単層カーボンナノチューブ/ポルフィリン-ポリ酸ランダムネットワークを用いたマテリアルリザバー演算素子 —次世代機械知能への新規アプローチ

九州工業大学博士学位論文（要旨）学位記番号：生工博甲第425号 学位授与年月日：令和3年12月27

単層カーボンナノチューブ/ポルフィリン-ポリ酸ランダムネットワークを用いたマテリアルリザバー演算素子 —次世代機械知能への新規アプローチ

In a layman’s term, computation is defined as the execution of a given instruction through a programmable algorithm. History has it that starting from the simplest calculator to the sophisticated von Neumann machine, the above definition has been followed without a flaw. Logical operations for which a human takes a minute long to solve, is a matter of fraction of seconds for these gadgets. But contrastingly, when it comes to critical and analytical thinking that requires learning through observation like the human brain, these powerful machines falter and lag behind. Thus, inspired from the brain’s neural circuit, software models of neural networks (NN) integrated with high-speed supercomputers were developed as an alternative tool to implement machine intelligent tasks of function optimization, pattern, and voice recognition. But as device downscaling and transistor performance approaches the constant regime of Moore’s law due to high CMOS fabrication cost and large tunneling energy loss, training these algorithms over multiple hidden layers is turning out to be a grave concern for future applications. As a result, the interplay between faster performance and low computational power requirement for complex tasks deems highly disproportional. Therefore, alternative in terms of both NN models and conventional Neumann architecture needs to be addressed in today’s age for next-generation machine intelligence systems. Fortunately, through extensive research and studies, unconventional computing using a reservoir based neural network platform, called in-materio reservoir computing (RC) has come to the rescue. In-maerio RC uses physical, biological, chemical, cellular automata and other inanimate dynamical systems as a source of non-linear high dimensional spatio-temporal information processing unit to construct a specific target task. RC not only has a three-layer simplified neural architectural layer, but also imposes a cheap, fast, and simplified optimization of only the readout weights with machine intelligent regression algorithm to construct the supervised objective target via a weighted linear combination of the readouts. Thus, utilizing this idea, herein in this work we report such an in-materio RC with a dynamical random network of single walled carbon nanotube/porphyrin-polyoxometalate (SWNT/Por-POM) device. We begin with Chapter 1, which deals with the introduction covering the literature of ANN evolution and the shortcomings of von Neumann architecture and training models of these ANN, which leads us to adopt the in-materio RC architecture. We design the problem statement focused on extending the theoretical RC model of previously suggested SWNT/POM network to an experimental one and present the objective of fabricating a random network based on nanomaterials as they closely resemble the network structure of the brain. Finally, we conclude by stating the scope of this research work aiming towards validating the non-linear high dimensional reservoir property SWNT/Por-POM holds for it to explicitly demonstrate the RC benchmark tasks of optimization and classification. Chapter 2 describes the methodology including the chemical repository required for the facile synthesis of the material. The synthesis part is divided broadly into SWNT purification and then its dispersion with Por-POM to form the desired complex. It is then followed up with the microelectrode array fabrication and the consequent wet-transfer thin film deposition to give the ultimate reservoir architecture of input-output control read pads with SWNT/Por-POM reservoir. Finally we give a briefing of AFM, UV-Vis spectroscopy, FE-SEM characterization techniques of SWNT/Por-POM complex along with the electrical set-up interfaced with software algorithm to demonstrate the RC approach of in-materio machine intelligence. In Chapter 3, we study the current dynamics as a function of voltage and time and validate the non-linear information processing ability intrinsic to the device. The study reveals that the negative differential resistance (NDR) arising from redox nature of Por-POM results in oscillating random noise outputs giving rise to 1/f brain-like spatio-temporal information. We compute the memory capacity (MC) and prove that the device exhibits echo state property of fading memory, but remembers very little of the past information. The low MC and high non-linearity allowed us to choose mostly non-linear tasks of waveform generation, Boolean logic optimization and one-hot vector binary object classification as the RC benchmark. The Chapter 4 relates to the waveform generation task. Utilizing the high dimensional voltage readouts of varying amplitude, phase and higher harmonic frequencies, relative to input sine wave, a regression optimization was performed towards constructing cosine, triangular, square and sawtooth waves resulting in a high accuracy of around 95%. The task complexity of function optimization was further enhanced in Chapter 5 where two inputs were used to construct Boolean logic functions of OR, AND, XOR, NOR, NAND and XNOR. Similar to the waveform, accuracy over 95% could be achieved due to the presence of NDR nonlinearity. Furthermore, the device was also tested for classification problem in Chapter 6. Here we showed an off-line binary classification of four object toys; hedgehog, dog, block and bus, using the grasped tactile information of these objects as inputs obtained from the Toyota Human Support Robot. A one-ridge regression analysis to fit the hot vector supervised target was used to optimize the output weights for predicting the correct outcome. All the objects were successfully classified owing to the 1/f information processing factor. Lastly, we conclude the section in Chapter 7 with the future scope of extending the idea to fabricate a 3-D model of the same material as it opens up opportunity for higher memory capacity fruitful for future benchmark tasks of time-series prediction. Overall, our research marks a step stone in utilizing SWNT/Por-POM as the in-materio RC for the very first time thereby making it a desirable candidate for next-generation machine intelligence.九州工業大学博士学位論文 学位記番号：生工博甲第425号 学位授与年月日：令和3年12月27日1 Introduction and Literature review|2 Methodology|3 Reservoir dynamics emerging from an incidental structure of single-walled carbon nanotube/porphyrin-polyoxometalate complex|4 Fourier transform waveforms via in-materio reservoir computing from single-walled carbon nanotube/porphyrin-polyoxometalate complex|5 Room temperature demonstration of in-materio reservoir computing for optimizing Boolean function with single-walled carbon nanotube/porphyrin-polyoxometalate composite|6 Binary object classification with tactile sensory input information of via single-walled carbon nanotube/porphyrin-polyoxometalate network as in-materio reservoir computing|7 Future scope and Conclusion九州工業大学令和3年

Pulse Generation Behavior of Single-Walled Carbon Nanotube/Polyoxometalate Complex Random Network

Replacing von-Neumann architecture with walled carbon nanotube (SWNT) with new neuromorphic chips is vital for computers to perform polyoxometalate POM) ion ([SV2W10O40]H4TPP) complex cognitive problem with low power and see the effect of higher POM concentration. We consume like our brain. The synaptic part of the use simple sonication method for SWNT/POM brain has been well studied via memristors but fabrication and study the spiking and spike time research on the artificial neurons is only limited to high interval behavior via electrical measurements. The power CMOS circuitry. Following the previous work, results show that the device can behave as an artificial by H. Tanaka et al.[2] herein we functionalize single neuron even at low voltages and hence can be used for low power neuromorphic computing.Proceedings of International Symposium on Applied Science 2019 (ISAS),18-19 October, 2019, Ho Chi Minh City University of Technology, Ho Chi Minh City, Vietna

LETKF-ROMS: An improved predictability system for the Indian Ocean

We have developed the assimilation scheme Local Ensemble Transform Kalman Filter (LETKF) and interfaced with the present basin-wide operational ROMS set-up ( 1/12 degree horizontal resolution ) that assimilates in-situ temperature and salinity from RAMA moorings, NIOT buoys and Argo floats. The system also assimilate satellite track data of sea-surface temperature from AMSR-E. The speciality of this assimilation system is that it comprises of ensembles that are initialized with different model coefficients like diffusion parameters and the ensemble members also respond to two different mixing schemes - K profile parameterization and Mellor-Yamada. This aids in maintaining the spread of the ensemble intact - which has always been a challenging task. We have also employed a localization radius of ~200 km, i.e., observations influence the prognostic state variables that fall within this range. The assimilation system is also bestowed with better representative error estimates - a method developed in-house along the likes of Etherton et al. The ensemble members were forced with ensemble atmospheric fluxes provided by National Centre for Medium Range Weather Forecast (NCMRWF). Assimilation was performed every five day. We show that the assimilated system simulates the ocean state better than the present operational basin-wide ROMS. We validate it extensively against multiple observations ranging from RAMA moorings to ADCP observations across both dependent variables like temperature and salinity and independent variables like sealevel anomaly and currents. We show that assimilation improves the overall ocean state except at few isolated locations. It improves the correlation with respect to observations and reduces the root-mean-squared error. We also show that assimilation improves the estimation of mixed layer depth and 20 degree isotherm (which are diagnostic variables) thereby proving that the subsurface conditions are better simulated

Qualitative research approaches for studying local food environment and drivers of food purchase in South Asia

The High Level Panel of Experts on Food Security and Nutrition (2017)’s definition of the food environment has been expanded to include the significant issue of sustainability and the different types of food environment relevant to low- to middle-income countries (Downs et al., 2020), while Turner et al. (2018) builds on food environment research into the socio- ecological theory that posits that inter- related personal and environmental factors determine health-related behaviors

Copernicus Ocean State Report, issue 6

The 6th issue of the Copernicus OSR incorporates a large range of topics for the blue, white and green ocean for all European regional seas, and the global ocean over 1993–2020 with a special focus on 2020

Search for continuous gravitational wave emission from the Milky Way center in O3 LIGO--Virgo data

We present a directed search for continuous gravitational wave (CW) signals emitted by spinning neutron stars located in the inner parsecs of the Galactic Center (GC). Compelling evidence for the presence of a numerous population of neutron stars has been reported in the literature, turning this region into a very interesting place to look for CWs. In this search, data from the full O3 LIGO--Virgo run in the detector frequency band $[10,2000]\rm~Hz$ have been used. No significant detection was found and 95$\%$ confidence level upper limits on the signal strain amplitude were computed, over the full search band, with the deepest limit of about $7.6\times 10^{-26}$ at $\simeq 142\rm~Hz$. These results are significantly more constraining than those reported in previous searches. We use these limits to put constraints on the fiducial neutron star ellipticity and r-mode amplitude. These limits can be also translated into constraints in the black hole mass -- boson mass plane for a hypothetical population of boson clouds around spinning black holes located in the GC.Comment: 25 pages, 5 figure

Search for Eccentric Black Hole Coalescences during the Third Observing Run of LIGO and Virgo

Despite the growing number of confident binary black hole coalescences observed through gravitational waves so far, the astrophysical origin of these binaries remains uncertain. Orbital eccentricity is one of the clearest tracers of binary formation channels. Identifying binary eccentricity, however, remains challenging due to the limited availability of gravitational waveforms that include effects of eccentricity. Here, we present observational results for a waveform-independent search sensitive to eccentric black hole coalescences, covering the third observing run (O3) of the LIGO and Virgo detectors. We identified no new high-significance candidates beyond those that were already identified with searches focusing on quasi-circular binaries. We determine the sensitivity of our search to high-mass (total mass $M>70$ $M_\odot$) binaries covering eccentricities up to 0.3 at 15 Hz orbital frequency, and use this to compare model predictions to search results. Assuming all detections are indeed quasi-circular, for our fiducial population model, we place an upper limit for the merger rate density of high-mass binaries with eccentricities $0 < e \leq 0.3$ at $0.33$ Gpc$^{-3}$ yr$^{-1}$ at 90\% confidence level.Comment: 24 pages, 5 figure