3,389 research outputs found

    A Nexafs Study of Nitric Oxide Layers Adsorbed from a nitrite Solution onto a Pt(111) Surface

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    NO molecules adsorbed on a Pt(111) surface from dipping in an acidic nitrite solution are studied by near edge X-ray absorption fine structure spectroscopy (NEXAFS), X-ray photoelectron spectroscopy (XPS), low energy electron diffraction (LEED) and scanning tunnelling microscopy (STM) techniques. LEED patterns and STM images show that no long range ordered structures are formed after NO adsorption on a Pt(111) surface. Although the total NO coverage is very low, spectroscopic features in N K-edge and O K-edge absorption spectra have been singled out and related to the different species induced by this preparation method. From these measurements it is concluded that the NO molecule is adsorbed trough the N atom in an upright conformation. The maximum saturation coverage is about 0.3 monolayers, and although nitric oxide is the major component, nitrite and nitrogen species are slightly co-adsorbed on the surface. The results obtained from this study are compared with those previously reported in the literature for NO adsorbed on Pt(111) under UHV conditions

    ROUNDHOUSE KICK WITH AND WITHOUT IMPACT IN KARATEKA OF DIFFERENT TECHNICAL LEVEL

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    The purpose of this study was to compare two different Karate roundhouse kicks performed by athletes of different technical level. The combination of high movement velocities and a high technical difficulty, qualify these actions as a good model to quantify the ability of a Karateka to execute complex movements. The first kick, directed to the face, entails a strong braking action to avoid the impact (NI), the other, directed to the chest, is concluded by an impact (IM). Technical aspects and the role of muscular co-activation as joint protector were investigated in six top level Karateka (KA) and six practicing karate amateurs (CO), by estimating joint kinematics and neuromuscular activity patterns. KA presented a faster execution for both tasks, prevalently due to a faster knee extension, supported by a low co-activation of the antagonist Biceps Femoris. This behaviour confirms that elite KA tend to lower the co-activation of antagonist muscles during fast movements, partially in contrast with the antagonists possible role in maintaining knee stability. The NI task, requiring higher technical competence and entailing a high target, is performed by KA athletes using a peculiar technique, based on a wide hip flexion-extension range, with a peak hip ab-adduction occurring earlier than in CO. A lower co-activation presented by CO during knee flexion is presumably due to their difficulty in mastering this complex kick

    Optical devices provide unprecedented insights into the laser cleaning of calcium oxalate layers

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    Abstract Calcium oxalates are insoluble colorless or whitish salts constituting noble patina, on both natural and artificial stone artworks' surfaces, the presence of which is extremely valued. The oxalates are not considered detrimental to the substrate, however, being often accompanied by other substances such as gypsum, silicates, and pigmented particles. They may form very adherent, relatively thick and colored layers creating disfiguring effects and hindering legibility of the pictorial surface. For this reason it may be appropriate to diminish their thickness, but patina's partial preservation is particularly required calling for extremely gradual and controllable cleaning approach. Thinning of calcium oxalate patina from a detached 16th century fresco (from Sansepolcro) was performed through the use of laser (Nd:YAG and Er:YAG) systems and chemical means (Carbogel loaded 5 wt.% of tetrasodium EDTA). Optical coherence tomography (OCT), providing a non-invasive stratigraphic cross-section of the examined surface, allowed to distinguish the oxalate from the underlying original layers and therefore to have an overview about its distribution, to numerically evaluate patina's thickness range and to provide the information on the amount of the material both removed and left on the artwork's surface. Laser scanning conoscopic microprofilometry allowed for a high-density sampling of the artwork's surface providing a three-dimensional model of the surface pattern. The obtained 3D models were used to estimate the amount of material removed and to compare them with those provided by OCT. The successful exploitation of the proposed exceptional cleaning monitoring methodology may be seen as an innovative and valid support for the restorers in the conservation of mural painting or other surfaces covered by oxalate layers and may pilot more targeted, cautious and respectful cleaning intervention

    Sharp transition towards shared vocabularies in multi-agent systems

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    What processes can explain how very large populations are able to converge on the use of a particular word or grammatical construction without global coordination? Answering this question helps to understand why new language constructs usually propagate along an S-shaped curve with a rather sudden transition towards global agreement. It also helps to analyze and design new technologies that support or orchestrate self-organizing communication systems, such as recent social tagging systems for the web. The article introduces and studies a microscopic model of communicating autonomous agents performing language games without any central control. We show that the system undergoes a disorder/order transition, going trough a sharp symmetry breaking process to reach a shared set of conventions. Before the transition, the system builds up non-trivial scale-invariant correlations, for instance in the distribution of competing synonyms, which display a Zipf-like law. These correlations make the system ready for the transition towards shared conventions, which, observed on the time-scale of collective behaviors, becomes sharper and sharper with system size. This surprising result not only explains why human language can scale up to very large populations but also suggests ways to optimize artificial semiotic dynamics.Comment: 12 pages, 4 figure

    Extreme value laws in dynamical systems under physical observables

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    Extreme value theory for chaotic dynamical systems is a rapidly expanding area of research. Given a system and a real function (observable) defined on its phase space, extreme value theory studies the limit probabilistic laws obeyed by large values attained by the observable along orbits of the system. Based on this theory, the so-called block maximum method is often used in applications for statistical prediction of large value occurrences. In this method, one performs inference for the parameters of the Generalised Extreme Value (GEV) distribution, using maxima over blocks of regularly sampled observations along an orbit of the system. The observables studied so far in the theory are expressed as functions of the distance with respect to a point, which is assumed to be a density point of the system's invariant measure. However, this is not the structure of the observables typically encountered in physical applications, such as windspeed or vorticity in atmospheric models. In this paper we consider extreme value limit laws for observables which are not functions of the distance from a density point of the dynamical system. In such cases, the limit laws are no longer determined by the functional form of the observable and the dimension of the invariant measure: they also depend on the specific geometry of the underlying attractor and of the observable's level sets. We present a collection of analytical and numerical results, starting with a toral hyperbolic automorphism as a simple template to illustrate the main ideas. We then formulate our main results for a uniformly hyperbolic system, the solenoid map. We also discuss non-uniformly hyperbolic examples of maps (H\'enon and Lozi maps) and of flows (the Lorenz63 and Lorenz84 models). Our purpose is to outline the main ideas and to highlight several serious problems found in the numerical estimation of the limit laws

    Robot-era project: Preliminary results on the system usability

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    The European project Robot-Era is an ambitious integrated project (FP7-ICT-2011.5.4), which objective is the development of advanced robotic services, integrated in intelligent environments, to provide independent living to older people. In order to guarantee the matching of the users� need and the demands, two loops of experimentation were conceived, in realistic and real setting. The aim of the paper is to described the methods applied and the main results coming from the first experimental loop, concerning the degree of usability of the interfaces and provide guidelines for testing socially assistive robots with older people. � Springer International Publishing Switzerland 2015
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