Fractional Condensation of Bio-Oil Vapors

The research project described in this thesis deals with an investigation on the fractional condensation of bio-oil vapors to improve the separation of some of the key components of the bio-oil and, consequently, improve the properties and the value of each of the separated product streams. In the first part, the separation of a mixture of three model compounds of bio-oil from a vapor and carrier gas stream was investigated with the help of a series of three condensers maintained at different temperatures. The practical performance of the fractional condensation train was improved by comparing the experimental results with the theoretical results predicted by the HYSYS modeling tool. It showed that good heat transfer and mixing was essential, and could be achieved by using condensers with a cyclonic entry. It also showed that a good demister was essential to achieve effective separation. The second and third parts of the investigation focused on the fractional condensation of actual bio-oil vapors produced from the pyrolysis of two different biomasses: birch bark and Kraft lignin, respectively. In both cases, the temperatures of the condensers were optimized in order to separate the water present in the bio-oil vapor stream and increase the quality and the stability of the remaining bio-oil. The condenser train consisted of a condenser-cum-electrostatic precipitator (C-ESP) installed between two cyclonic condensers. The water content of the fractionated bio-oil was found to be less than 1 wt% with both biomasses. In case of Kraft lignin, the phenolics recovered in different bio-oil fractions were also analyzed. The effect of pyrolysis temperature on the fractionated bio-oil yield and characteristics was investigated

Leaders pay a price when they mismanage employees’ negative feelings

It impacts people's relationships with the boss, their job satisfaction and helping behaviours, write Laura M. Little, Janaki Gooty and Michele William

Precise Asymptotics in Wichura's Law of Iterated Logarithm

Let {Xn, n ≥ 1} be a sequence of independent and identically distributed random variables with a common distribution function F = P(X ≤ x) in the domain of attraction of an asymmetric stable law, with index α, 1 < α < 2 and set Sn=∑nK=1XK. We prove                                         limε->0(√ε) ∑n≥3(1/n)P(Sn≤(θα-ε)An )=1/(2√2α), where An = n1/α(log log n)((α-1)/α) θα =(B(α))((α-1)/α) and B(α) = (1 − α)α(α/(1-α)) (cos (πα/2)) (α/α-1

Development and test of a model linking emotions and work behaviors

Scope and Method of Study: This dissertation investigates the effects of discrete emotions and Emotional intelligence on work related behaviors. The research design follows a laboratory based design and an event based field longitudinal study.Findings and Conclusions: Emotional Intelligence moderated the relationship between four discrete emotions (anger, guilt, joy and pride) and coping strategies. Coping strategies (either task focused or emotion focused) in turn had effects on performance, workplace deviance behavior and organizational citizenship behaviors

Finite Element Study on the Effect of Geometrical Parameters on the Mechanical Behavior of 3D Reentrant Auxetic Honeycombs.

Abstract Auxetic materials are a special case of cellular materials, which exhibit a negative Poisson’s ratio. This in fact is the reason behind their peculiar behavior i.e. lateral shrinkage under longitudinal compression and vice versa. Since these materials do not obey the laws of “normal” materials and go beyond common sense, they are still an emerging class which can be put to use for various purposes like self-locking reinforcing fibers in composites, controlled release media, self-healing films, piezoelectric sensors, and also be used in biomedical engineering. Their stress-strain behavior, Poisson’s ratio and impact energy absorption are controlled by bulk material as well as the unit cell geometry. Among many forms of auxetic structures available, we have chosen a three-dimensional reentrant auxetic honeycomb unit cell. The unit cell geometrical parameters were taken from literature. In this study, we try to understand the effects of strut angle through finite element simulations while keeping the bulk material, unit cell size, strut thickness and number of repetitions constant. A total of three different angles were tested, based on which we conclude that as angle increases, the Poisson’s ratio increases and Energy absorption is maximum at 30 deg

A Comparative Study of Effect of Oral Melatonin Versus Oral Midazolam as Premedicant in Children Undergoing Surgery Under General Anesthesia

Background: Preoperative anxiety in children is associated with multiple post-operative outcomes like post-operative regressive behavioral disturbances, prolonged distress in the recovery phase, eating disorders, and bedwetting. The present study was designed to use low-dose oral melatonin versus oral midazolam in relieving pre-operative anxiety in children in the Indian population. Materials and Methods: A prospective randomized comparative study was conducted on children aged between 2 to 10 years of age scheduled for elective surgeries under general anesthesia are included in the study. This study was conducted with a sample size of 70. Patients were randomly distributed into two groups of 35 content. Group A (received 0.2mg/kg melatonin as premedical) and group B (received 0.5mg/kg midazolam as premedical). Results: Mean induction dose of propofol in the melatonin group was 52.143+ 18.36 mg and in the midazolam, the group was 48.714 + 16.6 mg. In our study, 90 minutes after premedication, the anxiety score was less in the midazolam group. There was no statistically significant difference between the sedation scores in melatonin and midazolam. Conclusion: Low-dose melatonin (0.2mg/kg) is not an effective alternative premedicant in children to alleviate preoperative anxiety compared to midazolam

Paper 2: Conceptualizing the transition from advanced to consultant practitioner: role clarity, self-perception, and adjustment

Background Interest in the influence of emotions on behaviour, decision making, and leadership has accelerated over the last decade. Despite this, the influence of emotions on career advancement and behaviour within radiography and radiotherapy has largely been ignored. The ease of transition from one work role to another within an individual's career may be influenced by previous experience, personal characteristics, organizational environment, culture, and the nature of the role itself. Consequently, the transition from the often well-defined role of advanced or specialist practitioner to the more fluid role of consultant practitioner is associated with changing emotions as reported in the first part of this two-part series. What remains unexplored are the emotional triggers that pre-empt each stage in the transition cycle and how our understanding of these might support the successful implementation of consultant practitioner roles. Objectives To explore the emotional triggers that pre-empted each stage in the transitional journey of trainee consultant radiographers as they moved from advanced to consultant practitioner within a locally devised consultant development program. Design Longitudinal qualitative enquiry. Methods and Settings Five trainee consultant radiographers were recruited to a locally devised consultant practice development program within a single UK hospital trust. Semistructured interviews were undertaken at 1, 6, and 12 months with the trainees. Results Although all trainee consultant radiographers experienced the emotional events described in the first part of this two-part series in a predictable order (ie, elation, denial, doubt, crisis, and recovery), the timing of the events was not consistent. Importantly, four emotional triggers were identified, and the dominance of these and the reaction of individuals to them determined the emotional well-being of the individual over time. Conclusions This study provides a unique and hitherto unexplored insight into the transition journey from advanced or specialist practitioner. Importantly, the findings suggest that commonly adopted supportive change interventions may, in fact, trigger the negative emotions they are intended to alleviate and disable rather than enable role transition

A Literature Review of Social and Economic Leader-Member Exchange

Leader–member exchange (LMX) research has increasingly relied upon the social exchange theory (SET) as a theoretical foundation, but the dominating way of measuring LMX has not followed this theoretical development (Gottfredson et al., 2020). With the aim of developing a measure that more coherently reflects SET, Kuvaas et al. (2012) conceptualized LMX as two qualitatively different relationships, labeled economic LMX and social LMX. Since the most applied LMX measures are under scrutiny for not being sufficiently grounded in theory (Gottfredson et al., 2020), it may be especially important to expose alternative measures. Therefore, we provide a comprehensive review of the research to date applying a two-dimensional approach to LMX, while also adding to interpretation and suggestions for how we can progress the field even further.publishedVersio

The place and role of (moral) anger in organizational behavior studies

The aim of this article is to conceptually delineate moral anger from other related constructs. Drawing upon social functional accounts of anger, we contend that distilling the finer nuances of morally motivated anger and its expression can increase the precision with which we examine prosocial forms of anger (e.g., redressing injustice), in general, and moral anger, in particular. Without this differentiation, we assert that (i) moral anger remains theoretically elusive, (ii) that this thwarts our ability to methodologically capture the unique variance moral anger can explain in important work outcomes, and that (iii) this can promote ill-informed organizational policies and practice. We offer a four-factor definition of moral anger and demonstrate the utility of this characterization as a distinct construct with application for workplace phenomena such as, but not limited to, whistle-blowing. Next, we outline a future research agenda, including how to operationalize the construct and address issues of construct, discriminant, and convergent validity. Finally, we argue for greater appreciation of anger's prosocial functions and concomitant understanding that many anger displays can be justified and lack harmful intent. If allowed and addressed with interest and concern, these emotional displays can lead to improved organizational practic