Spread of retailer food quality standards: an international perspective

Privately initiated food quality standards are currently important elements in the marketing of food and agricultural products. At the same time, they stand in the centre of a discussion about potential negative effects on small farmers and farmers in developing countries. This study aims at analysing the adoption of two private food standards, BRC Technical Food Standard and GlobalGAP, at an aggregated crosscountry level. The results of the econometric analysis reveal some (potential) barriers for developing countries to access this type of organisational innovation. Certificates seem to be issued more probably in larger and wealthier countries, countries with a better institutional quality, better infrastructural conditions and in former UK colonies

Jizz and the joy of pattern recognition:virtuosity, discipline and the agency of insight in UK naturalists’ arts of seeing

Approaches to visual skilling from anthropology and STS have tended to highlight the forces of discipline and control in understanding how shared visual accounts of the world are created in the face of potential differences brought about by multi-sensorial perception. Drawing upon a range of observational and interview material from an immersion in naturalist training and biological recording activities between 2003 and 2009, I focus upon jizz, a distinct form of gestalt perception much coveted by naturalist communities in the UK. Jizz is described as a tacit and embodied way of seeing that instantaneously reveals the identity of a species, relying upon but simultaneously suspending the arduous and meticulous study of an organism’s diagnostic characteristics. I explore the potential and limitations of jizz to allow for both visual precision and an enchanted and varied form of encounter with nature. In so doing, I explore how the specific characteristics of wild, intangible and irreverent virtuoso performance work closely together with disciplining taxonomic standards. As such, discipline and irreverence work together, are mutually enabling, and allow for an accommodation rather than a segregation of potential difference brought about by perceptual variety

Geostatistical and statistical classification of sea-ice properties and provinces from SAR data

Recent drastic reductions in the Arctic sea-ice cover have raised an interest in understanding the role of sea ice in the global system as well as pointed out a need to understand the physical processes that lead to such changes. Satellite remote-sensing data provide important information about remote ice areas, and Synthetic Aperture Radar (SAR) data have the advantages of penetration of the omnipresent cloud cover and of high spatial resolution. A challenge addressed in this paper is how to extract information on sea-ice types and sea-ice processes from SAR data. We introduce, validate and apply geostatistical and statistical approaches to automated classification of sea ice from SAR data, to be used as individual tools for mapping sea-ice properties and provinces or in combination. A key concept of the geostatistical classification method is the analysis of spatial surface structures and their anisotropies, more generally, of spatial surface roughness, at variable, intermediate-sized scales. The geostatistical approach utilizes vario parameters extracted from directional vario functions, the parameters can be mapped or combined into feature vectors for classification. The method is flexible with respect to window sizes and parameter types and detects anisotropies. In two applications to RADARSAT and ERS-2 SAR data from the area near Point Barrow, Alaska, it is demonstrated that vario-parameter maps may be utilized to distinguish regions of different sea-ice characteristics in the Beaufort Sea, the Chukchi Sea and in Elson Lagoon. In a third and a fourth case study the analysis is taken further by utilizing multi-parameter feature vectors as inputs for unsupervised and supervised statistical classification. Field measurements and high-resolution aerial observations serve as basis for validation of the geostatistical-statistical classification methods. A combination of supervised classification and vario-parameter mapping yields best results, correctly identifying several sea-ice provinces in the shore-fast ice and the pack ice. Notably, sea ice does not have to be static to be classifiable with respect to spatial structures. In consequence, the geostatistical-statistical classification may be applied to detect changes in ice dynamics, kinematics or environmental changes, such as increased melt ponding, increased snowfall or changes in the equilibrium line

Selectively dispersed isotope labeling for protein structure determination by magic angle spinning NMR

The power of nuclear magnetic resonance spectroscopy derives from its site-specific access to chemical, structural and dynamic information. However, the corresponding multiplicity of interactions can be difficult to tease apart. Complimentary approaches involve spectral editing on the one hand and selective isotope substitution on the other. Here we present a new “redox” approach to the latter: acetate is chosen as the sole carbon source for the extreme oxidation numbers of its two carbons. Consistent with conventional anabolic pathways for the amino acids, [1-[superscript 13]C] acetate does not label α carbons, labels other aliphatic carbons and the aromatic carbons very selectively, and labels the carboxyl carbons heavily. The benefits of this labeling scheme are exemplified by magic angle spinning spectra of microcrystalline immunoglobulin binding protein G (GB1): the elimination of most J-couplings and one- and two-bond dipolar couplings provides narrow signals and long-range, intra- and inter-residue, recoupling essential for distance constraints. Inverse redox labeling, from [2-[superscript 13]C] acetate, is also expected to be useful: although it retains one-bond couplings in the sidechains, the removal of CA–CO coupling in the backbone should improve the resolution of NCACX spectra.National Institutes of Health. National Institute for Biomedical Imaging and Bioengineering (Grant EB-001035)National Institutes of Health. National Institute for Biomedical Imaging and Bioengineering (Grant EB-001960)National Institutes of Health. National Institute for Biomedical Imaging and Bioengineering (Grant EB-002026

Solid state NMR and X-ray diffraction studies of α-d-galacturonic acid monohydrate

Crystalline a-d-galacturonic acid monohydrate has been studied by 13C CPMAS NMR and X-ray crystallography. The molecular dynamics were investigated by evaluating 13C spin-lattice relaxation in the rotating frame (T1?) and chemical-shift-anisotropy properties of each carbon. Only limited molecular motions can be detected in the low frequency

An Algorithm for Detection of Ground and Canopy Cover in Micropulse Photon-Counting Lidar Altimeter Data in Preparation of the ICESat-2 Mission

The Ice, Cloud and Land Elevation Satellite-II (ICESat-2) mission has been selected by NASA as a Decadal Survey mission, to be launched in 2016. Mission objectives are to measure land ice elevation, sea ice freeboard/ thickness and changes in these variables and to collect measurements over vegetation that will facilitate determination of canopy height, with an accuracy that will allow prediction of future environmental changes and estimation of sea-level rise. The importance of the ICESat-2 project in estimation of biomass and carbon levels has increased substantially, following the recent cancellation of all other planned NASA missions with vegetation-surveying lidars. Two innovative components will characterize the ICESat-2 lidar: (1) Collection of elevation data by a multi-beam system and (2) application of micropulse lidar (photon counting) technology. A micropulse photon-counting altimeter yields clouds of discrete points, which result from returns of individual photons, and hence new data analysis techniques are required for elevation determination and association of returned points to reflectors of interest including canopy and ground in forested areas. The objective of this paper is to derive and validate an algorithm that allows detection of ground under dense canopy and identification of ground and canopy levels in simulated ICESat-2-type data. Data are based on airborne observations with a Sigma Space micropulse lidar and vary with respect to signal strength, noise levels, photon sampling options and other properties. A mathematical algorithm is developed, using spatial statistical and discrete mathematical concepts, including radial basis functions, density measures, geometrical anisotropy, eigenvectors and geostatistical classification parameters and hyperparameters. Validation shows that the algorithm works very well and that ground and canopy elevation, and hence canopy height, can be expected to be observable with a high accuracy during the ICESat-2 mission. A result relevant for instrument design is that even the two weaker beam classes considered can be expected to yield useful results for vegetation measurements (93.01-99.57% correctly selected points for a beam with expected return of 0.93 mean signals per shot (msp9) and 72.85% - 98.68% for 0.48 msp (msp4)). Resampling options affect results more than noise levels. The algorithm derived here is generally applicable for analysis of micropulse lidar altimeter data collected over forested areas as well as other surfaces, including land ice, sea ice and land surfaces

The trough-system algorithm and its application to spatial modeling of Greenland subglacial topography

This is the published version. Copyright 2014 Herzfeld et al.Dynamic ice-sheet models are used to assess the contribution of mass loss from the Greenland ice sheet to sea-level rise. Mass transfer from ice sheet to ocean is in a large part through outlet glaciers. Bed topography plays an important role in ice dynamics, since the acceleration from the slow-moving inland ice to an ice stream is in many cases caused by the existence of a subglacial trough or trough system. Problems are that most subglacial troughs are features of a scale not resolved in most ice-sheet models and that radar measurements of subglacial topography do not always reach the bottoms of narrow troughs. The trough-system algorithm introduced here employs mathematical morphology and algebraic topology to correctly represent subscale features in a topographic generalization, so the effects of troughs on ice flow are retained in ice-dynamic models. The algorithm is applied to derive a spatial elevation model of Greenland subglacial topography, integrating recently collected radar measurements (CReSIS data) of the Jakobshavn Isbræ, Helheim, Kangerdlussuaq and Petermann glacier regions. The resultant JakHelKanPet digital elevation model has been applied in dynamic ice-sheet modeling and sea-level-rise assessment

Continuity, authority and the place of heritage in the Medieval world

Copyright © 2000 Elsevier. NOTICE: This is the author’s version of a work accepted for publication by Elsevier. Changes resulting from the publishing process, including corrections, structural formatting and other quality control mechanisms, may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Journal of Historical Geography, Vol 25 (1), 2000, pp. 47-59. DOI:10.1006/jhge.1999.0190This essay supports the contention that knowledge of the past should be seen as a political resource. Furthermore, the interpretation of a particular version of the past is related to power differentiation and the legitimisation of authority. The subjective use of the past is not a recent phenomenon and in this paper, the use of the past is related to the construction of identity and ecclesiastical organisation during the Medieval period. Bourdieu's notion of habitus is used as a way of grounding the rhetoric of legitimisation, with particular reference to ecclesiastical authority. Hagiographical accounts and legends correspond to discourses of power and are related to the (re)production of a religious identity that legitimated Church authority. The essay pays special attention to west Cornwall where such institutional power is related to an identity that is generated via contemporary notions of heritage and a particular sense of past

Continuously Tunable 250 GHz Gyrotron with a Double Disk Window for DNP-NMR Spectroscopy

In this paper, we describe the design and experimental results from the rebuild of a 250 GHz gyrotron used for Dynamic Nuclear Polarization enhanced Nuclear Magnetic Resonance spectroscopy on a 380 MHz spectrometer. Tuning bandwidth of approximately 2 GHz is easily achieved at a fixed magnetic field of 9.24 T and a beam current of 95 mA producing an average output power of >10 W over the entire tuning band. This tube incorporates a double disk output sapphire window in order to maximize the transmission at 250.58 GHz. DNP Signal enhancement of >125 is achieved on a [superscript 13]C-Urea sample using this gyrotron.National Institutes of Health (U.S.) (Grant EB002804)National Institutes of Health (U.S.) (Grant EB003151)National Institutes of Health (U.S.) (Grant EB002026)National Institutes of Health (U.S.) (Grant EB001960)National Institutes of Health (U.S.) (Grant EB001035)National Institutes of Health (U.S.) (Grant EB001965)National Institutes of Health (U.S.) (Grant EB004866

Statistical-mechanical theory of ultrasonic absorption in molecular liquids

We present results of theoretical description of ultrasonic phenomena in molecular liquids. In particular, we are interested in the development of microscopical, i.e., statistical-mechanical framework capable to explain the long living puzzle of the excess ultrasonic absorption in liquids. Typically, ultrasonic wave in a liquid can be generated by applying the periodically alternating external pressure with the angular frequency that corresponds to the ultrasound. If the perturbation introduced by such process is weak - its statistical-mechanical treatment can be done with the use of the linear response theory. We treat the liquid as a system of interacting sites, so that all the response/aftereffect functions as well as the energy dissipation and generalized (wave-vector and frequency dependent) ultrasonic absorption coefficient are obtained in terms of familiar site-site static and time correlation functions such as static structure factors or intermediate scattering functions. To express the site-site intermediate scattering functions we refer to the site-site memory equations in the mode-coupling approximation for the first-order memory kernels, while equilibrium properties such as site-site static structure factors, direct and total correlation functions are deduced from the integral equation theory of molecular liquids known as RISM or one of its generalizations. All the formalism is phrased in a general manner, hence the obtained results are expected to work for arbitrary type of molecular liquid including simple, ionic, polar, and non-polar liquids.Comment: 14 pages, 1 eps-figure, RevTeX4-forma