57 research outputs found

    Formic acid synthesis using CO₂ as raw material: Techno-economic and environmental evaluation and market potential

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    The future of carbon dioxide utilisation (CDU) processes, depend on (i) the future demand of synthesised products with CO₂, (ii) the availability of captured and anthropogenic CO₂, (iii) the overall CO₂ not emitted because of the use of the CDU process, and (iv) the economics of the plant. The current work analyses the mentioned statements through different technological, economic and environmental key performance indicators to produce formic acid from CO₂, along with their potential use and penetration in the European context. Formic acid is a well-known chemical that has potential as hydrogen carrier and as fuel for fuel cells. This work utilises process flow modelling, with simulations developed in CHEMCAD, to obtain the energy and mass balances, and the purchase equipment cost of the formic acid plant. Through a financial analysis, with the net present value as selected metric, the price of the tonne of formic acid and of CO₂ are varied to make the CDU project financially feasible. According to our research, the process saves CO₂ emissions when compared to its corresponding conventional process, under specific conditions. The success or effectiveness of the CDU process will also depend on other technologies and/or developments, like the availability of renewable electricity and steam

    Making space for shellfish farming along the Adriatic coast

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    This work focuses on the selection of new areas for shellfish farming along the coast of the Northern Adriatic Sea (Italy). Shellfish site suitability was assessed by means of a methodology based on Spatial Multi-Criteria Evaluation (SMCE), which provided the framework to combine mathematical models and operational oceanography products. Intermediate level criteria considered in the analysis included optimal growth conditions, environmental interactions, and socio-economic evaluation (e.g. organic carbon deposition; distance to harbour). Results showed that the whole coastal area comprised within 0 and 3 nm is highly suitable for farming of mussel, while the area comprised between 3 and 12 nm is divided between a highly suitable northern part, and a less suitable southern one. Seven different scenarios of development of shellfish aquaculture industry were explored. The introduction of a new species, and the assessment of the exposure to storm events are specific aspects taken into account in development scenarios. Results show that the degree of suitability for shellfish aquaculture in this area would not change dramatically with the introduction of oyster farming. Furthermore, results highlight that: (i) the growth potential in this area is high; (ii) the space with suitability index >0.5 increases when prioritizing the optimal growth condition criteria, and (iii) the socio-economic is the most restrictive Intermediate Level Criteria. Results were discussed by deriving general lessons concerning the use of SMCE in aquaculture space allocation, from the specific application in the Northern Adriatic Sea. Challenges and opportunities related to the proposed methodological framework, with particular reference to the use of resources provided by remote sensing and operational oceanography by means of mathematical models, were also discussed. Results can support a science-based identification of allocated zones for aquaculture in order to avoid conflicts, and promote sustainable aquaculture in the Mediterranean Sea, where the space for these activities is becoming increasingly limited

    Consolidated briefing of biochemical ethanol production from lignocellulosic biomass

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    AbstractBioethanol production is one pathway for crude oil reduction and environmental compliance. Bioethanol can be used as fuel with significant characteristics like high octane number, low cetane number and high heat of vaporization. Its main drawbacks are the corrosiveness, low flame luminosity, lower vapor pressure, miscibility with water, and toxicity to ecosystems. One crucial problem with bioethanol fuel is the availability of raw materials. The supply of feedstocks for bioethanol production can vary season to season and depends on geographic locations. Lignocellulosic biomass, such as forest-based woody materials, agricultural residues and municipal waste, is prominent feedstock for bioethanol cause of its high availability and low cost, even though the commercial production has still not been established. In addition, the supply and the attentive use of microbes render the bioethanol production process highly peculiar. Many conversion technologies and techniques for biomass-based ethanol production are under development and expected to be demonstrated. In this work a technological analysis of the biochemical method that can be used to produce bioethanol is carried out and a review of current trends and issues is conducted

    Environmental citizenship and public attitudes to hydrogen energy technologies

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    Some of the principal arguments in the debate about environmental citizenship are examined with reference to the development of hydrogen energy systems. In particular, qualitative evidence is drawn from a study of public attitudes towards hydrogen energy technologies and their perceived risks and benefits. Using data from focus groups in three areas of the UK, it is argued that while there is awareness of the importance of energy issues, opinions about innovation using hydrogen are generally neutral, and there is little indication of the collective and solidaristic values said to characterise environmental citizenship

    Sustainable transport visions: What role for hydrogen and fuel cell vehicle technologies?

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    Transport systems perform vital societal functions, but in their present state cannot be considered 'sustainable'. Particular concerns in this respect include emissions, accidents, land use, noise and inaccessibility of amenities. Increasing attention is being focussed or hydrogen transport technologies as a possible means of achieving more sustainable transport. In this paper, we draw on expert stakeholder evidence and the wider literature to elucidate criteria for sustainable transport and determine the extent to which hydrogen transport technologies can meet these criteria. Our findings indicate that hydrogen could alleviate some of the problems in the transport sector associated with emissions and energy supply security. However, other transport problems are not mitigated - and some may even be exacerbated - by hydrogen use. Thus, we highlight the need for integrated transport policies and argue for more reflexive and inclusive societal debate about the impacts and beneficiaries of hydrogen transport technologies
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