle in which a complex chemistry is taking place. We aim to study the formation pathways and the composition of the ices throughout the evolution of diffuse clouds. For this purpose, we use time-dependent rate equations to calculate the molecular abundances in both gas phase and on solid surfaces (onto dust grains). We fully consider the gas-dust interplay by including the details of freeze-out, chemical and thermal desorption, as well as the most important photo-processes on grain surfaces. The difference in binding energies of chemical species on bare and icy surfaces is also incorporated into our equations. Using the numerical code FLASH, we perform a hydrodynamical simulation of a gravitationally bound diffuse cloud and follow its contraction. We find that while the dust grains are still bare, water formation is enhanced by grain surface chemistry which is subsequently released into the gas phase, enriching the molecular medium. The CO molecules, on the other hand, tend to freeze out gradually on bare grains. This causes CO to be well mixed and strongly present within the first ice layer. Once one monolayer of water ice has formed, the binding energy of the grain surface changes significantly and an immediate and strong depletion of gas-phase water and CO molecules occur. While hydrogenation converts solid CO into formaldehyde (H$_2$CO) and methanol (CH$_3$OH), water ice becomes the main constituent of the icy grains. Inside molecular clumps formaldehyde is more abundant than water and methanol in the gas phase owing its presence in part to chemical desorption.Comment: 19 pages, 10 figures, 9 tables, 23 equations. Accepted for publication Astronomy & Astrophysics. In version 3: Language edit, added gas-phase reaction tables, title has change

Star formation near an obscured AGN: Variations in the initial mass function

The conditions that affect the formation of stars in radiatively and mechanically active environments are quite different than the conditions that apply to our local interstellar neighborhood. In such galactic environments, a variety of feedback processes can play a significant role in shaping the initial mass function (IMF). Here, we present a numerical study on the effects of an accreting black hole and the influence of nearby massive stars to a collapsing, 800 M_sun, molecular cloud at 10 pc distance from the black hole. We parametrize and study radiative feedback effects of hard X-rays emanating from the black hole broad line region, increased cosmic ray rates due to supernovae in starbursts, and strong UV radiation produced by nearby massive stars. We also investigate the importance of shear from the supermassive, 10^6-10^8 M_sun, black hole as the star-forming cloud orbits around it. We find that thermal pressure from X-rays compresses the cloud, which induces a high star formation rate early on, but reduces the overall star formation efficiency to about 7% due to gas depletion by evaporation. We see that the turn-over mass of the IMF increases up to a factor of 2.3, M_turn = 1-1.5 M_sun, for the model with the highest X-ray flux (160 erg s^-1 cm^-2), while the high-mass slope of the IMF becomes Gamma > -1. This results in more high mass stars and a non-Salpeter IMF. Cosmic rays penetrate deeply into the cloud and increase the gas temperature (50-200 K), which leads to a reduced formation efficiency of low mass stars. High cosmic ray rates increase the average mass of stars, thereby shifting the turn-over mass to higher values, i.e., up to several solar masses. Due to this process, the onset of star formation is also delayed. We conclude that the IMF inside active galaxies is different than the one obtained from local environments.Comment: 25 pages, 17 figure

The impact of freeze-out on collapsing molecular clouds

Atoms and molecules, and in particular CO, are important coolants during the evolution of interstellar star-forming gas clouds. The presence of dust grains, which allow many chemical reactions to occur on their surfaces, strongly impacts the chemical composition of a cloud. At low temperatures, dust grains can lock-up species from the gas phase which freeze out and form ices. In this sense, dust can deplete important coolants. Our aim is to understand the effects of freeze-out on the thermal balance and the evolution of a gravitationally bound molecular cloud. For this purpose, we perform 3D hydrodynamical simulations with the adaptive mesh code FLASH. We simulate a gravitationally unstable cloud under two different conditions, with and without grain surface chemistry. We let the cloud evolve until one free-fall time is reached and track the thermal evolution and the abundances of species during this time. We see that at a number density of 10$^4$ cm$^{-3}$ most of the CO molecules are frozen on dust grains in the run with grain surface chemistry, thereby depriving the most important coolant. As a consequence, we find that the temperature of the gas rises up to $\sim$25 K. The temperature drops once again due to gas-grain collisional cooling when the density reaches a few$\times$10$^4$ cm$^{-3}$. We conclude that grain surface chemistry not only affects the chemical abundances in the gas phase, but also leaves a distinct imprint in the thermal evolution that impacts the fragmentation of a star-forming cloud. As a final step, we present the equation of state of a collapsing molecular cloud that has grain surface chemistry included.Comment: Increased the number of significant digits in EQ 2. It mattered. Accepted for publication in MNRAS letter

Dust as interstellar catalyst I. Quantifying the chemical desorption process

Context. The presence of dust in the interstellar medium has profound consequences on the chemical composition of regions where stars are forming. Recent observations show that many species formed onto dust are populating the gas phase, especially in cold environments where UV and CR induced photons do not account for such processes. Aims. The aim of this paper is to understand and quantify the process that releases solid species into the gas phase, the so-called chemical desorption process, so that an explicit formula can be derived that can be included into astrochemical models. Methods. We present a collection of experimental results of more than 10 reactive systems. For each reaction, different substrates such as oxidized graphite and compact amorphous water ice are used. We derive a formula to reproduce the efficiencies of the chemical desorption process, which considers the equipartition of the energy of newly formed products, followed by classical bounce on the surface. In part II we extend these results to astrophysical conditions. Results. The equipartition of energy describes correctly the chemical desorption process on bare surfaces. On icy surfaces, the chemical desorption process is much less efficient and a better description of the interaction with the surface is still needed. Conclusions. We show that the mechanism that directly transforms solid species to gas phase species is efficient for many reactions.Comment: Accepted for publication in A&

Chemical fractionation of deuterium in the protosolar nebula

Understanding gas-grain chemistry of deuterium in star-forming objects may help to explain their history and present state. We aim to clarify how processes in ices affect the deuterium fractionation. In this regard, we investigate a Solar-mass protostellar envelope using an astrochemical rate-equation model that considers bulk-ice chem- istry. The results show a general agreement with the molecular D/H abundance ratios observed in low-mass protostars. The simultaneous processes of ice accumulation and rapid synthesis of HD on grain surfaces in the prestellar core hampers the deuteration of icy species. The observed very high D/H ratios exceeding 10 per cent, i.e., super- deuteration, are reproduced for formaldehyde and dimethyl ether, but not for other species in the protostellar envelope phase. Chemical transformations in bulk ice lower D/H ratios of icy species and do not help explaining the super-deuteration. In the protostellar phase, the D2O/HDO abundance ratio was calculated to be higher than the HDO/H2O ratio owing to gas-phase chemistry. Species that undergo evaporation from ices have high molecular D/H ratio and a high gas-phase abundance.Comment: 11 pages, 4 tables, 6 figures; +3 figures in appendix. Accepted for publication in MNRA

The asymmetric radio structure and record jet of giant quasar 4C 34.47

Giant double-lobed radio source 4C34.47 displays a straight one-sided jet, measuring a record length of 380kpc, in its double-lobed radio structure. Assuming an intrinsically symmetric two-sided jet structure the radio source jet axis must be at least 33 degrees away from the sky plane, that is within 57 degrees from the line of sight. The radio polarization properties indicate that this giant source has largely outgrown the depolarizing halo generally associated with the host galaxies of powerful radio sources. The measured small depolarization asymmetry is nevertheless in accordance with its inferred orientation. All data for this giant radio source are in agreement with its preferred orientation as predicted within the unification scheme for powerful radio sources. Seen under a small aspect angle the radio source is large but not excessively large. The global properties of 4C34.47 do not differ from other giant (old) FR2 radio sources: it is a slowly expanding low-luminosity radio source.Comment: Accepted for publication in Astronomy and Astrophysic

Parameterizing the interstellar dust temperature

The temperature of interstellar dust particles is of great importance to astronomers. It plays a crucial role in the thermodynamics of interstellar clouds, because of the gas-dust collisional coupling. It is also a key parameter in astrochemical studies that governs the rate at which molecules form on dust. In 3D (magneto)hydrodynamic simulations often a simple expression for the dust temperature is adopted, because of computational constraints, while astrochemical modelers tend to keep the dust temperature constant over a large range of parameter space. Our aim is to provide an easy-to-use parametric expression for the dust temperature as a function of visual extinction ($A_{\rm V}$) and to shed light on the critical dependencies of the dust temperature on the grain composition. We obtain an expression for the dust temperature by semi-analytically solving the dust thermal balance for different types of grains and compare to a collection of recent observational measurements. We also explore the effect of ices on the dust temperature. Our results show that a mixed carbonaceous-silicate type dust with a high carbon volume fraction matches the observations best. We find that ice formation allows the dust to be warmer by up to 15% at high optical depths ($A_{\rm V}> 20$ mag) in the interstellar medium. Our parametric expression for the dust temperature is presented as $T_{\rm d} = \left[ 11 + 5.7\times \tanh\bigl( 0.61 - \log_{10}(A_{\rm V})\bigr) \right] \, \chi_{\rm uv}^{1/5.9}$, where $\chi_{\rm uv}$ is in units of the Draine (1978) UV fieldComment: 16 pages, 17 figures, 4 tables. Accepted for publication in A&A. Version 2: the omission of factor 0.921 in equation 4 is correcte

The impact of X-rays on molecular cloud fragmentation and the IMF

Star formation is regulated through a variety of feedback processes. In this study, we treat feedback by X-rays and discuss its implications. Our aim is to investigate whether star formation is significantly affected when a star forming cloud resides in the vicinity of a strong X-ray source. We perform an Eulerian grid simulation with embedded Lagrangian sink particles of a collapsing molecular cloud near a massive, 10^7 M_o black hole. The chemical and thermal changes caused by radiation are incorporated into the FLASH code. When there is strong X-ray feedback the star forming cloud fragments into larger clumps whereby fewer but more massive protostellar cores are formed. Competitive accretion has a strong impact on the mass function and a near-flat, non-Salpeter IMF results.Comment: 6 pages, 4 figures. Accepted for publication in Astronomy and Astrophysic

Warm dust surface chemistry in protoplanetary disks : formation of phyllosilicates

Funding: Dr. Thomas Müller, and Dr. Victor Ali-Lagoa. IK,WFT, CR, and PW acknowledge fundingfrom the EU FP7- 2011 under Grant Agreement nr. 284405. CR also acknowl-edges funding by the Austrian Science Fund (FWF), project number P24790.Context. The origin of the reservoirs of water on Earth is debated. The Earth’s crust may contain at least three times more water than the oceans. This crust water is found in the form of phyllosilicates, whose origin probably differs from that of the oceans. Aims. We test the possibility to form phyllosilicates in protoplanetary disks, which can be the building blocks of terrestrial planets. Methods. We developed an exploratory rate-based warm surface chemistry model where water from the gas-phase can chemisorb on dust grain surfaces and subsequently diffuse into the silicate cores. We applied the phyllosilicate formation to a zero-dimensional chemical model and to a 2D protoplanetary disk model (PRODIMO). The disk model includes in addition to the cold and warm surface chemistry continuum and line radiative transfer, photoprocesses (photodissociation, photoionisation, and photodesorption), gas-phase cold and warm chemistry including three-body reactions, and detailed thermal balance. Results. Despite the high energy barrier for water chemisorption on silicate grain surfaces and for diffusion into the core, the chemisorption sites at the surfaces can be occupied by a hydroxyl bond (–OH) at all gas and dust temperatures from 80 to 700 K for a gas density of 2 × 104 cm−3. The chemisorption sites in the silicate cores are occupied at temperatures between 250 and 700 K. At higher temperatures thermal desorption of chemisorbed water occurs. The occupation efficiency is only limited by the maximum water uptake of the silicate. The timescales for complete hydration are at most 105 yr for 1 mm radius grains at a gas density of 108 cm−3. Conclusions. Phyllosilicates can be formed on dust grains at the dust coagulation stage in protoplanetary disks within 1 Myr. It is however not clear whether the amount of phyllosilicate formed by warm surface chemistry is sufficient compared to that found in Solar System objects.PostprintPeer reviewe