16 research outputs found
Properties of poly(vinyl chloride) fibers crosslinked by 2-dibutylamino-4,6-dimercapto-1,3,5-triazine
Hybrid polyoxometalate clusters with appended aromatic platforms
The assembly of polyoxometalate architectures based on Mn-Anderson clusters capped with different aromatic platforms via the 'Tris' linker (Tris tris(hydroxymethyl) aminomethane), allows the formation and isolation of four new hybrid polyoxometalate clusters of 2-5 with the general composition of [n-N(C4H9)(4)](3)[MnMo6O18{(OCH2)(3)CN = CH-R}(2)]center dot solv., (R = (C6H5) 2, -(C6H5O) 3, -(C11H8N) 4 and -(C13H9) 5; solv. MeOH or H2O). These compounds were obtained simply by the reaction of compound 1, ([n-N(C4H9)(4)](3)[MnMo6O18{(OCH2)(3)CNH2}(2)]), with the corresponding aldehyde and the aromatic platforms were chosen to explore the design principles for covalently constructed POM aromatic-organic-inorganic hybrids
Novel Gallium Polyoxometalate/Nano-Gold Hybrid Material Supported on Nano-sized Silica for Mild Cyclohexene Oxidation Using Molecular Oxygen
Design and synthesis of "dumb-bell" and "triangular" inorganic-organic hybrid nanopolyoxometalate clusters and their characterisation through ESI-MS analyses
A series of tris(hydroxymethyl)aminomethane (TRIS)-based linear (bis(TRIS)) and triangular (tris(TRIS)) ligands has been synthesised and were covalently attached to the WellsâDawson type cluster [P<sub>2</sub>V<sub>3</sub>W<sub>15</sub>O<sub>62</sub>]<sup>9â</sup> to generate a series of nanometer-sized inorganicâorganic hybrid polyoxometalate clusters. These huge hybrids, with a molecular mass similar to that of small proteins in the range of ≈10â16â
kDa, were unambiguously characterised by using high-resolution ESI-MS. The ESI-MS spectra of these compounds revealed, in negative ion mode, a characteristic pattern showing distinct groups of peaks corresponding to different anionic charge states ranging from 3<sup>â</sup> to 8<sup>â</sup> for the hybrids. Each peak in these individual groups could be unambiguously assigned to the corresponding hybrid cluster anion with varying combinations of tetrabutylammonium (TBA) and other cations. This study therefore highlights the prowess of the high-resolution ESI-MS for the unambiguous characterisation of large, nanoscale, inorganicâorganic hybrid clusters that have huge mass, of the order of 10â16â
kDa. Also, the designed synthesis of these compounds points to the fact that we were able to achieve a great deal of structural pre-design in the synthesis of these inorganicâorganic hybrid polyoxometalates (POMs) by means of a ligand design route, which is often not possible in traditional âone-potâ POM synthesis