49 research outputs found

    Zircon and allanite U-Pb ID-TIMS ages of vaugnerites from the Calzadilla pluton, Salamanca (Spain) : dating mantle-derived magmatism and post-magmatic subsolidus overprint

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    Basic to intermediate high-K, high-Mg mantle-derived rocks occur throughout the Iberian Massif and are particularly important in the Tormes Dome, where vaugnerites form several stocks and small plutons. One of the largest and geochemically most variable among these plutons is the Calzadilla pluton in the Tormes Dome that crystallized at 318 ± 1.4Ma (Bashkirian; U-Pb TIMS zircon). This age reveals that the vaugnerite pluton was emplaced during the transition from late D2 extensional deformation to early D3 contractional deformation (319 to 317Ma). Large-scale extension in the area resulted, on one hand, in extensive anatexis in the crust due to quasiisothermal decompression and mica-dehydration melting and, on the other hand, in the upwelling of the mantle, which induced partial melting of the enriched domains in the lithospheric mantle. The driving reason why crustal and mantle melts were coeval is extension. The U-Pb ID-TIMS age of allanite is not related to the emplacement nor cooling of the Calzadilla vaugnerite, but it seems to be related to a younger subsolidus overprint ca. 275Ma that, in the scale of the Central Iberian Zone, corresponds to a period of hydrothermal alteration, including episyenite formation and tungsten mineralization

    Mapping of tecto-lineaments and their influence on sedimentological processes in a GIS environment: a case study of the Iberian trough, Spain

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    p. 165-174The subsurface sedimentary succession of the Iberian Trough, Spain was examined using geophysical t echniques (analogue seismic profiles) and inverse distance weighted (IDW) interpolation algorithm implemented in a gvGIS open source software. The results showed that the Late Cretaceous succession is divided into two depositional sequences: DS­1 (Late Albian–Middle Turonian) and DS­2 (Late Turonian–Campanian). From the analogical seismic sections, digital data and quantitative isopach maps for DS­1 and DS­2 were obtained. The new isopach maps obtained for the DS­1 sequence showed that the deeper sectors of the basin were located to the northeast and the proximal ones to the southwest. The palaeoshoreline was inferred to be situated in the N 150 direction. Across and parallel to this direction several blocks were delimited by faults, with a direction between 30 N and N 65. The thickness of the sediments in these blocks varied in direction NW–SE, with subsidence and depocentres in hangingwall and uplift in the footwall. These variations may have been related to active synsedimentary faults (e.g., Boñar and Yugueros Faults). In the DS­2 sequence, a lineament separated the smaller thicknesses to the southwest from the larger thicknesses (up to 1400 m) to the northeast. This lineament had an N170 orientation and it indicated the position of the palaeoshoreline. In the isopach map for DS­2 there were two groups of lineaments. The first showed a block structure that was limited by N100–120, they were foundering toward the S and had large thicknesses (depocentres), and rose towards the N, where there were smaller thicknesses. The second group of lineaments had a N 50–65 direction and, in this case, they had a similar interpretation as the one in DS­1. The maps obtained are of great help for geologists and permit better understanding of the geological setting and stratigraphic succession of the Late Cretaceous of the Iberian Trough.S

    Liberation characteristics of Ta-Sn ores from Penouta, NW Spain

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    The strategic importance of tantalum and its scarcity in Europe makes its recovery from low grade deposits and tailings interesting. In Penouta, the contents of Ta and Sn in old tailings from an Sn mine are of economic interest. Due to the relatively low grade of Ta of around 100 ppm, a detailed study of the mineralogy and liberation conditions is necessary. In this study, the mineralogy and the liberation characteristics of Sn and Ta ores of the Penouta tailings were investigated and compared with the current leucogranite outcropping ores. The characterization was conducted through X-ray diffraction, scanning electron microscopy, and electron microprobe. In addition, automated mineralogy techniques were used to determine the mineral associations and liberation characteristics of ore minerals. The grade of the leucogranite outcropping was found to be about 80 ppm for Ta and 400 ppm for Sn, and in the tailings used for the liberation study, the concentrations of Ta and Sn were about 100 ppm Ta and 500 ppm Sn, respectively. In both, the leucogranite outcropping and tailings, the major minerals found were quartz, albite, K-feldspar, and white mica. Ore minerals identified were columbite-group minerals (CGM), microlite, and cassiterite. The majority of CGM examined were associated with cassiterite, quartz, and muscovite particle compositions and cassiterite was mainly associated with CGM, quartz, and muscovite. The liberation size was 180 µm for CGM

    Late-Variscan multistage hydrothermal processes unveiled by chemical ages coupled with compositional and textural uraninite variations in W-Au deposits in the western Spanish Central System Batholith

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    The scheelite skarn from Los Santos and the W-Au veins from El Cabaco district, located in the Spanish Central System Batholith (SCSB), are some of the best-known tungsten ore deposits in Spain. Uraninite is an accessory mineral in both deposits, which underwent several hydrothermal flow events. Chemical and textural characteristics, as well as electron microprobe U-Th-Pb uraninite chemical data from the different stages of the skarn and the vein-type mineralizations, are presented here. Based on these data the uraninite was able to be classified into two groups. Group I uraninite has an octahedral habit and occurs as inclusions in K-feldspar relicts of the leucogranite related to Los Santos skarn formation. It shows high Th (6.95 to 8.51wt.% ThO2) and high Rare Earth Elements (REEs) contents (0.55 to 1.38wt.% ∑REE2O3). Group II uraninite occurs i) associated to El Cabaco granite, in a greenish selvage-style greisen and its reddish envelope and in the mineralized rimming quartz veins and ii) in Los Santos high-temperature endoskarn and anorthite skarn, where it is associated with U-rich mica. This uraninite type has lower Th and ∑REE2O3contents than Group-I uraninite. The mineral chemistry and the assemblage and textural relationships suggest that Group-I uraninite is magmatic and the attained U-Th-Pb chemical age of 300±4Ma is interpreted as the magmatic age of the skarn-forming aplite granites in the western part of the SCSB. Group-II uraninite includes two events: i) hydrothermal uraninite, which yields an age of 295±2Ma, dates a strong alkali mobilization and early tungsten deposition and ii) a later hydrothermal process, around 287±4Ma, that resulted in sulfides and late scheelite precipitation and widespread silicification. Finally, the gold deposition is younger than this silicification according to textural criteria. Therefore, W-Au deposits in the western part of the SCSB were formed by superposition of several processes that took place some 15Ma after the skarn-forming granite crystallized. Comparable W, W-Au and U deposits in the Variscan orogenic belt show a similar timing of hydrothermal events, suggesting that the hydrothermal history was controlled by large-scale Late-Variscan tectonic processes

    Textural and mineral-chemistry constraints on columbite-group minerals in the Penouta deposit: evidence from magmatic and fluid-related processes

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    The Penouta Sn-Ta deposit, in the northwest of Spain, is a greisenized granitic cupola where Ta minerals occur mainly as disseminations in a leucogranite body intruded in Precambrian–Lower Cambrian gneisses and mica-schists. This leucogranite is a medium- to fine-grained inequigranular rock consisting mainly of quartz, albite, K-feldspar and muscovite. Accessory minerals are mainly of spessartine, zircon, cassiterite, Nb-Ta oxides, monazite, xenotime, native bismuth and pyrite. The alteration processes were mainly albitization, muscovitization and kaolinitization. This leucogranite is peraluminous and P-poor, with 0.03–0.07 wt.% P2O5, 900–1500 ppm Rb, 30–65 ppm Cs, 120–533 ppm Li, 80–140 ppm Ta, 51–81 ppm Nb and up to 569 ppm of Sn. Mineralogical characterization of Nb-Ta oxide minerals was determined by X-ray diffraction, scanning electron microscopy, electron microprobe analysis and mineral liberation analysis. Mn-rich members of the columbite-group minerals (CGM) are the most common Ta-bearing phases, but microlite, wodginite, tapiolite and Ta-rich cassiterite occur also. CGM crystals are commonly zoned concentrically, with a Nb-rich core surrounded by a Ta-rich rim, with a sharp boundary between them. Convoluted zoning occurs also. Dissolution textures resulting from the corrosion of columbite and tantalite rims, in particular, are common. TheMn/(Mn + Fe) ratio varies between 0.33 and 0.97 and the Ta/(Ta + Nb) ratio between 0.07 and 0.93. Wodginite and microlite formed as late replacements of CGM and occur associated with tantalite and cassiterite. Subhedral to anhedral cassiterite crystals, usually up to 200 µmacross, occur in two generations: the earlier one is Nb,Ta-poor whereas in the later generation, the Ta content can reach >9 wt.%of Ta2O5 and 1.7 wt.%of Nb. The presence of a fluid phase in the apical zone of the granite, probably related to the separation of a fluid/vapour of the melt, could explain the sponge-like textures, the Ta enrichment associated with these textures, the occurrence of Taenriched mineral phases (microlite and wodginite) and their common interstitial character.Peer ReviewedPostprint (published version

    A clinical method for mapping and quantifying blood stasis in the left ventricle

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    In patients at risk of intraventrcular thrombosis, the benefits of chronic anticoagulation therapy need to be balanced with the pro-hemorrhagic effects of therapy. Blood stasis in the cardiac chambers is a recognized risk factor for intracardiac thrombosis and potential cardiogenic embolic events. In this work, we present a novel flow image-based method to assess the location and extent of intraventricular stasis regions inside the left ventricle (LV) by digital processing flow-velocity images obtained either by phase-contrast magnetic resonance (PCMR) or 2D color-Doppler velocimetry (echo-CDV). This approach is based on quantifying the distribution of the blood Residence Time (TR) from time-resolved blood velocity fields in the LV. We tested the new method in illustrative examples of normal hearts, patients with dilated cardiomyopathy and one patient before and after the implantation of a left ventricular assist device (LVAD). The method allowed us to assess in-vivo the location and extent of the stasis regions in the LV. Original metrics were developed to integrate flow properties into simple scalars suitable for a robust and personalized assessment of the risk of thrombosis. From a clinical perspective, this work introduces the new paradigm that quantitative flow dynamics can provide the basis to obtain subclinical markers of intraventricular thrombosis risk. The early prediction of LV blood stasis may result in decrease strokes by appropriate use of anticoagulant therapy for the purpose of primary and secondary prevention. It may also have a significant impact on LVAD device design and operation set-up

    The Importance of Spanish Data (BDMIN & PANORAMA MINERO) in the European Raw Materials Knowledge Base (EURMKB)

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    [EN] The IGME has an extensive experience in the field of mineral resources and the main source of information is the Mineral Resources Database (BDMIN) that integrates the geological‐mining information on occurrences, mines and exploitations (active and inactive) of metallic, nonmetallic and industrial minerals, and rocks in Spain. In addition, since 1981, the Panorama Minero has been carried out with the aim of providing reliable data on Spanish mining production, based on the Spanish Mining Statistics (MITERD). This information includes data on the national production of minerals, in tonnage and value, metallurgical production, foreign trade, etc. Other sources include the National Mining Cadastre and Foreign Trade statistics from the Tax Agency.Peer reviewe
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