A combined FEG-SEM and TEM study of silicon nanodot assembly

Nanodots forming dense assembly on a substrate are difficult to characterize in terms of size, density, morphology and cristallinity. The present study shows how valuable information can be obtained by a combination of electron microscopy techniques. A silicon nanodots deposit has been studied by Scanning Electron Microscopy (SEM) and Transmission Electron Microscopy (TEM) to estimate essentially the dot size and density, quantities emphasized because of their high interest for application. High resolution SEM indicates a density of 1.6 × 1012 dots/cm2 for a 5 nm to 10 nm dot size. TEM imaging using a phase retrieval treatment of a focus series gives a higher dot density (2 × 1012 dots/cm2) for a 5 nm dot size. High Resolution Transmission Electron Microscopy (HRTEM) indicates that the dots are crystalline which is confirmed by electron diffraction. According to HRTEM and electron diffraction, the dot size is about 3 nm which is significantly smaller than the SEM and TEM results. These differences are not contradictory but attributed to the fact that each technique is probing a different phenomenon. A core-shell structure for the dot is proposed which reconcile all the results. All along the study, Fourier transforms have been widely used under many aspects

Reaction of terminal phosphinidene complexes with acetylenic alcohols: Intramolecular hydrophosphination of a phosphirene ring

The transient phosphinidene complex [PhP-Mo(CO) 5], as generated from the appropriate 7-phosphanorbornadiene complex at 110°C in toluene, selectively reacts with the C=≡C triple bond of 4-phenyl-3-butyn-1-ol to give the corresponding phosphirene complex 4. Upon further heating, this phosphirene evolves via two pathways. The minor pathway involves the formal addition of the OH bond of the alcohol function onto the phosphirene P-C ring bond to give the 3-benzylidene-1,2-oxaphospholane complex 5. The major pathway involves the reaction of a second molecule of [PhP-Mo(CO) 5] with the OH group of 4, giving an intermediate phosphirene with an additional secondary alkoxyphosphine functionality (7). An intramolecular hydrophosphination of one P-C bond of the phosphirene ring then immediately takes place to give the cis-1,2-bis(phosphino)ethene [MoCCO) 4] complex 8 as a mixture of two diastereomers. After methylation of the PH group of 8, decomplexation can be efficiently achieved by reaction with sulfur. Structures have been ascertained by X-ray analysis for 5, 8, and the disulfide 10

Про водогосподарський комплекс Криму

В статье дается определение понятия "водохозяйственный комплекс региона". Приводятся количественные и качественные характеристики состояния развития этой отрасли в АРК. Делаются выводы и предложения относительно повышения эффективности функционирования отрасли, улучшению качества предоставляемых услуг.У статті дається визначення поняття "водогосподарський комплекс регіону". Приводяться кількісні і якісні характеристики стану розвитку цієї галузі в АРК. Робляться висновки й пропозиції щодо підвищення ефективності функціонування галузі, поліпшенню якості надаваних послуг.There is given the definition of concept "a water complex of the region" in this article. Quantitative are resulted and qualitative behaviors of a condition of development of this area in АRК. The conclusions and proposals concerning increase of efficiency of operation of area, improvement of the quality of rendered services are done

Transitions across Melancholia States in a climate model: reconciling the deterministic and stochastic points of view

The Earth is well known to be, in the current astronomical configuration, in a regime where two asymptotic states can be realized. The warm state we live in is in competition with the ice-covered snowball state. The bistability exists as a result of the positive ice-albedo feedback. In a previous investigation performed on a intermediate complexity climate model we identified the unstable climate states (melancholia states) separating the coexisting climates, and studied their dynamical and geometrical properties. The melancholia states are ice covered up to the midlatitudes and attract trajectories initialized on the basin boundary. In this Letter, we study how stochastically perturbing the parameter controlling the intensity of the incoming solar radiation impacts the stability of the climate. We detect transitions between the warm and the snowball state and analyze in detail the properties of the noise-induced escapes from the corresponding basins of attraction. We determine the most probable paths for the transitions and find evidence that the melancholia states act as gateways, similarly to saddle points in an energy landscape

Further evidence for superterminal raindrops

A network of optical disdrometers (including laser precipitation monitors and a two‐dimensional video disdrometer) was utilized to determine whether the recent reports of “superterminal” raindrops were spurious results of drop breakup occurring on instrumentation. Results unequivocally show that superterminal raindrops at small (less than 1 mm) sizes are ubiquitous, are measurable over an extended area, and appear in every rain event investigated. No evidence was found to suggest that superterminal drops are the result of drop breakup due to impact with the measurement instrument; thus, if the superterminal drops are the result of drop fragmentation, this fragmentation happens in the ambient atmosphere during all rain events measured in this study. The ubiquity of superterminal drops at small drop sizes raises natural questions regarding rain accumulation estimations, estimates of drop size distributions, and erosion characterization

Cenozoic evolution of the steppe-desert biome in Central Asia

The origins and development of the arid and highly seasonal steppe-desert biome in Central Asia, the largest of its kind in the world, remain largely unconstrained by existing records. It is unclear how Cenozoic climatic, geological, and biological forces, acting at diverse spatial and temporal scales, shaped Central Asian ecosystems through time. Our synthesis shows that the Central Asian steppe-desert has existed since at least Eocene times but experienced no less than two regime shifts, one at the Eocene–Oligocene Transition and one in the mid-Miocene. These shifts separated three successive “stable states,” each characterized by unique floral and faunal structures. Past responses to disturbance in the Asian steppe-desert imply that modern ecosystems are unlikely to recover their present structures and diversity if forced into a new regime. This is of concern for Asian steppes today, which are being modified for human use and lost to desertification at unprecedented rates

Rapport de sondages et d'analyses, Le Kilian et les carrières anciennes de trachyte dans la Chaîne des Puys (Puy-de-Dôme)

En 2008, l'existence de carrières souterraines médiévales avait été mise en évidence dans la pente ouest du Bois de Manson qui domine la dépression du Cratère Kilian, au pied sud du puy de Dôme. En 2009-2010, des sondages et prospections ont été étendus à tout l'ensemble du Kilian de façon à préciser l'étendue et, si possible, la chronologie de son exploitation dans le passé. Ces travaux ont permis d'observer, dans le fond du cratère et sur son flanc interne ouest, des amoncellements de déblais d'un volume considérable, témoignant d'une extraction de roche à grande échelle durant le haut Moyen Âge et très probablement aussi à l'époque gallo-romaine. Une nouvelle carrière souterraine a été découverte dans la pente interne ouest du cratère. La base du remplissage de cette carrière a livré des charbons datés entre la fin du IV e siècle et le début du VI e siècle par le radiocarbone, tandis que le sommet du remplissage contenait des tessons de céramique datables, par leur typologie, de la fin du V e siècle au début du VIII e siècle. L'état actuel des investigations conduit à faire l'hypothèse que les gallo-romains ont exploité, au fond du cratère, un trachyte compact dont on ne trouve aujourd'hui que les déchets de taille, et dont les affleurements sont masqués par les déblais, tandis que les artisans du Moyen Âge ont recherché un trachyte plus tendre dans les pentes hautes du cratère. Le Kilian doit donc s'ajouter aux trois sources actuellement connues de trachyte d'oeuvre dans le passé, à savoir les volcans Sarcoui, Aumône (ou petit Suchet) et Cliersou. Dès cette découverte, en 2008, s'est posée la question de savoir quelle part éventuelle le trachyte du Kilian avait pu prendre dans la construction du temple de Mercure au sommet du puy de Dôme et dans l'agglomération gallo-romaine située au col de Ceyssat. Pour y répondre, une campagne d'analyses géochimiques et pétrographiques été engagée pour caractériser, aux fins de comparaison, non seulement les trachytes du Kilian et ceux des ruines gallo-romaines, mais, de plus, les trachytes du Cliersou, de l'Aumône et du Sarcoui. Ces analyses ont finalement montré qu'il est possible de faire une discrimination statistiquement significative entre les différents trachytes étudiés, à l'exception de ceux du couple Cliersou-Aumône dont les laves sont très peu différentes les unes des autres. Le résultat le plus remarquable est que tous les trachytes gallo-romains échantillonnés (dont 10 échantillons distincts au temple de Mercure et 10 au col de Ceyssat) se rattachent sans ambiguïté au Kilian. En toute rigueur, ces nouvelles données ne permettent pas d'exclure sans appel la possibilité d'utilisation à l'époque gallo-romaine, au temple de Mercure et au col de Ceyssat, de trachytes provenant d'autres sources que le Kilian (cas des chaperons de mur du col de Ceyssat, provenant du puy de Dôme). Cependant, il faut ajouter qu'un examen visuel des trachytes d'oeuvre dans ces deux sites, portant sur un nombre de moellons et d'éléments architecturaux bien supérieur au nombre de ceux qui ont été analysés, conduit à conclure que leur source est probablement commune. Cette conclusion est basée sur un faciès minéralogique particulier, observable à l'oeil nu ou à la loupe

Global instability in the Ghil--Sellers model

The Ghil--Sellers model, a diffusive one-dimensional energy balance model of Earth's climate, features---for a considerable range of the parameter descriptive of the intensity of the incoming radiation---two stable climate states, where the bistability results from the celebrated ice-albedo feedback. The warm state is qualitatively similar to the present climate, while the cold state corresponds to snowball conditions. Additionally, in the region of bistability, one can find unstable climate states. We find such unstable states by applying for the first time in a geophysical context the so-called edge tracking method, which has been used for studying multiple coexisting states in shear flows. This method has a great potential for studying the global instabilities in multistable systems, and for providing crucial information on the possibility of transitions when forcing is present. We examine robustness, efficiency, and accuracy properties of the edge tracking algorithm. We find that the procedure is the most efficient when taking a single bisection per cycle. Due to the strong diffusivity of the system, the transient dynamics, is approximately confined to the heteroclininc trajectory, connecting the fixed unstable and stable states, after relatively short transient times. Such a constraint dictates a functional relationship between observables. We characterize such a relationship between the global average temperature and a descriptor of nonequilibrium thermodynamics, the large scale temperature gradient between low and high latitudes. We find that a maximum of the temperature gradient is realized at the same value of the average temperature, about 270 K, largely independent of the strength of incoming solar radiation. Due to this maximum, a transient increase and nonmonotonic evolution of the temperature gradient is possible and not untypical. We also examine the structural properties of the system defined by bifurcation diagrams describing the equilibria depending on a system parameter of interest, here the solar strength. We construct new bifurcation diagrams in terms of quantities relevant for describing thermodynamic properties such as the temperature gradient and the material entropy production due to heat transport. We compare our results for the energy balance model to results for the intermediate complexity general circulation model the Planet Simulator and find an interesting qualitative agreement

Barcoding T Cell Calcium Response Diversity with Methods for Automated and Accurate Analysis of Cell Signals (MAAACS)

International audienceWe introduce a series of experimental procedures enabling sensitive calcium monitoring in T cell populations by confocal video-microscopy. Tracking and post-acquisition analysis was performed using Methods for Automated and Accurate Analysis of Cell Signals (MAAACS), a fully customized program that associates a high throughput tracking algorithm, an intuitive reconnection routine and a statistical platform to provide, at a glance, the calcium barcode of a population of individual T-cells. Combined with a sensitive calcium probe, this method allowed us to unravel the heterogeneity in shape and intensity of the calcium response in T cell populations and especially in naive T cells, which display intracellular calcium oscillations upon stimulation by antigen presenting cells