Investigation of mineral transformations and ash deposition during staged combustion. Quarterly technical progress report, January 1, 1996--March 31, 1996

Progress during the tenth quarter of a three-year study of ash formation and deposition was made in several areas. One of the key contributions this quarter was the development of an algorithm to distinguish between ash particles that are associated with char particles (included) and ash particles which are excluded. This algorithm was used to determine the extent to which pyrite transformations are influenced by whether the pyrite grains are included or excluded. The results indicate that pyrite oxidation is slower for included pyrite grains. Replicate experiments were also performed for the Pittsburgh No. 8 coal (washed) under both staged and conventional conditions. An objective of these experiments was to validate the effect of staged combustion on the size distribution of ash particles as reported for the previous quarter. Analysis of the new samples and repeat analyses of previous samples showed no significant difference in the ash particle size for samples collected at stoichiometric ratios of 0.75 (before the stage) and 1.04. The number of points in the new analyses was considerably higher than in previous analyses, resulting in greater confidence. The similarity in the ash composition for samples collected under staged and conventional conditions was also verified this quarter with replicate samples and analyses. The net result is that staged combustion does not appear to have a significant impact on either ash size or composition for the Pittsburgh No. 8 coal. Finally, numerical simulations of the temperature distribution in the laboratory combustor were performed and evaluated. Also, a paper documenting the classification algorithm developed last quarter was presented at the March ACS meeting in New Orleans and published in the ACS Division of Fuel Chemistry Preprints

Chandra and Suzaku observations of the Be/X-ray star HD110432

We present an analysis of a pointed 141 ks Chandra high resolution transmission gratings observation of the Be X-ray emitting star HD110432, a prominent member of the gamma Cas analogs. The Chandra lightcurve shows a high variability but its analysis fails to detect any coherent periodicity up to a frequency of 0.05 Hz. The analysis of the Chandra HETG spectrum shows that, to correctly describe the spectrum, three model components are needed. Two of those components are optically thin thermal plasmas of different temperatures (kT~8-9 and 0.2-0.3 keV respectively). Two different models seem to describe well the third component. One possibility is a third hot optically thin thermal plasma at kT=16-21 keV with an Fe abundance Z~0.3Zo, definitely smaller than for the other two thermal components. Alternatively, the third component can be described by a powerlaw with a photon index Gamma=1.56. In either case, the Chandra HETG spectrum establishes that each one of these components must be modified by distinct absorption columns. The analysis of a non contemporaneous 25 ks Suzaku observation shows the presence of a hard tail extending up to at least 33 keV. The Suzaku spectrum is described with the sum of two components: an optically thin thermal plasma at kT ~ 9 keV and a very hot second plasma with kT ~33 keV or, alternatively, a powerlaw with photon index Gamma=1.58. The analysis of the Si XIII and S XV He like triplets present in the Chandra spectrum point to a very dense (n_e ~ 10^13 cm^-3) plasma located either close to the stellar surface (r<3R_*) of the Be star or, alternatively, very close (r ~1.5R_WD) to the surface of a (hypothetical) WD companion. We argue, however, that the available data supports the first scenario.Comment: 13 pages, 21 Figures. Accepted for publication in Ap

Ring closing reaction in diarylethene captured by femtosecond electron crystallography

The photoinduced ring-closing reaction in diarylethene, which serves as a model system for understanding reactive crossings through conical intersections, was directly observed with atomic resolution using femtosecond electron diffraction. Complementary ab initio calculations were also performed. Immediately following photoexcitation, subpicosecond structural changes associated with the formation of an open-ring excited-state intermediate were resolved. The key motion is the rotation of the thiophene rings, which significantly decreases the distance between the reactive carbon atoms prior to ring closing. Subsequently, on the few picosecond time scale, localized torsional motions of the carbon atoms lead to the formation of the closed-ring photoproduct. These direct observations of the molecular motions driving an organic chemical reaction were only made possible through the development of an ultrabright electron source to capture the atomic motions within the limited number of sampling frames and the low data acquisition rate dictated by the intrinsically poor thermal conductivity and limited photoreversibility of organic materials

Does organizational formalization facilitate voice and helping organizational citizenship behaviors? It depends on (national) uncertainty norms

Prosocial work behaviors in a globalized environment do not operate in a cultural vacuum. We assess to what extent voice and helping organizational citizenship behaviors (OCBs) vary across cultures, depending on employees’ perceived level of organizational formalization and national uncertainty. We predict that in contexts of uncertainty, cognitive resources are engaged in coping with this uncertainty. Organizational formalization can provide structure that frees up cognitive resources to engage in OCB. In contrast, in contexts of low uncertainty, organizational formalization is not necessary for providing structure and may increase constraints on discretionary behavior. A three-level hierarchical linear modeling analysis of data from 7,537 employees in 267 organizations across 17 countries provides broad support for our hypothesis: perceived organizational formalization is weakly related to OCB, but where uncertainty is high; formalization facilitates voice significantly, helping OCB to a lesser extent. Our findings contribute to clarifying the dynamics between perceptions of norms at organizational and national levels for understanding when employees may engage in helping and voice behaviors. The key implication is that managers can foster OCB through organizational formalization interventions in uncertain environments that are cognitively demanding

New Studies of the Pulsar Wind Nebula in the Supernova Remnant CTB 80

We investigated the kinematics of the pulsar wind nebula (PWN) associated with PSR B1951+32 in the old supernova remnant CTB 80 using the Fabry-Perot interferometer of the 6m Special Astrophysical Observatory telescope. In addition to the previously known expansion of the system of bright filaments with a velocity of 100-200km/s, we detected weak high-velocity features in the H-alpha line at least up to velocities of 400-450km/s. We analyzed the morphology of the PWN in the H-alpha, [SII], and [OIII] lines using HST data and discuss its nature. The shape of the central filamentary shell, which is determined by the emission in the [OIII] line and in the radio continuum, is shown to be consistent with the bow-shock model for a significant (about 60 degrees) inclination of the pulsar's velocity vector to the plane of the sky. In this case, the space velocity of the pulsar is twice higher than its tangential velocity, i.e., it reaches ~500 km/s, and PSR B1951+32 is the first pulsar whose line-of-sight velocity (of about 400 km/s) has been estimated from the PWN observations. The shell-like H-alpha-structures outside the bow shock front in the east and the west may be associated with both the pulsar's jets and the pulsar-wind breakthrough due to the layered structure of the extended CTB 80 shell.Comment: to appear in Astronomy Letters, 12 pages, 6 postscript figures, two in colour; for a version with high resolution figures see http://www.sao.ru/hq/grb/team/vkom/CTB80_fine.pd

Discovery of a highly energetic pulsar associated with IGR J14003-6326 in a young uncataloged Galactic supernova remnant G310.6-1.6

We report the discovery of 31.18 ms pulsations from the INTEGRAL source IGR J14003-6326 using the Rossi X-ray Timing Explorer (RXTE). This pulsar is most likely associated with the bright Chandra X-ray point source lying at the center of G310.6-1.6, a previously unrecognised Galactic composite supernova remnant with a bright central non-thermal radio and X-ray nebula, taken to be the pulsar wind nebula (PWN). PSR J1400-6325 is amongst the most energetic rotation-powered pulsars in the Galaxy, with a spin-down luminosity of Edot = 5.1E+37 erg.s-1. In the rotating dipole model, the surface dipole magnetic field strength is B_s = 1.1E+12 G and the characteristic age tau_c = P/2Pdot = 12.7 kyr. The high spin-down power is consistent with the hard spectral indices of the pulsar and the nebula of 1.22 +/- 0.15 and 1.83 +/- 0.08, respectively, and a 2-10 keV flux ratio F_PWN/F_PSR ~ 8. Follow-up Parkes observations resulted in the detection of radio emission at 10 and 20 cm from PSR J1400-6325 at a dispersion measure of ~ 560 cm-3 pc, which implies a relatively large distance of 10 +/- 3 kpc. However, the resulting location off the Galactic Plane of ~ 280 pc would be much larger than the typical thickness of the molecular disk, and we argue that G310.6-1.6 lies at a distance of ~ 7 kpc. There is no gamma-ray counterpart to the nebula or pulsar in the Fermi data published so far. A multi-wavelength study of this new composite supernova remnant, from radio to very-high energy gamma-rays, suggests a young (< 1000 yr) system, formed by a sub-energetic (~ 1E+50 ergs), low ejecta mass (M_ej ~ 3 Msun) SN explosion that occurred in a low-density environment (n_0 ~ 0.01 cm-3).Comment: 9 pages, 6 figures, 2 tables. Accepted for publication in ApJ (after responding to referee's comments, expanded version after the radio detection of the pulsar

Accuracy of single progesterone test to predict early pregnancy outcome in women with pain or bleeding: Meta-analysis of cohort studies

Objective To determine the accuracy with which a single progesterone measurement in early pregnancy discriminates between viable and non-viable pregnancy. Design Systematic review and meta-analysis of diagnostic accuracy studies. Data sources Medline, Embase, CINAHL, Web of Science, ProQuest, Conference Proceedings Citation Index, and the Cochrane Library from inception until April 2012, plus reference lists of relevant studies. Study selection Studies were selected on the basis of participants (women with spontaneous pregnancy of less than 14 weeks of gestation); test (single serum progesterone measurement); outcome (viable intrauterine pregnancy, miscarriage, or ectopic pregnancy) diagnosed on the basis of combinations of pregnancy test, ultrasound scan, laparoscopy, and histological examination; design (cohort studies of test accuracy); and sufficient data being reported. Results 26 cohort studies, including 9436 pregnant women, were included, consisting of 7 studies in women with symptoms and inconclusive ultrasound assessment and 19 studies in women with symptoms alone. Among women with symptoms and inconclusive ultrasound assessments, the progesterone test (5 studies with 1998 participants and cut-off values from 3.2 to 6 ng/mL) predicted a non-viable pregnancy with pooled sensitivity of 74.6% (95% confidence interval 50.6% to 89.4%), specificity of 98.4% (90.9% to 99.7%), positive likelihood ratio of 45 (7.1 to 289), and negative likelihood ratio of 0.26 (0.12 to 0.57). The median prevalence of a non-viable pregnancy was 73.2%, and the probability of a non-viable pregnancy was raised to 99.2% if the progesterone was low. For women with symptoms alone, the progesterone test had a higher specificity when a threshold of 10 ng/mL was used (9 studies with 4689 participants) and predicted a non-viable pregnancy with pooled sensitivity of 66.5% (53.6% to 77.4%), specificity of 96.3% (91.1% to 98.5%), positive likelihood ratio of 18 (7.2 to 45), and negative likelihood ratio of 0.35 (0.24 to 0.50). The probability of a non-viable pregnancy was raised from 62.9% to 96.8%. Conclusion A single progesterone measurement for women in early pregnancy presenting with bleeding or pain and inconclusive ultrasound assessments can rule out a viable pregnancy.Jorine Verhaegen, Ioannis D Gallos, Norah M van Mello, Mohamed Abdel-Aziz, Yemisi Takwoingi, Hoda Harb, Jonathan J Deeks, Ben W J Mol, Arri Coomarasam

(B)ordering South of Lebanon: Hizbullah’s identity building strategy

International audienceThis paper examines the importance of the Lebanese southern borderland area in the political strategy of Hizbullah's identity building. It highlights how Hizbullah succeeded in its quest to become a major political player in Lebanon by using South Lebanon. The main hypothesis is that this borderland area has been ordered and bordered by Hizbullah to create a common identity among the Lebanese Shi'i population based on a Shi'i religious involvement and the " duty " of armed resistance against Israel. To support this idea, I will rely on a theoretical framework articulating space and identity building and will refer to concepts provided by Middle Eastern studies. In the first part of the paper, I will discuss the conditions of the emergence of the group of solidarity and how it articulates to the religious Shi'i ideology. Then, I will highlight the " lebanonization " process Hizbullah undertaken at the end of the civil war and how during the 1990s it transformed the South into a sanctuary. Finally, I will show how Hizbullah enforced the national legitimacy of its social, political and military actions before targeting the state apparatus