A survey of Sierra Nevada magmatism using Great Valley detrital zircon trace-element geochemistry: View from the forearc

The well-characterized Sierra Nevada magmatic arc offers an unparalleled opportunity to improve our understanding of continental arc magmatism, but present bedrock exposure provides an incomplete record that is dominated by Cretaceous plutons, making it challenging to decipher details of older magmatism and the dynamic interplay between plutonism and volcanism. Moreover, the forearc detrital record includes abundant zircon formed during apparent magmatic lulls, suggesting that understanding the long-term history of arc magmatism requires integrating plutonic, volcanic, and detrital records. We present trace-element geochemistry of detrital zircon grains from the Great Valley forearc basin to survey Sierra Nevadan arc magmatism through Mesozoic time. We analyzed 257 previously dated detrital zircon grains from seven sandstone samples of volcanogenic, arkosic, and mixed compositions deposited ca. 145–80 Ma along the length of the forearc basin. Detrital zircon trace-element geochemistry is largely consistent with continental arc derivation and shows similar geochemical ranges between samples, regardless of location along strike of the forearc basin, depositional age, or sandstone composition. Comparison of zircon trace-element data from the forearc, arc, and retroarc regions revealed geochemical asymmetry across the arc that was persistent through time and demonstrated that forearc and retroarc basins sampled different parts of the arc and therefore recorded different magmatic histories. In addition, we identified a minor group of Jurassic detrital zircon grains with oceanic geochemical signatures that may have provenance in the Coast Range ophiolite. Taken together, these results suggest that the forearc detrital zircon data set reveals information different from that gleaned from the arc itself and that zircon compositions can help to identify and differentiate geochemically distinct parts of continental arc systems. Our results highlight the importance of integrating multiple proxies to fully document arc magmatism, demonstrating that detrital zircon geochemical data can enhance understanding of a well-characterized arc, and these data may prove an effective means by which to survey an arc that is inaccessible and therefore poorly characterized

Leveraging Detrital Zircon Geochemistry to Study Deep Arc Processes: REE-Rich Magmas Mobilized by Jurassic Rifting of the Sierra Nevada Arc

Anomalous trace element compositions of Middle to Late Jurassic detrital zircon separated from Sierra Nevada forearc and intra-arc strata reveal processes of differentiation occurring within the deep arc lithosphere. REE-Sc-Nb-Ti-Hf-U-Th covariations define three populations of atypically REE-rich grains that we interpret as crystallizing from (1) differentiates produced by olivine+clinopyroxene+plagioclase+garnet±ilmenite fractionation; (2) mixing between mafic arc magmas and partial melts of Proterozoic Mojave province crust; and (3) compositionally transient, low Gd/Yb magmas generated by hornblende resorption during decompression. We interpret a fourth population of Middle Jurassic to Early Cretaceous zircons having REE contents similar to “typical” arc zircon but with atypically high Gd/Yb ratios as having crystallized from partial melts of recycled arc crust and from deep-arc differentiates that evolved down-temperature through hornblende saturation. We hypothesize that latest Jurassic extension ripped open the arc, facilitating upward migration and eruption of geochemically anomalous zircon-bearing magmas. The anomalous compositions relative to “typical” arc zircon imply that these zircons and their host magmas rarely reach the upper arc crust, where eruption and/or erosion would release their zircon cargo to the clastic system. Focusing on the trace element compositions of zircons of syn-extensional age represents a productive new strategy for learning about deep magmatic reservoirs and early differentiation pathways within the thick lithosphere of continental margin arcs

An experimental study addressing the use of geoforensic analysis for the exploitation of improvised explosive devices (IEDs)

The use of geoforensic analysis in criminal investigations is continuing to develop, with the diversification of analytical techniques, many of which are semi-automated, facilitating prompt analysis of large sample sets at a relatively low cost. Whilst micro-scale geoforensic analysis has been shown to assist criminal investigations including homicide (Concheri et al., 2011 [1]), wildlife crime (Morgan et al., 2006 [2]), illicit drug distribution (Stanley, 1992 [3]), and burglary (Mildenhall, 2006 [4]), its application to the pressing international security threat posed by Improvised Explosive Devices (IEDs) is yet to be considered. This experimental study simulated an IED supply chain from the sourcing of raw materials through to device emplacement. Mineralogy, quartz grain surface texture analysis (QGSTA) and particle size analysis (PSA) were used to assess whether environmental materials were transferred and subsequently persisted on the different components of three pressure plate IEDs. The research also addressed whether these samples were comprised of material from single or multiple geographical provenances that represented supply chain activity nodes. The simulation demonstrated that material derived from multiple activity nodes, was transferred and persisted on device components. The results from the mineralogy and QGSTA illustrated the value these techniques offer for the analysis of mixed provenance samples. The results from the PSA, which produces a bulk signature of the sample, failed to distinguish multiple provenances. The study also considered how the environmental material recovered could be used to generate information regarding the geographical locations the device had been in contact with, in an intelligence style investigation, and demonstrated that geoforensic analysis has the potential to be of value to international counter-IED efforts. It is a tool that may be used to prevent the distribution of large quantities of devices, by aiding the identification of the geographical location of key activity nodes

Ordovician calc-alkaline granitoids in the Acatlán complex, southern México : geochemical and geochronologic data and implications for the tectonics of the Gondwanan margin of the Rheic Ocean

U-Pb zircon data from three undeformed to slightly deformed, megacrystic, granitoid plutons in the northern Acatlán Complex of southern México has indicated that all three are part of a larger suite of late Ordovician plutons. ⁴⁰Ar/³⁹Ar data from hornblende and biotite show mainly disturbed spectra, but biotite from the Palo Liso and Los Hornos plutons yields plateaus with ages of 305 ± 26 Ma and 157 ± 12 Ma, respectively. These thermal events may be correlated, respectively, with Permo-Triassic and Jurassic tectonothermal events recorded elsewhere in the Acatlán Complex. All three plutons are peraluminous with calc-alkaline affinities, characteristics that are consistent with inherited zircon ages and together suggest a source in Mesopro-terozoic calc-alkaline rocks similar to those exposed in the neighboring Oaxaca terrane. We interpret these granites to be related to the early Ordovician separation of peri-Gondwanan terranes from Gondwana during the opening of the Rheic Ocean. Elsewhere in the Acatlán Complex, Ordovician megacrystic granitoids of the Piaxtla Suite were subjected to high-grade metamorphism, which we infer to be related to subduction along the Gondwanan margin during the Devonian-Carboniferous. The three plutons reported here were not affected by Devono-Carboniferous metamorphism and thus are inferred to have remained outside the subduction zone.11 page(s